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文章导航 >  矿物冶金与材料学报（英文）  > 2025  > 二校
Shaorou Ke, Yajing Zhao, Xin Min, Yanghong Li, Ruiyu Mi, Yangai Liu, Xiaowen Wu, Minghao Fang,  and Zhaohui Huang, Highly mass activity electrocatalysts with ultralow Pt loading on carbon black for hydrogen evolution reaction, Int. J. Miner. Metall. Mater.,(2025). https://doi.org/10.1007/s12613-024-2912-x
Cite this article as:
Shaorou Ke, Yajing Zhao, Xin Min, Yanghong Li, Ruiyu Mi, Yangai Liu, Xiaowen Wu, Minghao Fang,  and Zhaohui Huang, Highly mass activity electrocatalysts with ultralow Pt loading on carbon black for hydrogen evolution reaction, Int. J. Miner. Metall. Mater.,(2025). https://doi.org/10.1007/s12613-024-2912-x
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研究论文

高质量活性铂/碳黑电催化剂制备及其高效电催化析氢性能

  • 中国地质大学（北京）材料科学与工程学院，地质碳储与资源低碳利用教育部工程研究中心，矿物材料国家专业实验室，非金属矿物与固废资源材料化利用北京市重点实验室，北京 100083，中国



    • * 共同第一作者
  • 通讯作者:

    闵鑫    E-mail: minx@cugb.edu.cn

文章亮点

  • (1) 成功制备了铂含量低但催化性能优异的铂碳纳米催化剂，对降低成本及提高资源利用率具有重要意义。
  • (2) 通过超声辅助–原位合成技术开发了活性组分均匀分布的铂碳催化剂，其质量活性优于商业Pt/C催化剂。
  • (3) 揭示碳黑与铂之间的轨道杂化效应，阐明制得铂碳催化剂保持良好稳定性的作用机制。
  • 铂基纳米催化剂在催化等领域中具有巨大的应用前景，但开发高效稳定且铂载量更低的铂基纳米催化剂仍是当前的重要挑战。本研究通过超声辅助的原位合成技术成功制备了一类以碳黑作为载体的铂基纳米催化剂，其铂的负载量仅为铂载量6.84wt%，金属铂纳米颗粒的粒径约为2 nm，且在碳黑表面均匀分布，归因于碳黑和铂之间强烈的s–p–d轨道杂化作用，有效防止了铂纳米颗粒团聚。研究结果表明，制得铂碳催化剂具有优异的电催化析氢性能，在电流密度为100 mA·cm−2时其过电位仅为100 mV，且具有优异的循环稳定性；其质量活性高达1.61 A/mg，是商业铂碳催化剂（0.37 A/mg）的4倍。论文研究成果可望为推进贵金属高效制备高效电催化剂和铂基纳米催化剂发展应该提供新的技术思路。
    • Research Article

    Highly mass activity electrocatalysts with ultralow Pt loading on carbon black for hydrogen evolution reaction

    + Author Affiliations
      Abstract
    • Pt-based nanocatalysts offer excellent prospects for various industries. However, the low loading of Pt with excellent performance for efficient and stable nanocatalysts still presents a considerable challenge. In this study, nanocatalysts with ultralow Pt content, excellent performance, and carbon black as support were prepared through in-situ synthesis. These ~2-nm particles uniformly and stably dispersed on carbon black because of the strong s–p–d orbital hybridizations between carbon black and Pt, which suppressed the agglomeration of Pt ions. This unique structure is beneficial for the hydrogen evolution reaction. The catalysts exhibited remarkable catalytic activity for hydrogen evolution reaction, exhibiting a potential of 100 mV at 100 mA·cm−2, which is comparable to those of commercial Pt/C catalysts. Mass activity (1.61 A/mg) was four times that of a commercial Pt/C catalyst (0.37 A/mg). The ultralow Pt loading (6.84wt%) paves the way for the development of next-generation electrocatalysts.
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