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Boyang Fu, Maciej Moździerz, Andrzej Kulka, and Konrad Świerczek, Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp.2345-2367. https://dx.doi.org/10.1007/s12613-024-2948-y
Boyang Fu, Maciej Moździerz, Andrzej Kulka, and Konrad Świerczek, Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp.2345-2367. https://dx.doi.org/10.1007/s12613-024-2948-y
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富镍层状氧化物及锂离子电池正极材料研究进展

摘要: 毫无疑问,近年来富镍层状正极材料的巨大进步对于推动锂离子电池(LIB)技术的发展至关重要。在能量密度、可循环性、充电速度、降低成本以及安全性和稳定性方面取得的进步,已经为LIB的广泛采用做出了贡献,如今它已从移动电子产品、电动工具和电动汽车扩展到新的应用范围,包括电网存储解决方案等。因为大量关于富镍氧化物的论文和广泛的综述已经发表了,本综述更多地关注参考文献中提出的最新进展和新思想。本文涵盖的主题包括掺杂和成分优化,先进涂层,浓度梯度和单晶材料,以及新电解质及其改性的创新和富镍阴极在固态电池中的应用。文章简要介绍了相关的正极材料,并提出了高熵方法和零应变概念。对尚未解决的问题进行了批判性的概述,并对进一步的研究方向和预期的成果提出了看法。

 

Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells

Abstract: Undoubtedly, the enormous progress observed in recent years in the Ni-rich layered cathode materials has been crucial in terms of pushing boundaries of the Li-ion battery (LIB) technology. The achieved improvements in the energy density, cyclability, charging speed, reduced costs, as well as safety and stability, already contribute to the wider adoption of LIBs, which extends nowadays beyond mobile electronics, power tools, and electric vehicles, to the new range of applications, including grid storage solutions. With numerous published papers and broad reviews already available on the subject of Ni-rich oxides, this review focuses more on the most recent progress and new ideas presented in the literature references. The covered topics include doping and composition optimization, advanced coating, concentration gradient and single crystal materials, as well as innovations concerning new electrolytes and their modification, with the application of Ni-rich cathodes in solid-state batteries also discussed. Related cathode materials are briefly mentioned, with the high-entropy approach and zero-strain concept presented as well. A critical overview of the still unresolved issues is given, with perspectives on the further directions of studies and the expected gains provided.

 

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