失效三元锂电池中有价金属回收利用综述

廖浩; 张深根; 刘波; 何学峰; 邓纪新; 丁云集

doi:10.1007/s12613-024-2895-7

Volume 31 Issue 12

Dec. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(12): 2556-2581

Hao Liao, Shengen Zhang, Bo Liu, Xuefeng He, Jixin Deng, and Yunji Ding, Valuable metals recovery from spent ternary lithium-ion battery: A review, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2556-2581. https://doi.org/10.1007/s12613-024-2895-7

Cite this article as:

Hao Liao, Shengen Zhang, Bo Liu, Xuefeng He, Jixin Deng, and Yunji Ding, Valuable metals recovery from spent ternary lithium-ion battery: A review, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2556-2581. https://doi.org/10.1007/s12613-024-2895-7

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综述

失效三元锂电池中有价金属回收利用综述

1)
北京科技大学新材料技术研究院，北京 100083，中国
2)
北京科技大学顺德创新学院，佛山 528399，中国
3)
中国石化催化剂有限公司工程技术研究院，北京 101111，中国
4)
新疆有色金属研究院，乌鲁木齐 830009，中国

通讯作者:
张深根 E-mail: zhangshengen@mater.ustb.edu.cn

丁云集 E-mail: dingyunji@ustb.edu.cn

文章亮点

(1) 回顾了三元锂电池的消耗和未来需求

(2) 综述了废旧三元锂离子电池金属回收的各种方法

(3) 讨论了回收技术的优点和对环境的影响

(4) 总结并提出了对面向环境的技术的考虑

中文摘要

三元锂离子电池(LIBs)以其能量密度高、工作温度范围宽、循环性能优异等优点被广泛应用于新能源汽车和电子产品中。随着电池产业的快速发展，由于废旧三元锂电池回收利用的经济价值和环境问题而成为一个热门话题。迄今为止，已有大量文献报道了废旧三元锂电池的回收利用，旨在为电池回收提供一种高效、经济、环保的方法。本文从研究和实际生产两方面综述了各种废旧三元锂电池回收技术的最新进展，包括预处理、火法冶金、湿法冶金、火法-湿法冶金和直接再生。根据每种方法的优缺点，提出了应对挑战的建议。最后，通过比较各种技术的可行性和经济效益，总结了电池回收面临的挑战，并提出了未来的发展方向。

关键词:

Review

Valuable metals recovery from spent ternary lithium-ion battery: A review

+ Author Affiliations

1)
Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
2)
Shunde Innovation School, University of Science and Technology Beijing, Foshan 528399, China
3)
Institute of Engineering Technology, SINOPEC Catalyst Co., Ltd., Beijing 101111, China
4)
Xinjiang Research Institute for Nonferrous Metals, Urumqi 830009, China

The authors declare no conflict of interest.

Corresponding authors:
Shengen Zhang E-mail: zhangshengen@mater.ustb.edu.cn

Yunji Ding E-mail: dingyunji@ustb.edu.cn
Received: 18 September 2023; Revised: 28 March 2024; Accepted: 29 March 2024; Available online: 30 March 2024

Abstract

Abstract

Ternary lithium-ion batteries (LIBs), widely used in new energy vehicles and electronic products, are known for their high energy density, wide operating temperature range, and excellent cycling performance. With the rapid development of the battery industry, the recycling of spent ternary LIBs has become a hot topic because of their economic value and environmental concerns. To date, a considerable amount of literature has reported on the recycling of spent ternary LIBs designed to provide an efficient, economical, and environmentally friendly method for battery recycling. This article examines the latest developments in various technologies for recycling spent ternary LIBs in both research and practical production, including pretreatment, pyrometallurgy, hydrometallurgy, pyro-hydrometallurgy, and direct regeneration. Suggestions for addressing challenges based on the benefits and disadvantages of each method are made. Finally, through a comparison of the feasibility and economic benefits of various technologies, the challenges faced during battery recycling are summarized, and future development directions are proposed.
- spent ternary LIBs;
- recycling technologies;
- valuable metals;
- economic analysis

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