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Qiuhong Liu, Qing Du, Xiaobin Zhang, Yuan Wu, Andrey A. Rempel, Xiangyang Peng, Xiongjun Liu, Hui Wang, Wenli Song, and Zhaoping Lü, Characterization of local chemical ordering and deformation behavior in high entropy alloys by transmission electron microscopy, Int. J. Miner. Metall. Mater., 31(2024), No. 5, pp.877-886. https://dx.doi.org/10.1007/s12613-024-2884-x
Qiuhong Liu, Qing Du, Xiaobin Zhang, Yuan Wu, Andrey A. Rempel, Xiangyang Peng, Xiongjun Liu, Hui Wang, Wenli Song, and Zhaoping Lü, Characterization of local chemical ordering and deformation behavior in high entropy alloys by transmission electron microscopy, Int. J. Miner. Metall. Mater., 31(2024), No. 5, pp.877-886. https://dx.doi.org/10.1007/s12613-024-2884-x
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高熵合金局域化学有序及变形机制的透射电子显微学表征

摘要: 基于高熵理念而设计的高熵合金具有不同于传统合金的独特的力学性能。近些年的研究表明,高熵合金最重要的特征之一是其具有短程有序结构。然而,短程有序结构具有尺寸小、成分复杂、位置多样的特点,导致其化学成分和结构分析非常困难。同时,如何调控短程有序结构的形成进而改善高熵合金的力学性能也是极大的挑战。透射电子显微镜结合球差校正技术是精准表征材料微观组织结构的强有力工具,应用不同的透射电子显微镜技术不仅可以表征高熵合金中的短程有序结构并揭示其形成机制,而且可以辅助调控高熵合金的性能。基于此,本文综述了近年来先进透射电子显微镜技术在高熵合金短程有序结构表征领域的最新进展,并根据短程有序结构形成方式的不同,对证明短程有序结构存在的表征手段分别进行了总结,阐明了短程有序结构对高熵合金变形机制的影响,最后展望了先进透射电子显微镜技术在高熵合金中的应用前景。

 

Characterization of local chemical ordering and deformation behavior in high entropy alloys by transmission electron microscopy

Abstract: Short-range ordering (SRO) is one of the most important structural features of high entropy alloys (HEAs). However, the chemical and structural analyses of SROs are very difficult due to their small size, complexed compositions, and varied locations. Transmission electron microscopy (TEM) as well as its aberration correction techniques are powerful for characterizing SROs in these compositionally complex alloys. In this short communication, we summarized recent progresses regarding characterization of SROs using TEM in the field of HEAs. By using advanced TEM techniques, not only the existence of SROs was confirmed, but also the effect of SROs on the deformation mechanism was clarified. Moreover, the perspective related to application of TEM techniques in HEAs are also discussed.

 

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