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Guonan Ma, Shize Zhu, Dong Wang, Peng Xue, Bolü Xiao, and Zongyi Ma, Effect of heat treatment on the microstructure, mechanical properties and fracture behaviors of ultra-high-strength SiC/Al–Zn–Mg–Cu composites, Int. J. Miner. Metall. Mater., 31(2024), No. 10, pp.2233-2243. https://dx.doi.org/10.1007/s12613-024-2856-1
Guonan Ma, Shize Zhu, Dong Wang, Peng Xue, Bolü Xiao, and Zongyi Ma, Effect of heat treatment on the microstructure, mechanical properties and fracture behaviors of ultra-high-strength SiC/Al–Zn–Mg–Cu composites, Int. J. Miner. Metall. Mater., 31(2024), No. 10, pp.2233-2243. https://dx.doi.org/10.1007/s12613-024-2856-1
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热处理对超高强度SiC/Al–Zn–Mg–Cu复合材料微观组织、力学性能和断裂行为的影响

摘要: SiC/Al–Zn–Mg–Cu铝基复合材料具有可以媲美钛合金的抗拉强度和弹性模量,作为轻量化结构材料的应用潜力巨大,成为了近年来的研究热点。增加合金元素含量,尤其是Zn元素,是提高Al–Zn–Mg–Cu系铝基复合材料力学性能的有效手段。然而,提高合金含量意味着沉淀相的种类、含量和分布可能发生变化,从而影响复合材料的力学性能和断裂行为。本文旨在开发一种超高强度铝基复合材料,阐明影响其力学性能的关键因素,为材料组织调控提供理论基础。本研究采用粉末冶金和热挤压变形的方法,制备了含12%SiC(体积分数)颗粒的SiC/Al–13.3Zn–3.27Mg–1.07Cu(质量分数,%)复合材料,通过微观组织表征、硬度、电导率和力学性能测试系统地优化了固溶和时效处理工艺,研究了第二相演化及其对复合材料微观组织、力学性能和断裂机制的影响规律。结果表明:双级固溶(470°C/1 h + 480°C/1 h)和低温时效(100°C/22 h)处理可以获得第二相充分溶解且纳米析出相均匀分布的微观组织,最佳抗拉强度可达781 MPa。断口分析表明,沿晶断裂和界面脱粘是超高强度SiC/Al–Zn–Mg–Cu复合材料的主要断裂机制。SiC/Al界面和高角度晶界处存在无析带,是限制复合材料强度提高的主要因素。界面反应产物MgO以及第二相MgZn2和Cu5Zn8优先在SiC/Al界面形核并长大,降低界面结合强度,进一步导致界面开裂。

 

Effect of heat treatment on the microstructure, mechanical properties and fracture behaviors of ultra-high-strength SiC/Al–Zn–Mg–Cu composites

Abstract: A high-zinc composite, 12vol% SiC/Al–13.3 Zn–3.27 Mg–1.07Cu (wt%), with an ultra-high-strength of 781 MPa was successfully fabricated through a powder metallurgy method, followed by an extrusion process. The effects of solid-solution and aging heat treatments on the microstructure and mechanical properties of the composite were extensively investigated. Compared with a single-stage solid-solution treatment, a two-stage solid-solution treatment (470°C/1 h + 480°C/1 h) exhibited a more effective solid-solution strengthening owing to the higher degree of solid-solution and a more uniform microstructure. According to the aging hardness curves of the composite, the optimized aging parameter (100°C/22 h) was determined. Reducing the aging temperature and time resulted in finer and more uniform nanoscale precipitates but only yielded a marginal increase in tensile strength. The fractography analysis revealed that intergranular cracking and interface debonding were the main fracture mechanisms in the ultra-high-strength SiC/Al–Zn–Mg–Cu composites. Weak regions, such as the SiC/Al interface containing numerous compounds and the precipitate-free zones at the high-angle grain boundaries, were identified as significant factors limiting the strength enhancement of the composite. Interfacial compounds, including MgO, MgZn2, and Cu5Zn8, reduced the interfacial bonding strength, leading to interfacial debonding.

 

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