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Xiao Zhang, and Ping Yang, Advances in noble metal-modified g-C3N4 heterostructures toward enhanced photocatalytic redox ability, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp.2368-2389. https://dx.doi.org/10.1007/s12613-024-2924-6
Xiao Zhang, and Ping Yang, Advances in noble metal-modified g-C3N4 heterostructures toward enhanced photocatalytic redox ability, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp.2368-2389. https://dx.doi.org/10.1007/s12613-024-2924-6
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具有增强光催化氧化还原能力的贵金属改性g-C3N4异质结的研究进展

摘要: 催化剂的光催化活性取决于太阳光利用率和光生载流子的分离和传输。通过改变贵金属纳米颗粒(如Cu、Au、Pd等)的分布,可以在整个可见光区域实现表面等离子体共振效应,以提高石墨氮化碳(g-C3N4)基复合材料的光吸收能力。由于贵金属的等离子体共振效应能够增强局域电磁场,改善带间跃迁,以及通过近场电磁相互作用实现从等离子体偶极子到电子空穴对的共振能量转移,贵金属被广泛用于g-C3N4纳米材料改性,并用于CO2光还原和水分解。本综述系统讨论了贵金属(单原子、团簇或纳米粒子形式)和无机/有机纳米组分掺入的g-C3N4纳米片基复合光催化剂的最新研究进展,特别是这些光催化剂在CO2光转化和光解水产氢中的重要应用。还讨论了不同类型的多组分纳米异质结(肖特基结、Z-/S型异质结,由贵金属和其他半导体纳米组分组成的多组分异质结)以及异质结构维度调整(通过在g-C3N4上掺入贵金属纳米板形成2D/2D异质结)的相关问题。特别是分析了在光解水、二氧化碳减排、污染降解和化学转化应用方面,贵金属(如金、铂、钯和铜)掺杂g-C3N4复合光催化剂的应用前景和可能面临的挑战。

 

Advances in noble metal-modified g-C3N4 heterostructures toward enhanced photocatalytic redox ability

Abstract: The photocatalytic activity of catalysts depends on the energy-harvesting ability and the separation or transport of photogenerated carriers. The light absorption capacity of graphitic carbon nitride (g-C3N4)-based composites can be enhanced by adjusting the surface plasmon resonance (SPR) of noble metal nanoparticles (e.g., Cu, Au, and Pd) in the entire visible region. Adjustments can be carried out by varying the nanocomponents of the materials. The SPR of noble metals can enhance the local electromagnetic field and improve interband transition, and resonant energy transfer occurs from plasmonic dipoles to electron–hole pairs via near-field electromagnetic interactions. Thus, noble metals have emerged as relevant nanocomponents for g-C3N4 used in CO2 photoreduction and water splitting. Herein, recent key advances in noble metals (either in single atom, cluster, or nanoparticle forms) and composite photocatalysts based on inorganic or organic nanocomponent-incorporated g-C3N4 nanosheets are systematically discussed, including the applications of these photocatalysts, which exhibit improved photoinduced charge mobility in CO2 photoconversion and H2 production. Issues related to the different types of multi-nanocomponent heterostructures (involving Schottky junctions, Z-/S-scheme heterostructures, noble metals, and additional semiconductor nanocomponents) and the adjustment of dimensionality of heterostructures (by incorporating noble metal nanoplates on g-C3N4 forming 2D/2D heterostructures) are explored. The current prospects and possible challenges of g-C3N4 composite photocatalysts incorporated with noble metals (e.g., Au, Pt, Pd, and Cu), particularly in water splitting, CO2 reduction, pollution degradation, and chemical conversion applications, are summarized.

 

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