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Jiande Liu, Zhenghua He, Yuhui Sha, Xiaofei Zhu, Hongbo Hao, Lijia Chen, and Liang Zuo, Multiple impacts of trace Tb addition on the secondary recrystallization and magnetostriction of Fe–Ga thin sheet, Int. J. Miner. Metall. Mater.,(2025). https://dx.doi.org/10.1007/s12613-024-2943-3
Jiande Liu, Zhenghua He, Yuhui Sha, Xiaofei Zhu, Hongbo Hao, Lijia Chen, and Liang Zuo, Multiple impacts of trace Tb addition on the secondary recrystallization and magnetostriction of Fe–Ga thin sheet, Int. J. Miner. Metall. Mater.,(2025). https://dx.doi.org/10.1007/s12613-024-2943-3
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微量Tb添加对Fe–Ga合金薄带二次再结晶与磁致伸缩性能的多重影响规律

摘要: Fe–Ga合金兼具优良的磁致伸缩与机械性能,作为新一代磁致伸缩材料,在传感器、换能器和执行器中有巨大的应用潜力。为了提高超高频磁场下的功能期间的转换效率,需要制备出具有<001>取向的大磁致伸缩的Fe–Ga合金薄带。微量Tb元素掺杂被认为可同时提高Fe–Ga合金的磁致伸缩性能与塑性,但微量Tb元素掺杂对Fe–Ga合金薄带的微结构和磁致伸缩性能的影响机制并不清晰。本文通过比较Fe–Ga与Fe–Ga–Tb合金薄带的析出相、织构和纳米夹杂物的特征演变,系统研究了微量Tb添加对Fe–Ga合金薄带二次再结晶和磁致伸缩性能的影响机制。结果表明,微量Tb元素添加可加速Goss织构的二次再结晶,归因于初次再结晶中呈双峰尺寸特征分布的析出相、细晶和更多的高能晶界的共同作用。合金薄带经900°C淬火后,0.07at% Tb掺杂导致Fe81Ga19合金薄带磁致伸缩系数提升30%。磁致伸缩值的显著增加归因于淬火后微量Tb元素溶固溶引起的富Tb析出相数量的减少和纳米级Modified-D03异质相密度的增加。研究结果表明,通过添加微量稀土元素和传统轧制方法相结合,可高效制备具有大磁致伸缩系数Fe–Ga合金薄带, 这是一种简单且高效的方法。

 

Multiple impacts of trace Tb addition on the secondary recrystallization and magnetostriction of Fe–Ga thin sheet

Abstract: Fe–Ga sheets with large magnetostriction are required for improving the conversion efficiency under the ultra-high frequency magnetic field. Trace Tb element doping can simultaneously improve the magnetostriction and ductility of Fe–Ga alloy. However, the impact of trace Tb doping on the microstructure and magnetostriction of Fe–Ga thin sheets is an open question. In this paper, the effects of trace Tb addition on the secondary recrystallization and magnetostriction of Fe–Ga thin sheets are systematically studied by comparing the characteristics evolution of precipitation, texture, and nanoinclusions. The results indicate that trace Tb addition accelerates the secondary recrystallization of Goss texture due to the combined action of the bimodal size distributed precipitates, smaller grains, and more HEGBs in primary recrystallization. After quenching at 900°C, the magnetostriction value in 0.07at%Tb-doped Fe81Ga19 thin sheets increases by 30% to that of Fe81Ga19 thin sheets. The increase in magnetostriction is attributed to the decrease in the number of Tb-rich precipitates and the higher density of the nanometer-sized modified-D03 inclusions induced by the dissolving of trace Tb elements after quenching. These results demonstrate a simple and efficient approach for preparing Fe–Ga thin sheets with a large magnetostrictive coefficient by a combination of trace RE element addition and conventional rolling method.

 

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