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Volume 31 Issue 7
Jul.  2024
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文章导航 >  矿物冶金与材料学报（英文）  > 2024  >  31(7): 1713-1719
Shufang Li, Huilan Guan, Can Zhu, Chaoyuan Sun, Qingya Wei, Jun Yuan,  and Yingping Zou, Alkyl chain modulation of asymmetric hexacyclic fused acceptor synergistically with wide bandgap third component for high efficiency ternary organic solar cells, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1713-1719. https://doi.org/10.1007/s12613-024-2903-y
Cite this article as:
Shufang Li, Huilan Guan, Can Zhu, Chaoyuan Sun, Qingya Wei, Jun Yuan,  and Yingping Zou, Alkyl chain modulation of asymmetric hexacyclic fused acceptor synergistically with wide bandgap third component for high efficiency ternary organic solar cells, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1713-1719. https://doi.org/10.1007/s12613-024-2903-y
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研究论文

非对称六元稠环受体的烷基链调节与宽带隙第三组分协同用于高效三元有机太阳能电池

  • 1)

    中南大学化学与化工学院, 湖南, 410083, 中国

  • 2)

    中国科学院化学研究所有机固体重点实验室, 北京100190, 中国

  • 3)

    杭州电子科技大学电子与信息学院, 杭州310018, 中国



  • 通讯作者:

    邹应萍    E-mail: yingpingzou@csu.edu.cn

文章亮点

  • (1) 合成了两种具有不同长度侧链的非对称的六元稠环小分子受体，BP4F-HU和BP4F-UU。
  • (2) 基于PM6:BP4F-UU的器件相较于PM6:BP4F-HU（0.863 V）表现出0.878 V的高开路电压。
  • (3) 合成了一种新的宽带隙小分子受体，BTP-TA，三元器件PM6:BP4F-UU:BTP-TA达到了17.83％的最佳光电转化效率。
  • 有机太阳能电池(OSCs)作为一种新型清洁光伏技术，因其具有质量轻、柔性和可溶液法加工等优点受到广泛关注。精细分子设计与器件工艺优化之间的协同作用为实现OSCs中开路电压（Voc）、短路电流密度（Jsc）和填充因子（FF）之间的平衡提供了可能途径，从而进一步推动高效有机光伏器件的发展。在此，合成了两种非对称的六元稠环小分子受体（SMAs），命名为BP4F-HU和BP4F-UU。BP4F-UU分子中外侧烷基链的延伸限制了其末端基团的旋转，降低了混合薄膜中的能量失序，进而减少了器件中的能量损失。同时，BP4F-UU分子中π–π堆积的增强提高了薄膜的电荷迁移率。基于PM6:BP4F-UU的器件相较于PM6:BP4F-HU（0.863 V）表现出0.878 V的高Voc。此外，设计合成了一种与PM6:BP4F-UU二元体系具有互补吸收的新的宽带隙SMA，命名为BTP-TA。由于BTP-TA的光致发光（PL）光谱与BP4F-UU的吸收光谱之间有良好的重叠，BTP-TA与BP4F-UU之间可以通过荧光共振能量转移（FRET）途径实现有效的分子间能量转移。宽带隙第三组分BTP-TA的加入进一步提高了器件的Voc。最终，含有15wt％BTP-TA的三元器件PM6:BP4F-UU:BTP-TA实现了Voc（0.905 V）、Jsc（26.14 mA/cm2）和FF（75.38％）的同时提高，达到了17.83％的最佳PCE。这项工作表明，分子结构设计与器件工艺优化的协同策略是提高有机太阳能器件光伏性能的有效方法。
    • Research Article

    Alkyl chain modulation of asymmetric hexacyclic fused acceptor synergistically with wide bandgap third component for high efficiency ternary organic solar cells

    + Author Affiliations
      Abstract
    • Herein, two asymmetric hexacyclic fused small molecule acceptors (SMAs), namely BP4F-HU and BP4F-UU, were synthesized. The elongated outside chains in the BP4F-UU molecule played a crucial role in optimizing the morphology of blend film, thereby improving charge mobility and reducing energy loss within the corresponding film. Notably, the PM6:BP4F-UU device exhibited a higher open-circuit voltage (Voc) of 0.878 V compared to the PM6:BP4F-HU device with a Voc of 0.863 V. Further, a new wide bandgap SMA named BTP-TA was designed and synthesized as the third component to the PM6:BP4F-UU host binary devices, which showed an ideal complementary absorption spectrum in PM6:BP4F-UU system. In addition, BTP-TA can achieve efficient intermolecular energy transfer to BP4F-UU by fluorescence resonance energy transfer (FRET) pathway, due to the good overlap between the photoluminescence (PL) spectrum of BTP-TA and the absorption region of BP4F-UU. Consequently, ternary devices with 15wt% BTP-TA exhibits broader photon utilization, optimal blend morphology, and reduced charge recombination compared to the corresponding binary devices. Consequently, PM6:BP4F-UU:BTP-TA ternary device achieved an optimal power conversion efficiency (PCE) of 17.83% with simultaneously increased Voc of 0.905 V, short-circuit current density (Jsc) of 26.14 mA/cm2, and fill factor (FF) of 75.38%.
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    • [1]
      L.L. Feng, J. Yuan, Z.Z. Zhang, et al., Thieno [3,2-b] pyrrolo-fused pentacyclic benzotriazole-based acceptor for efficient organic photovoltaics, ACS Appl. Mater. Interfaces, 9(2017), No. 37, p. 31985. doi: 10.1021/acsami.7b10995
      [2]
      M. Li, Y.Y. Zhou, J.Q. Zhang, J.S. Song, and Z.S. Bo, Tuning the dipole moments of nonfullerene acceptors with an asymmetric terminal strategy for highly efficient organic solar cells, J. Mater. Chem. A, 7(2019), No. 15, p. 8889. doi: 10.1039/C8TA12530A
      [3]
      K. Jiang, Q.Y. Wei, J.Y.L. Lai, et al., Alkyl chain tuning of small molecule acceptors for efficient organic solar cells, Joule, 3(2019), No. 12, p. 3020. doi: 10.1016/j.joule.2019.09.010
      [4]
      S. Liu, J. Yuan, W.Y. Deng, et al., High-efficiency organic solar cells with low non-radiative recombination loss and low energetic disorder, Nat. Photonics, 14(2020), No. 5, p. 300. doi: 10.1038/s41566-019-0573-5
      [5]
      C. Zhu, J. Yuan, F.F. Cai, et al., Tuning the electron-deficient core of a non-fullerene acceptor to achieve over 17% efficiency in a single-junction organic solar cell, Energy Environ. Sci., 13(2020), No. 8, p. 2459. doi: 10.1039/D0EE00862A
      [6]
      S.N. Bao, H. Yang, H.Y. Fan, et al., Volatilizable solid additive-assisted treatment enables organic solar cells with efficiency over 18.8% and fill factor exceeding 80, Adv. Mater., 33(2021), No. 48, art. No. 2105301. doi: 10.1002/adma.202105301
      [7]
      X.J. Chen, D. Wang, Z.K. Wang, et al., 18.02% efficiency ternary organic solar cells with a small-molecular donor third component, Chem. Eng. J., 424(2021), art. No. 130397. doi: 10.1016/j.cej.2021.130397
      [8]
      Y. Cui, Y. Xu, H.F. Yao, et al., Single-junction organic photovoltaic cell with 19% efficiency, Adv. Mater., 33(2021), No. 41, art. No. 2102420. doi: 10.1002/adma.202102420
      [9]
      L.Z. Liu, S.Y. Chen, Y.Y. Qu, et al., Nanographene–osmapentalyne complexes as a cathode interlayer in organic solar cells enhance efficiency over 18%, Adv. Mater., 33(2021), No. 30, art. No. 2101279. doi: 10.1002/adma.202101279
      [10]
      R.J. Ma, T. Yang, Y.Q. Xiao, et al., Air-processed efficient organic solar cells from aromatic hydrocarbon solvent without solvent additive or post-treatment: Insights into solvent effect on morphology, Energy Environ. Mater., 5(2022), No. 3, p. 977. doi: 10.1002/eem2.12226
      [11]
      G.U. Kim, C. Sun, D. Lee, et al., Effect of the selective halogenation of small molecule acceptors on the blend morphology and voltage loss of high-performance solar cells, Adv. Funct. Mater., 32(2022), No. 25, art. No. 2201150. doi: 10.1002/adfm.202201150
      [12]
      G.L. Cai, Z. Chen, X.X. Xia, et al., Pushing the efficiency of high open-circuit voltage binary organic solar cells by vertical morphology tuning, Adv. Sci., 9(2022), No. 14, art. No. 2200578. doi: 10.1002/advs.202200578
      [13]
      F. Lin, K. Jiang, W. Kaminsky, Z.L. Zhu, and A.K.Y. Jen, A non-fullerene acceptor with enhanced intermolecular π-core interaction for high-performance organic solar cells, J. Am. Chem. Soc., 142(2020), No. 36, p. 15246. doi: 10.1021/jacs.0c07083
      [14]
      Z.C. Zhou, W.R. Liu, G.Q. Zhou, et al., Subtle molecular tailoring induces significant morphology optimization enabling over 16% efficiency organic solar cells with efficient charge generation, Adv. Mater., 32(2020), No. 4, art. No. 1906324. doi: 10.1002/adma.201906324
      [15]
      Y. Cui, H.F. Yao, J.Q. Zhang, et al., Single-junction organic photovoltaic cells with approaching 18% efficiency, Adv. Mater., 32(2020), No. 19, art. No. 1908205. doi: 10.1002/adma.201908205
      [16]
      C. Li, J.D. Zhou, J.L. Song, et al., Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells, Nat. Energy, 6(2021), No. 6, p. 605. doi: 10.1038/s41560-021-00820-x
      [17]
      Z.H. Luo, R.J. Ma, T. Liu, et al., Fine-tuning energy levels via asymmetric end groups enables polymer solar cells with efficiencies over 17%, Joule, 4(2020), No. 6, p. 1236. doi: 10.1016/j.joule.2020.03.023
      [18]
      H. Chen, H.J. Lai, Z.Y. Chen, et al., 17.1%-efficient eco-compatible organic solar cells from a dissymmetric 3D network acceptor, Angew. Chem. Int. Ed., 60(2021), No. 6, p. 3238. doi: 10.1002/anie.202013053
      [19]
      F. Liu, L. Zhou, W.R. Liu, et al., Organic solar cells with 18% efficiency enabled by an alloy acceptor: A two-in-one strategy, Adv. Mater., 33(2021), No. 27, art. No. 2100830. doi: 10.1002/adma.202100830
      [20]
      Y.H. Cai, Y. Li, R. Wang, et al., A well-mixed phase formed by two compatible non-fullerene acceptors enables ternary organic solar cells with efficiency over 18.6%, Adv. Mater., 33(2021), No. 33, art. No. 2101733. doi: 10.1002/adma.202101733
      [21]
      T. Zhang, C.B. An, P.Q. Bi, et al., A thiadiazole-based conjugated polymer with ultradeep HOMO level and strong electroluminescence enables 18.6% efficiency in organic solar cell, Adv. Energy Mater., 11(2021), No. 35, art. No. 2101705. doi: 10.1002/aenm.202101705
      [22]
      G.C. Liu, R.X. Xia, Q.R. Huang, et al., Tandem organic solar cells with 18.7% efficiency enabled by suppressing the charge recombination in front sub-cell, Adv. Funct. Mater., 31(2021), No. 29, art. No. 2103283. doi: 10.1002/adfm.202103283
      [23]
      J.Q. Wang, Z. Zheng, Y.F. Zu, et al., A tandem organic photovoltaic cell with 19.6% efficiency enabled by light distribution control, Adv. Mater., 33(2021), No. 39, art. No. 2102787. doi: 10.1002/adma.202102787
      [24]
      Z. Zheng, J.Q. Wang, P.Q. Bi, et al., Tandem organic solar cell with 20.2% efficiency, Joule, 6(2022), No. 1, p. 171. doi: 10.1016/j.joule.2021.12.017
      [25]
      X.J. Zheng, L.J. Zuo, F. Zhao, et al., High-efficiency ITO-free organic photovoltaics with superior flexibility and upscalability, Adv. Mater., 34(2022), No. 17, art. No. 2200044. doi: 10.1002/adma.202200044
      [26]
      J. Yao, B.B. Qiu, Z.G. Zhang, et al., Cathode engineering with perylene-diimide interlayer enabling over 17% efficiency single-junction organic solar cells, Nat. Commun., 11(2020), No. 1, art. No. 2726. doi: 10.1038/s41467-020-16509-w
      [27]
      J. Lv, H. Tang, J.M. Huang, et al., Additive-induced miscibility regulation and hierarchical morphology enable 17.5% binary organic solar cells, Energy Environ. Sci., 14(2021), No. 5, p. 3044. doi: 10.1039/D0EE04012F
      [28]
      X.P. Xu, L.Y. Yu, H. Yan, R.P. Li, and Q. Peng, Highly efficient non-fullerene organic solar cells enabled by a delayed processing method using a non-halogenated solvent, Energy Environ. Sci., 13(2020), No. 11, p. 4381. doi: 10.1039/D0EE02034F
      [29]
      L. Zhu, M. Zhang, J.Q. Xu, et al., Single-junction organic solar cells with over 19% efficiency enabled by a refined double-fibril network morphology, Nat. Mater., 21(2022), No. 6, p. 656. doi: 10.1038/s41563-022-01244-y
      [30]
      L.L. Zhan, S.C. Yin, Y.K. Li, et al., Multiphase morphology with enhanced carrier lifetime via quaternary strategy enables high-efficiency thick-film, and large-area organic photovoltaics, Adv. Mater., 34(2022), No. 45, art. No. 2206269. doi: 10.1002/adma.202206269
      [31]
      J.Q. Zhang, H.S. Tan, X.G. Guo, A. Facchetti, and H. Yan, Material insights and challenges for non-fullerene organic solar cells based on small molecular acceptors, Nat. Energy, 3(2018), No. 9, p. 720. doi: 10.1038/s41560-018-0181-5
      [32]
      Z.Z. Zhang, Y.W. Li, G.L. Cai, Y.H. Zhang, X.H. Lu, and Y.Z. Lin, Selenium heterocyclic electron acceptor with small urbach energy for as-cast high-performance organic solar cells, J. Am. Chem. Soc., 142(2020), No. 44, p. 18741. doi: 10.1021/jacs.0c08557
      [33]
      F.F. Cai, H.J. Peng, H.G. Chen, et al., An asymmetric small molecule acceptor for organic solar cells with a short circuit current density over 24 mA·cm−2, J. Mater. Chem. A, 8(2020), No. 31, p. 15984. doi: 10.1039/D0TA01636E
      [34]
      W. Gao, H.T. Fu, Y.X. Li, et al., Asymmetric acceptors enabling organic solar cells to achieve an over 17% efficiency: Conformation effects on regulating molecular properties and suppressing nonradiative energy loss, Adv. Energy Mater., 11(2021), No. 4, art. No. 2003177. doi: 10.1002/aenm.202003177
      [35]
      Y.Z. Chen, F.J. Bai, Z.X. Peng, et al., Asymmetric alkoxy and alkyl substitution on nonfullerene acceptors enabling high-performance organic solar cells, Adv. Energy Mater., 11(2021), No. 3, art. No. 2003141. doi: 10.1002/aenm.202003141
      [36]
      L.Y. Su, H.H. Huang, Y.C. Lin, et al., Enhancing long-term thermal stability of non-fullerene organic solar cells using self-assembly amphiphilic dendritic block copolymer interlayers, Adv. Funct. Mater., 31(2021), No. 4, art. No. 2005753. doi: 10.1002/adfm.202005753
      [37]
      J.S. Song and Z.S. Bo, Asymmetric molecular engineering in recent nonfullerene acceptors for efficient organic solar cells, Chin. Chem. Lett., 34(2023), No. 10, art. No. 108163. doi: 10.1016/j.cclet.2023.108163
      [38]
      Z.H. Luo, Y. Gao, H.J. Lai, et al., Asymmetric side-chain substitution enables a 3D network acceptor with hydrogen bond assisted crystal packing and enhanced electronic coupling for efficient organic solar cells, Energy Environ. Sci., 15(2022), No. 11, p. 4601. doi: 10.1039/D2EE01848A
      [39]
      X. Zhang, C.Q. Li, L.Q. Qin, et al., Side-chain engineering for enhancing the molecular rigidity and photovoltaic performance of noncovalently fused-ring electron acceptors, Angew. Chem. Int. Ed., 60(2021), No. 32, p. 17720. doi: 10.1002/anie.202106753
      [40]
      Y.L. Yin, L.L. Zhan, M. Liu, et al., Boosting photovoltaic performance of ternary organic solar cells by integrating a multi-functional guest acceptor, Nano Energy, 90(2021), art. No. 106538. doi: 10.1016/j.nanoen.2021.106538
      [41]
      L.L. Zhan, S.X. Li, Y.K. Li, et al., Desired open-circuit voltage increase enables efficiencies approaching 19% in symmetric-asymmetric molecule ternary organic photovoltaics, Joule, 6(2022), No. 3, p. 662. doi: 10.1016/j.joule.2022.02.001
      [42]
      X.W. Guo, D.Q. Li, Y.X. Zhang, et al., Understanding the effect of N2200 on performance of J71:ITIC bulk heterojunction in ternary non-fullerene solar cells, Org. Electron., 71(2019), p. 65. doi: 10.1016/j.orgel.2019.05.004
      [43]
      J. Lee, S.M. Lee, S. Chen, et al., Organic photovoltaics with multiple donor–acceptor pairs, Adv. Mater., 31(2019), No. 20, art. No. 1804762. doi: 10.1002/adma.201804762
      [44]
      F.F. Cai, C. Zhu, J. Yuan, et al., Efficient organic solar cells based on a new “Y-series” non-fullerene acceptor with an asymmetric electron-deficient-core, Chem. Commun., 56(2020), No. 31, p. 4340. doi: 10.1039/C9CC10076H
      [45]
      L.G. Xiao, M.A. Kolaczkowski, Y.G. Min, and Y. Liu, Substitution effect on thiobarbituric acid end groups for high open-circuit voltage non-fullerene organic solar cells, ACS Appl. Mater. Interfaces, 12(2020), No. 37, p. 41852. doi: 10.1021/acsami.0c11828
      [46]
      N.Y. Doumon, L.L. Yang, and F. Rosei, Ternary organic solar cells: A review of the role of the third element, Nano Energy, 94(2022), art. No. 106915. doi: 10.1016/j.nanoen.2021.106915
      [47]
      L.C. Chang, M. Sheng, L.P. Duan, and A. Uddin, Ternary organic solar cells based on non-fullerene acceptors: A review, Org. Electron., 90(2021), art. No. 106063. doi: 10.1016/j.orgel.2021.106063
      [48]
      Y.J. Cheng, B. Huang, X.X. Huang, et al., Oligomer-assisted photoactive layers enable >18% efficiency of organic solar cells, Angew. Chem. Int. Ed., 61(2022), No. 21, art. No. e202200329. doi: 10.1002/anie.202200329
      [49]
      Z.P. Yu, Z.X. Liu, F.X. Chen, et al., Simple non-fused electron acceptors for efficient and stable organic solar cells, Nat. Commun., 10(2019), art. No. 2152. doi: 10.1038/s41467-019-10098-z
      [50]
      J. Yuan, C.J. Zhang, H.G. Chen, et al., Understanding energetic disorder in electron-deficient-core-based non-fullerene solar cells, Sci. China Chem., 63(2020), No. 8, p. 1159. doi: 10.1007/s11426-020-9747-9
      [51]
      B. Qiu, Z. Chen, S. Qin, et al., Highly efficient all-small-molecule organic solar cells with appropriate active layer morphology by side chain engineering of donor molecules and thermal annealing, Adv. Mater., 32(2020), No. 21, art. No. 1908373. doi: 10.1002/adma.201908373
      [52]
      S.X. Li, L.L. Zhan, C.K. Sun, et al., Highly efficient fullerene-free organic solar cells operate at near zero highest occupied molecular orbital offsets, J. Am. Chem. Soc., 141(2019), No. 7, p. 3073. doi: 10.1021/jacs.8b12126
      [53]
      J.N. Song, M. Zhang, M. Yuan, Y.H. Qian, Y.M. Sun, and F. Liu, Morphology characterization of bulk heterojunction solar cells, Small Methods, 2(2018), No. 3, art. No. 1700229. doi: 10.1002/smtd.201700229
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