富镍层状氧化物及锂离子电池正极材料研究进展

Boyang Fu; Maciej Moździerz; Andrzej Kulka; Konrad Świerczek

doi:10.1007/s12613-024-2948-y

Volume 31 Issue 11

Nov. 2024

Turn off MathJax

图(12) / 表(4)

数据统计

计量

文章访问数: 436
HTML全文浏览量: 184
PDF下载量: 59
被引次数: 0

文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(11): 2345-2367

Boyang Fu, Maciej Moździerz, Andrzej Kulka, and Konrad Świerczek, Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2345-2367. https://doi.org/10.1007/s12613-024-2948-y

Cite this article as:

Boyang Fu, Maciej Moździerz, Andrzej Kulka, and Konrad Świerczek, Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2345-2367. https://doi.org/10.1007/s12613-024-2948-y

Citation:

PDF( 3475 KB)

引用本文 PDF XML SpringerLink

综述Open Access

富镍层状氧化物及锂离子电池正极材料研究进展

1)
Faculty of Energy and Fuels, AGH University of Krakow, al. A. Mickiewicza 30, 30-059 Krakow, Poland
2)
AGH Centre of Energy, AGH University of Krakow, ul. Czarnowiejska 36, 30-054 Krakow, Poland

通讯作者:
Konrad Świerczek E-mail: xi@agh.edu.pl

中文摘要

毫无疑问，近年来富镍层状正极材料的巨大进步对于推动锂离子电池(LIB)技术的发展至关重要。在能量密度、可循环性、充电速度、降低成本以及安全性和稳定性方面取得的进步，已经为LIB的广泛采用做出了贡献，如今它已从移动电子产品、电动工具和电动汽车扩展到新的应用范围，包括电网存储解决方案等。因为大量关于富镍氧化物的论文和广泛的综述已经发表了，本综述更多地关注参考文献中提出的最新进展和新思想。本文涵盖的主题包括掺杂和成分优化，先进涂层，浓度梯度和单晶材料，以及新电解质及其改性的创新和富镍阴极在固态电池中的应用。文章简要介绍了相关的正极材料，并提出了高熵方法和零应变概念。对尚未解决的问题进行了批判性的概述，并对进一步的研究方向和预期的成果提出了看法。

关键词:

ReviewOpen Access

Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells

+ Author Affiliations

1)
Faculty of Energy and Fuels, AGH University of Krakow, al. A. Mickiewicza 30, 30-059 Krakow, Poland
2)
AGH Centre of Energy, AGH University of Krakow, ul. Czarnowiejska 36, 30-054 Krakow, Poland

Konrad Świerczek is the Executive Editor-in-Chief of this journal and was not involved in the editorial review or the decision to publish this article. All authors declare that they have no conflicts of interest.
Open Access Funding provided by the Poland ICM.
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licensee, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/ by/4.0/.

Corresponding author:
Konrad Świerczek E-mail: xi@agh.edu.pl
Received: 23 March 2024; Revised: 27 May 2024; Accepted: 31 May 2024; Available online: 4 June 2024

Abstract

Abstract

Undoubtedly, the enormous progress observed in recent years in the Ni-rich layered cathode materials has been crucial in terms of pushing boundaries of the Li-ion battery (LIB) technology. The achieved improvements in the energy density, cyclability, charging speed, reduced costs, as well as safety and stability, already contribute to the wider adoption of LIBs, which extends nowadays beyond mobile electronics, power tools, and electric vehicles, to the new range of applications, including grid storage solutions. With numerous published papers and broad reviews already available on the subject of Ni-rich oxides, this review focuses more on the most recent progress and new ideas presented in the literature references. The covered topics include doping and composition optimization, advanced coating, concentration gradient and single crystal materials, as well as innovations concerning new electrolytes and their modification, with the application of Ni-rich cathodes in solid-state batteries also discussed. Related cathode materials are briefly mentioned, with the high-entropy approach and zero-strain concept presented as well. A critical overview of the still unresolved issues is given, with perspectives on the further directions of studies and the expected gains provided.
- lithium-ion batteries;
- cathode materials;
- nickel-rich layered oxides;
- recent progress;
- critical issues;
- improvement strategies

FullText(HTML)

Supplements(0)

References(194)

References

[1]	S.C. Jiao, J.Y. Wang, Y.S. Hu, X.Q. Yu, and H. Li, High-capacity oxide cathode beyond 300 mAh/g, ACS Energy Lett., 8(2023), No. 7, p. 3025. doi: 10.1021/acsenergylett.3c00563
[2]	Y.K. Sun, High-capacity layered cathodes for next-generation electric vehicles, ACS Energy Lett., 4(2019), No. 5, p. 1042. doi: 10.1021/acsenergylett.9b00652
[3]	J.J. Xu, X.Y. Cai, S.M. Cai, et al., High-energy lithium-ion batteries: Recent progress and a promising future in applications, Energy Environ. Mater., 6(2023), No. 5, art. No. e12450. doi: 10.1002/eem2.12450
[4]	A. Aishova, G.T. Park, C.S. Yoon, and Y.K. Sun, Cobalt-free high-capacity Ni-rich layered Li[Ni_0.9Mn_0.1]O₂ cathode, Adv. Energy Mater., 10(2020), No. 4, art. No. 1903179. doi: 10.1002/aenm.201903179
[5]	J.R. Dahn, U.V. Sacken, and C.A. Michal, Structure and electrochemistry of Li_{1± y}NiO₂ and a new Li₂NiO₂ phase with the Ni(OH)₂ structure, Solid State Ionics, 44(1990), No. 1-2, p. 87. doi: 10.1016/0167-2738(90)90049-W
[6]	H.H. Ryu, N.Y. Park, J.H. Seo, et al., A highly stabilized Ni-rich NCA cathode for high-energy lithium-ion batteries, Mater. Today, 36(2020), p. 73. doi: 10.1016/j.mattod.2020.01.019
[7]	L.S. Li, Z. Zhang, S.H. Fu, Z.Z. Liu, and Y.M. Liu, Co-modification by LiAlO₂-coating and Al-doping for LiNi_0.5Co_0.2Mn_0.3O₂ as a high-performance cathode material for lithium-ion batteries with a high cutoff voltage, J. Alloys Compd., 768(2018), p. 582. doi: 10.1016/j.jallcom.2018.07.223
[8]	T. Ohzuku and Y. Makimura, Layered lithium insertion material of LiCo_1/3Ni_1/3Mn_1/3O₂ for lithium-ion batteries, Chem. Lett., 30(2001), No. 7, p. 642. doi: 10.1246/cl.2001.642
[9]	J.G. Gao, Z.P. Qin, G.Y. Zhao, et al., Modulating NCM622 electrode to efficiently boost the lithium storage and thermal safety of its full batteries, Energy Storage Mater., 67(2024), art. No. 103332. doi: 10.1016/j.ensm.2024.103332
[10]	S.L. Wang, S.M. Chen, W.Q. Gao, L.L. Liu, and S.J. Zhang, A new additive 3-Isocyanatopropyltriethoxysilane to improve electrochemical performance of Li/NCM622 half-cell at high voltage, J. Power Sources, 423(2019), p. 90. doi: 10.1016/j.jpowsour.2019.03.046
[11]	Z.S. Wang, C.L. Zhu, J.D. Liu, et al., Catalytically induced robust inorganic-rich cathode electrolyte interphase for 4.5 V Li\|\|NCM622 batteries, Adv. Funct. Mater., 33(2023), No. 19, art. No. 2212150. doi: 10.1002/adfm.202212150
[12]	G. Salitra, E. Markevich, M. Afri, et al., High-performance cells containing lithium metal anodes, LiNi_0.6Co_0.2Mn_0.2O₂ (NCM 622) cathodes, and fluoroethylene carbonate-based electrolyte solution with practical loading, ACS Appl. Mater. Interfaces, 10(2018), No. 23, p. 19773. doi: 10.1021/acsami.8b07004
[13]	K.J. Park, M.J. Choi, F. Maglia, et al., High-capacity concentration gradient Li[Ni_0.865Co_0.120Al_0.015]O₂ cathode for lithium-ion batteries, Adv. Energy Mater., 8(2018), No. 19, art. No. 1703612. doi: 10.1002/aenm.201703612
[14]	C.M. Julien and A. Mauger, NCA, NCM811, and the route to Ni-richer lithium-ion batteries, Energies, 13(2020), No. 23, art. No. 6363. doi: 10.3390/en13236363
[15]	F. Reuter, A. Baasner, J. Pampel, et al., Importance of capacity balancing on the electrochemical performance of Li[Ni_0.8Co_0.1Mn_0.1]O₂ (NCM811)/silicon full cells, J. Electrochem. Soc., 166(2019), No. 14, p. A3265. doi: 10.1149/2.0431914jes
[16]	H.L. Zhang and J.J. Zhang, An overview of modification strategies to improve LiNi_0.8Co_0.1Mn_.1O₂ (NCM811) cathode performance for automotive lithium-ion batteries, eTransportation, 7(2021), art. No. 100105. doi: 10.1016/j.etran.2021.100105
[17]	L.H. Zhang, F.Q. Min, Y. Luo, et al., Practical 4.4 V Li\|\|NCM811 batteries enabled by a thermal stable and HF free carbonate-based electrolyte, Nano Energy, 96(2022), art. No. 107122. doi: 10.1016/j.nanoen.2022.107122
[18]	M.Y. Zhang, C.Y. Wang, J.K. Zhang, G. Li, and L. Gu, Preparation and electrochemical characterization of La and Al co-doped NCM811 cathode materials, ACS Omega, 6(2021), No. 25, p. 16465. doi: 10.1021/acsomega.1c01552
[19]	Y.Z. Zheng, N.B. Xu, S.J. Chen, et al., Construction of a stable LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) cathode interface by a multifunctional organosilicon electrolyte additive, ACS Appl. Energy Mater., 3(2020), No. 3, p. 2837. doi: 10.1021/acsaem.9b02486
[20]	W.D. Li, X.M. Liu, Q. Xie, Y. You, M.F. Chi, and A. Manthiram, Long-term cyclability of NCM-811 at high voltages in lithium-ion batteries: An In-depth diagnostic study, Chem. Mater., 32(2020), No. 18, p. 7796. doi: 10.1021/acs.chemmater.0c02398
[21]	S.S. Zhang, Understanding of performance degradation of LiNi_0.80Co_0.10Mn_0.10O₂ cathode material operating at high potentials, J. Energy Chem., 41(2020), p. 135. doi: 10.1016/j.jechem.2019.05.013
[22]	M.H. Kim, H.S. Shin, D. Shin, and Y.K. Sun, Synthesis and electrochemical properties of Li[Ni_0.8Co_0.1Mn_0.1]O₂ and Li[Ni_0.8Co_0.2]O₂ via co-precipitation, J. Power Sources, 159(2006), No. 2, p. 1328. doi: 10.1016/j.jpowsour.2005.11.083
[23]	Y. Cheng, X.Z. Zhang, Q.Y. Leng, et al., Boosting electrochemical performance of Co-free Ni-rich cathodes by combination of Al and high-valence elements, Chem. Eng. J., 474(2023), art. No. 145869. doi: 10.1016/j.cej.2023.145869
[24]	W.B. Hua, J.L. Zhang, S.N. Wang, et al., Long-range cationic disordering induces two distinct degradation pathways in Co-free Ni-rich layered cathodes, Angew. Chem. Int. Ed., 62(2023), No. 12, art. No. e202214880. doi: 10.1002/anie.202214880
[25]	H. Li, L. Wang, Y.Z. Song, et al., Understanding the insight mechanism of chemical-mechanical degradation of layered Co-free Ni-rich cathode materials: A review, Small, 19(2023), No. 32, art. No. 2302208. doi: 10.1002/smll.202302208
[26]	N. Li, S. Sallis, J.K. Papp, B.D. McCloskey, W.L. Yang, and W. Tong, Correlating the phase evolution and anionic redox in Co-Free Ni-Rich layered oxide cathodes, Nano Energy, 78(2020), art. No. 105365. doi: 10.1016/j.nanoen.2020.105365
[27]	A. Liu, N. Zhang, J.E. Stark, P. Arab, H.Y. Li, and J.R. Dahn, Synthesis of Co-free Ni-rich single crystal positive electrode materials for lithium ion batteries: Part I. two-step lithiation method for Al- or Mg-doped LiNiO₂, J. Electrochem. Soc., 168(2021), No. 4, art. No. 040531. doi: 10.1149/1945-7111/abf7e8
[28]	J.J. Liu, Y.F. Yuan, J.H. Zheng, et al., Understanding the synthesis kinetics of single-crystal Co-free Ni-rich cathodes, Angew. Chem. Int. Ed., 62(2023), No. 20, art. No. e202302547. doi: 10.1002/anie.202302547
[29]	T.C. Liu, L. Yu, J.J. Liu, et al., Understanding Co roles towards developing Co-free Ni-rich cathodes for rechargeable batteries, Nat. Energy, 6(2021), No. 3, p. 277. doi: 10.1038/s41560-021-00776-y
[30]	L.S. Ni, R.T. Guo, S.S. Fang, et al., Crack-free single-crystalline Co-free Ni-rich LiNi_0.95Mn_0.05O₂ layered cathode, eScience, 2(2022), No. 1, p. 116. doi: 10.1016/j.esci.2022.02.006
[31]	Y.L. Liu, P.H. Xiao, G.A. Botton, et al., Tungsten infused grain boundaries enabling universal performance enhancement of Co-free Ni-rich cathode materials, J. Electrochem. Soc., 168(2021), No. 12, art. No. 120514. doi: 10.1149/1945-7111/ac3c26
[32]	N. Voronina, Y.K. Sun, and S.T. Myung, Co-free layered cathode materials for high energy density lithium-ion batteries, ACS Energy Lett., 5(2020), No. 6, p. 1814. doi: 10.1021/acsenergylett.0c00742
[33]	C. Wang, L. Tan, H.L. Yi, et al., Unveiling the impact of residual Li conversion and cation ordering on electrochemical performance of Co-free Ni-rich cathodes, Nano Res., 15(2022), No. 10, p. 9038. doi: 10.1007/s12274-022-4889-0
[34]	Y.K. Xi, M.J. Wang, L. Xu, et al., A new Co-free Ni-rich LiNi_0.8Fe_0.1Mn_0.1O₂ cathode for low-cost Li-ion batteries, ACS Appl. Mater. Interfaces, 13(2021), No. 48, p. 57341. doi: 10.1021/acsami.1c18303
[35]	J.U. Choi, N. Voronina, Y.K. Sun, and S.T. Myung, Recent progress and perspective of advanced high-energy Co-less Ni-rich cathodes for Li-ion batteries: Yesterday, today, and tomorrow, Adv. Energy Mater., 10(2020), No. 42, art. No. 2002027. doi: 10.1002/aenm.202002027
[36]	S. Jamil, G. Wang, M. Fasehullah, and M.W. Xu, Challenges and prospects of nickel-rich layered oxide cathode material, J. Alloys Compd., 909(2022), art. No. 164727. doi: 10.1016/j.jallcom.2022.164727
[37]	L.S. Li, D.M. Wang, G.J. Xu, et al., Recent progress on electrolyte functional additives for protection of nickel-rich layered oxide cathode materials, J. Energy Chem., 65(2022), p. 280. doi: 10.1016/j.jechem.2021.05.049
[38]	Y. Lu, Y.D. Zhang, Q. Zhang, F.Y. Cheng, and J. Chen, Recent advances in Ni-rich layered oxide particle materials for lithium-ion batteries, Particuology, 53(2020), p. 1. doi: 10.1016/j.partic.2020.09.004
[39]	H.H. Ryu, H.H. Sun, S.T. Myung, C.S. Yoon, and Y.K. Sun, Reducing cobalt from lithium-ion batteries for the electric vehicle era, Energy Environ. Sci., 14(2021), No. 2, p. 844. doi: 10.1039/D0EE03581E
[40]	C. Xu, P.J. Reeves, Q. Jacquet, and C.P. Grey, Phase behavior during electrochemical cycling of Ni-rich cathode materials for Li-ion batteries, Adv. Energy Mater., 11(2021), No. 7, art. No. 2003404. doi: 10.1002/aenm.202003404
[41]	S.S. Zhang, Problems and their origins of Ni-rich layered oxide cathode materials, Energy Storage Mater., 24(2020), p. 247. doi: 10.1016/j.ensm.2019.08.013
[42]	A. Chakraborty, S. Kunnikuruvan, S. Kumar, et al., Layered cathode materials for lithium-ion batteries: Review of computational studies on LiNi_{1– x– y}Co_xMn_yO₂ and LiNi_{1– x– y}Co_xAl_yO₂, Chem. Mater., 32(2020), No. 3, p. 915. doi: 10.1021/acs.chemmater.9b04066
[43]	J. Yang, X.H. Liang, H.H. Ryu, C.S. Yoon, and Y.K. Sun, Ni-rich layered cathodes for lithium-ion batteries: From challenges to the future, Energy Storage Mater., 63(2023), art. No. 102969. doi: 10.1016/j.ensm.2023.102969
[44]	S. Lee, L.S. Su, A. Mesnier, Z.H. Cui, and A. Manthiram, Cracking vs. surface reactivity in high-nickel cathodes for lithium-ion batteries, Joule, 7(2023), No. 11, p. 2430. doi: 10.1016/j.joule.2023.09.006
[45]	Z.H. Cui and A. Manthiram, Thermal stability and outgassing behaviors of high-nickel cathodes in lithium-ion batteries, Angew. Chem. Int. Ed., 62(2023), No. 43, art. No. e202307243. doi: 10.1002/anie.202307243
[46]	Z.Z. Cui, X. Li, X.Y. Bai, X.D. Ren, and X. Ou, A comprehensive review of foreign-ion doping and recent achievements for nickel-rich cathode materials, Energy Storage Mater., 57(2023), p. 14. doi: 10.1016/j.ensm.2023.02.003
[47]	Y. Kim, H. Park, J.H. Warner, and A. Manthiram, Unraveling the intricacies of residual lithium in high-Ni cathodes for lithium-ion batteries, ACS Energy Lett., 6(2021), No. 3, p. 941. doi: 10.1021/acsenergylett.1c00086
[48]	B.Y. Fu, A. Kulka, B. Wang, et al., Ni-rich LiNi_0.905Co_0.043Al_0.052O₂ cathode material for high-energy density Li-ion cells: Tuning lithium content, structural evolution, and full-cell performance, Electrochim. Acta, 494(2024), art. No. 144455. doi: 10.1016/j.electacta.2024.144455
[49]	M. Liu, Y. Jiang, Y.P. Qin, Z.J. Feng, D.Y. Wang, and B.K. Guo, Enhanced electrochemical performance of Ni-rich cathodes by neutralizing residual lithium with acid compounds, ACS Appl. Mater. Interfaces, 13(2021), No. 46, p. 55072. doi: 10.1021/acsami.1c16482
[50]	M. Jiang, D.L. Danilov, R.A. Eichel, and P.H.L. Notten, A review of degradation mechanisms and recent achievements for Ni-rich cathode-based Li-ion batteries, Adv. Energy Mater., 11(2021), No. 48, art. No. 2103005. doi: 10.1002/aenm.202103005
[51]	B. Aktekin, M.J. Lacey, T. Nordh, et al., Understanding the capacity loss in LiNi_0.5Mn_1.5O₄–Li₄Ti₅O₁₂ lithium-ion cells at ambient and elevated temperatures, J. Phys. Chem. C, 122(2018), No. 21, p. 11234. doi: 10.1021/acs.jpcc.8b02204
[52]	M. Dixit, B. Markovsky, F. Schipper, D. Aurbach, and D.T. Major, Origin of structural degradation during cycling and low thermal stability of Ni-rich layered transition metal-based electrode materials, J. Phys. Chem. C, 121(2017), No. 41, p. 22628. doi: 10.1021/acs.jpcc.7b06122
[53]	H.J. Noh, S. Youn, C.S. Yoon, and Y.K. Sun, Comparison of the structural and electrochemical properties of layered Li[Ni_xCo_yMn_z]O₂ (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries, J. Power Sources, 233(2013), p. 121. doi: 10.1016/j.jpowsour.2013.01.063
[54]	D. Leanza, M. Mirolo, C.A.F. Vaz, P. Novák, and M. El Kazzi, Surface degradation and chemical electrolyte oxidation induced by the oxygen released from layered oxide cathodes in Li-ion batteries, Batter. Supercaps, 2(2019), No. 5, p. 482. doi: 10.1002/batt.201800126
[55]	J.T. Zhao, Y. Liang, X. Zhang, et al. , In situ construction of uniform and robust cathode–electrolyte interphase for Li-rich layered oxides, Adv. Funct. Mater., 31(2021), No. 8, art. No. 2009192. doi: 10.1002/adfm.202009192
[56]	W.M. Dose, I. Temprano, J.P. Allen, et al., Electrolyte reactivity at the charged Ni-rich cathode interface and degradation in Li-ion batteries, ACS Appl. Mater. Interfaces, 14(2022), No. 11, p. 13206. doi: 10.1021/acsami.1c22812
[57]	R. Jung, M. Metzger, F. Maglia, C. Stinner, and H.A. Gasteiger, Oxygen release and its effect on the cycling stability of LiNi_xMn_yCo_zO₂(NMC) cathode materials for Li-ion batteries, J. Electrochem. Soc., 164(2017), No. 7, p. A1361. doi: 10.1149/2.0021707jes
[58]	S.M. Bak, E.Y. Hu, Y.N. Zhou, et al., Structural changes and thermal stability of charged LiNi_xMn_yCo_zO₂ cathode materials studied by combined in situ time-resolved XRD and mass spectroscopy, ACS Appl. Mater. Interfaces, 6(2014), No. 24, p. 22594. doi: 10.1021/am506712c
[59]	S.K. Jung, H. Gwon, J. Hong,et al., Understanding the degradation mechanisms of LiNi_0.5Co_0.2Mn_0.3O₂ cathode material in lithium ion batteries, Adv. Energy Mater., 4(2014), No. 1, art. No. 1300787. doi: 10.1002/aenm.201300787
[60]	K.W. Nam, S.M. Bak, E.Y. Hu, et al., Combining in situ synchrotron X-ray diffraction and absorption techniques with transmission electron microscopy to study the origin of thermal instability in overcharged cathode materials for lithium-ion batteries, Adv. Funct. Mater., 23(2013), No. 8, p. 1047. doi: 10.1002/adfm.201200693
[61]	H. Li, P.F. Zhou, F.M. Liu, H.X. Li, F.Y. Cheng, and J. Chen, Stabilizing nickel-rich layered oxide cathodes by magnesium doping for rechargeable lithium-ion batteries, Chem. Sci., 10(2018), No. 5, p. 1374.
[62]	J.H. Kim, H.H. Ryu, S.J. Kim, C.S. Yoon, and Y.K. Sun, Degradation mechanism of highly Ni-rich Li[Ni_xCo_yMn_{1– x– y}]O₂ cathodes with x > 0.9, ACS Appl. Mater. Interfaces, 11(2019), No. 34, p. 30936. doi: 10.1021/acsami.9b09754
[63]	A.O. Kondrakov, A. Schmidt, J. Xu, et al., Anisotropic lattice strain and mechanical degradation of high- and low-nickel NCM cathode materials for Li-ion batteries, J. Phys. Chem. C, 121(2017), No. 6, p. 3286. doi: 10.1021/acs.jpcc.6b12885
[64]	G.W. Nam, N.Y. Park, K.J. Park, et al., Capacity fading of Ni-rich NCA cathodes: Effect of microcracking extent, ACS Energy Lett., 4(2019), No. 12, p. 2995. doi: 10.1021/acsenergylett.9b02302
[65]	H.H. Ryu, B. Namkoong, J.H. Kim, I. Belharouak, C.S. Yoon, and Y.K. Sun, Capacity fading mechanisms in Ni-rich single-crystal NCM cathodes, ACS Energy Lett., 6(2021), No. 8, p. 2726. doi: 10.1021/acsenergylett.1c01089
[66]	D.J. Miller, C. Proff, J.G. Wen, D.P. Abraham, and J. Bareño, Observation of microstructural evolution in Li battery cathode oxide particles by in situ electron microscopy, Adv. Energy Mater., 3(2013), No. 8, p. 1098. doi: 10.1002/aenm.201300015
[67]	K.J. Park, J.Y. Hwang, H.H. Ryu, et al., Degradation mechanism of Ni-enriched NCA cathode for lithium batteries: Are microcracks really critical?, ACS Energy Lett., 4(2019), No. 6, p. 1394. doi: 10.1021/acsenergylett.9b00733
[68]	H.H. Ryu, K.J. Park, C.S. Yoon, and Y.K. Sun, Capacity fading of Ni-rich Li[Ni_xCo_yMn_{1– x– y}]O₂ (0.6≤x≤0.95) cathodes for high-energy-density lithium-ion batteries: Bulk or surface degradation?, Chem. Mater., 30(2018), No. 3, p. 1155. doi: 10.1021/acs.chemmater.7b05269
[69]	A. Manthiram, A.V. Murugan, A. Sarkar, and T. Muraliganth, Nanostructured electrode materials for electrochemical energy storage and conversion, Energy Environ. Sci., 1(2008), No. 6, p. 621. doi: 10.1039/b811802g
[70]	I. Nakai, K. Takahashi, Y. Shiraishi, T. Nakagome, and F. Nishikawa, Study of the Jahn-Teller distortion in LiNiO₂ , a cathode material in a rechargeable lithium battery, by in situ X-ray absorption fine structure analysis, J. Solid State Chem., 140(1998), No. 1, p. 145. doi: 10.1006/jssc.1998.7943
[71]	P. Kalyani and N. Kalaiselvi, Various aspects of LiNiO₂ chemistry: A review, Sci. Technol. Adv. Mater., 6(2005), No. 6, p. 689. doi: 10.1016/j.stam.2005.06.001
[72]	A. Rougier, I. Saadoune, P. Gravereau, P. Willmann, and C. Delmasa, Effect of cobalt substitution on cationic distribution in LiNi_{1– y}Co_yO₂ electrode materials, Solid State Ionics, 90(1996), No. 1-4, p. 83. doi: 10.1016/S0167-2738(96)00370-0
[73]	Z.H. Lu, D.D. MacNeil, and J.R. Dahn, Layered Li[Ni_xCo_{1–2 x}Mn_x]O₂ cathode materials for lithium-ion batteries, Electrochem. Solid-State Lett., 4(2001), No. 12, p. A200. doi: 10.1149/1.1413182
[74]	U.H. Kim, L.Y. Kuo, P. Kaghazchi, C.S. Yoon, and Y.K. Sun, Quaternary layered Ni-rich NCMA cathode for lithium-ion batteries, ACS Energy Lett., 4(2019), No. 2, p. 576. doi: 10.1021/acsenergylett.8b02499
[75]	K. Kang and G. Ceder, Factors that affect Li mobility in layered lithium transition metal oxides, Phys. Rev. B, 74(2006), No. 9, art. No. 094105. doi: 10.1103/PhysRevB.74.094105
[76]	R.R. Zhao, Z.L. Yang, J.X. Liang, et al., Understanding the role of Na-doping on Ni-rich layered oxide LiNi_0.5Co_0.2Mn_0.3O₂, J. Alloys Compd., 689(2016), p. 318. doi: 10.1016/j.jallcom.2016.07.230
[77]	T. He, L. Chen, Y.F. Su, et al., The effects of alkali metal ions with different ionic radii substituting in Li sites on the electrochemical properties of Ni-rich cathode materials, J. Power Sources, 441(2019), art. No. 227195. doi: 10.1016/j.jpowsour.2019.227195
[78]	Z.C. Ye, L. Qiu, W. Yang, et al., Nickel-rich layered cathode materials for lithium-ion batteries, Chemistry, 27(2021), No. 13, p. 4249. doi: 10.1002/chem.202003987
[79]	R.P. Qing, J.L. Shi, D.D. Xiao, et al., Enhancing the kinetics of Li-rich cathode materials through the pinning effects of gradient surface Na⁺ doping, Adv. Energy Mater., 6(2016), No. 6, art. No. 1501914. doi: 10.1002/aenm.201501914
[80]	M.M. Chen, E.Y. Zhao, D.F. Chen, et al., Decreasing Li/Ni disorder and improving the electrochemical performances of Ni-rich LiNi_0.8Co_0.1Mn_0.1O₂ by Ca doping, Inorg. Chem., 56(2017), No. 14, p. 8355. doi: 10.1021/acs.inorgchem.7b01035
[81]	K. Kang, Y.S. Meng, J. Breger, C.P. Grey, and G. Ceder, Electrodes with high power and high capacity for rechargeable lithium batteries, ChemInform, 311(2006), No. 5763, p. 977.
[82]	E.J. Wu, P.D. Tepesch, and G. Ceder, Size and charge effects on the structural stability of LiMO₂ (M=transition metal) compounds, Philos. Mag. B, 77(1998), No. 4, p. 1039.
[83]	L.S. Ni, H.Y. Chen, J.Q. Gao, et al., Calcium-induced pinning effect for high-performance Co-free Ni-rich NMA layered cathode, Nano Energy, 115(2023), art. No. 108743. doi: 10.1016/j.nanoen.2023.108743
[84]	A. Rajkamal and H. Kim, Formation of pillar-ions in the Li layer decreasing the Li/Ni disorder and improving the structural stability of cation-doped Ni-rich LiNi_0.8Co_0.1Mn_0.1O₂: A first-principles verification, ACS Appl. Energy Mater., 4(2021), No. 12, p. 14068. doi: 10.1021/acsaem.1c02837
[85]	Y.D. Zhang, J.D. Liu, W.C. Xu, et al., Gradient doping Mg and Al to stabilize Ni-rich cathode materials for rechargeable lithium-ion batteries, J. Power Sources, 535(2022), art. No. 231445. doi: 10.1016/j.jpowsour.2022.231445
[86]	H.F. Yu, H.W. Zhu, Z.F. Yang, M.M. Liu, H. Jiang, and C.Z. Li, Bulk Mg-doping and surface polypyrrole-coating enable high-rate and long-life for Ni-rich layered cathodes, Chem. Eng. J., 412(2021), art. No. 128625. doi: 10.1016/j.cej.2021.128625
[87]	C.L. Xu, W. Xiang, Z.G. Wu, et al., Dual-site lattice modification regulated cationic ordering for Ni-rich cathode towards boosted structural integrity and cycle stability, Chem. Eng. J., 403(2021), art. No. 126314. doi: 10.1016/j.cej.2020.126314
[88]	A. D’Epifanio, F. Croce, F. Ronci, V. Rossi Albertini, E. Traversa, and B. Scrosati, Effect of Mg²⁺ doping on the structural, thermal, and electrochemical properties of LiNi_0.8Co_0.16Mg_0.04O₂, Chem. Mater., 16(2004), No. 18, p. 3559. doi: 10.1021/cm040130x
[89]	C. Pouillerie, F. Perton, P. Biensan, J.P. Pérès, M. Broussely, and C. Delmas, Effect of magnesium substitution on the cycling behavior of lithium nickel cobalt oxide, J. Power Sources, 96(2001), No. 2, p. 293. doi: 10.1016/S0378-7753(00)00653-4
[90]	J.S. Kim, S. Lim, H. Munakata, S.S. Kim, and K. Kanamura, Understanding the relationship of electrochemical properties and structure of microstructure-controlled core shell gradient type Ni-rich cathode material by single particle measurement, Electrochim. Acta, 390(2021), art. No. 138813. doi: 10.1016/j.electacta.2021.138813
[91]	C.C. Chang, J.Y. Kim, and P.N. Kumta, Synthesis and electrochemical characterization of divalent cation-incorporated lithium nickel oxide, J. Electrochem. Soc., 147(2000), No. 5, p. 1722. doi: 10.1149/1.1393424
[92]	B. Ammundsen, J. Paulsen, I. Davidson, et al., Local structure and first cycle redox mechanism of layered Li_1.2Cr_0.4Mn_0.4O₂ cathode material, J. Electrochem. Soc., 149(2002), No. 4, p. A431. doi: 10.1149/1.1456535
[93]	L.J. Li, Z.X. Wang, Q.C. Liu, C. Ye, Z.Y. Chen, and L. Gong, Effects of chromium on the structural, surface chemistry and electrochemical of layered LiNi_{0.8− x}Co_0.1Mn_0.1Cr_xO₂, Electrochim. Acta, 77(2012), p. 89. doi: 10.1016/j.electacta.2012.05.076
[94]	C.X. Zhang, S. Xu, B. Han, et al., Towards rational design of high performance Ni-rich layered oxide cathodes: The interplay of borate-doping and excess lithium, J. Power Sources, 431(2019), p. 40. doi: 10.1016/j.jpowsour.2019.05.048
[95]	L.C. Pan, Y.G. Xia, B. Qiu, et al., Structure and electrochemistry of B doped Li(Li_0.2Ni_0.13Co_0.13Mn_0.54)_{1− x}B_xO₂ as cathode materials for lithium-ion batteries, J. Power Sources, 327(2016), p. 273. doi: 10.1016/j.jpowsour.2016.07.064
[96]	K.J. Park, H.G. Jung, L.Y. Kuo, P. Kaghazchi, C.S. Yoon, and Y.K. Sun, Improved cycling stability of Li[Ni_0.90Co_0.05Mn_0.05]O₂ through microstructure modification by boron doping for Li-ion batteries, Adv. Energy Mater., 8(2018), No. 25, art. No. 1801202. doi: 10.1002/aenm.201801202
[97]	X. Liu, G.L. Xu, L. Yin, et al., Probing the thermal-driven structural and chemical degradation of Ni-rich layered cathodes by Co/Mn exchange, J. Am. Chem. Soc., 142(2020), No. 46, p. 19745. doi: 10.1021/jacs.0c09961
[98]	W.W. Yan, S.Y. Yang, Y.Y. Huang, Y. Yang, and G.H. Yuan, A review on doping/coating of nickel-rich cathode materials for lithium-ion batteries, J. Alloys Compd., 819(2020), art. No. 153048. doi: 10.1016/j.jallcom.2019.153048
[99]	F.X. Xin, H. Zhou, Y.X. Zong, et al., What is the role of Nb in nickel-rich layered oxide cathodes for lithium-ion batteries?, ACS Energy Lett., 6(2021), No. 4, p. 1377.
[100]	B. Wang, H.L. Zhao, F.P. Cai, et al., Surface engineering with ammonium niobium oxalate: A multifunctional strategy to enhance electrochemical performance and thermal stability of Ni-rich cathode materials at 4.5V cutoff potential, Electrochim. Acta, 403(2022), art. No. 139636. doi: 10.1016/j.electacta.2021.139636
[101]	M. Wang, Y.Q. Han, M. Chu, L. Chen, M. Liu, and Y.J. Gu, Enhanced electrochemical performances of cerium-doped Li-Rich Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ cathode materials, J. Alloys Compd., 861(2021), art. No. 158000. doi: 10.1016/j.jallcom.2020.158000
[102]	T. Thien Nguyen, U.H. Kim, C.S. Yoon, and Y.K. Sun, Enhanced cycling stability of Sn-doped Li[Ni_0.90Co_0.05Mn_0.05]O₂ via optimization of particle shape and orientation, Chem. Eng. J., 405(2021), art. No. 126887. doi: 10.1016/j.cej.2020.126887
[103]	L. Cheng, Y.N. Zhou, B. Zhang, et al., High-rate Ni-rich single-crystal cathodes with highly exposed {010} active planes through in-situ Zr doping, Chem. Eng. J., 452(2023), art. No. 139336. doi: 10.1016/j.cej.2022.139336
[104]	B. Wang, F.P. Cai, C.X. Chu, et al., Modification of the Ni-rich layered cathode material by Hf addition: Synergistic microstructural engineering and surface stabilization, ACS Appl. Mater. Interfaces, 16(2024), No. 10, p. 12599. doi: 10.1021/acsami.3c18865
[105]	S.Q. Liu, B.Y. Wang, X. Zhang, S. Zhao, Z.H. Zhang, and H.J. Yu, Reviving the lithium-manganese-based layered oxide cathodes for lithium-ion batteries, Matter, 4(2021), No. 5, p. 1511. doi: 10.1016/j.matt.2021.02.023
[106]	X. Li, W.J. Ge, K.K. Zhang, G.C. Peng, Y.X. Fu, and X.G. Ma, Comprehensive study of tantalum doping on morphology, structure, and electrochemical performance of Ni-rich cathode materials, Electrochim. Acta, 403(2022), art. No. 139653. doi: 10.1016/j.electacta.2021.139653
[107]	C.X. Mei, F.H. Du, L. Wu, et al., Stabilization of crystal and interfacial structure of Ni-rich cathode material by vanadium-doping, J. Colloid Interface Sci., 617(2022), p. 193. doi: 10.1016/j.jcis.2022.03.004
[108]	Z.P. Qiu, Y.L. Zhang, Z. Liu, Y. Gao, J.M. Liu, and Q.G. Zeng, Stabilizing Ni-rich LiNi_0.92Co_0.06Al_0.02O₂ cathodes by boracic polyanion and tungsten cation co-doping for high-energy lithium-ion batteries, ChemElectroChem, 7(2020), No. 18, p. 3811. doi: 10.1002/celc.202000927
[109]	T. Sattar, S.H. Lee, B.S. Jin, and H.S. Kim, Influence of Mo addition on the structural and electrochemical performance of Ni-rich cathode material for lithium-ion batteries, Sci. Rep., 10(2020), No. 1, art. No. 8562. doi: 10.1038/s41598-020-64546-8
[110]	A. Gomez-Martin, F. Reissig, L. Frankenstein, et al., Magnesium substitution in Ni-rich NMC layered cathodes for high-energy lithium ion batteries, Adv. Energy Mater., 12(2022), No. 8, art. No. 2103045. doi: 10.1002/aenm.202103045
[111]	H.H. Sun, T.P. Pollard, O. Borodin, K. Xu, and J.L. Allen, Degradation of high nickel Li-ion cathode materials induced by exposure to fully-charged state and its mitigation, Adv. Energy Mater., 13(2023), No. 18, art. No. 2204360. doi: 10.1002/aenm.202204360
[112]	G.T. Park, B. Namkoong, S.B. Kim, J. Liu, C.S. Yoon, and Y.K. Sun, Introducing high-valence elements into cobalt-free layered cathodes for practical lithium-ion batteries, Nat. Energy, 7(2022), p. 946. doi: 10.1038/s41560-022-01106-6
[113]	X.Y. Zhang, P.P. Zhang, T.Y. Zeng, et al., Improving the structure stability of LiNi_0.8Co_0.15Al_0.05O₂ by double modification of tantalum surface coating and doping, ACS Appl. Energy Mater., 4(2021), No. 8, p. 8641. doi: 10.1021/acsaem.1c01811
[114]	L.S. Li, Z. Zhang, S.H. Fu, and Z.Z. Liu, F127-assisted synthesis of LiNi_0.5Co_0.2Mn_0.3O_1.99F_0.01 as a high rate and long lifespan cathode material for lithium-ion batteries, Appl. Surf. Sci., 476(2019), p. 1061. doi: 10.1016/j.apsusc.2019.01.160
[115]	X.L. Liu, S. Wang, L. Wang, et al., Stabilizing the high-voltage cycle performance of LiNi_0.8Co_0.1Mn_0.1O₂ cathode material by Mg doping, J. Power Sources, 438(2019), art. No. 227017. doi: 10.1016/j.jpowsour.2019.227017
[116]	Z.H. Cui, Q. Xie, and A. Manthiram, Zinc-doped high-nickel, low-cobalt layered oxide cathodes for high-energy-density lithium-ion batteries, ACS Appl. Mater. Interfaces, 13(2021), No. 13, p. 15324. doi: 10.1021/acsami.1c01824
[117]	H. Gu, Y. Mu, S.T. Zhang, et al., Enhanced thermal safety and rate capability of nickel-rich cathodes via optimal Nb-doping strategy, Electrochim. Acta, 487(2024), art. No. 144216. doi: 10.1016/j.electacta.2024.144216
[118]	N.Y. Park, G. Cho, S.B. Kim, and Y.K. Sun, Multifunctional doping strategy to develop high-performance Ni-rich cathode material, Adv. Energy Mater., 13(2023), No. 14, art. No. 2204291. doi: 10.1002/aenm.202204291
[119]	H.H. Ryu, H.W. Lim, S.G. Lee, and Y.K. Sun, Optimization of molybdenum-doped Ni-rich layered cathodes for long-term cycling, Energy Storage Mater., 59(2023), art. No. 102771. doi: 10.1016/j.ensm.2023.102771
[120]	R. Zhang, C.Y. Wang, P.C. Zou, et al., Compositionally complex doping for zero-strain zero-cobalt layered cathodes, Nature, 610(2022), No. 7930, p. 67. doi: 10.1038/s41586-022-05115-z
[121]	B.K. Yu, Y.Q. Wang, J.Q. Li, et al., Recent advances on low-Co and Co-free high entropy layered oxide cathodes for lithium-ion batteries, Nanotechnology, 34(2023), No. 45, art. No. 452501. doi: 10.1088/1361-6528/acec4f
[122]	J.B. Wang, Y.Y. Cui, Q.S. Wang, et al., Lithium containing layered high entropy oxide structures, Sci. Rep., 10(2020), No. 1, art. No. 18430. doi: 10.1038/s41598-020-75134-1
[123]	J. Sturman, C.H. Yim, E.A. Baranova, and Y. Abu-Lebdeh, Communication—Design of LiNi_0.2Mn_0.2Co_0.2Fe_0.2Ti_0.2O₂ as a high-entropy cathode for lithium-ion batteries guided by machine learning, J. Electrochem. Soc., 168(2021), No. 5, art. No. 050541. doi: 10.1149/1945-7111/ac00f4
[124]	K.D. Wang, K. Nishio, K. Horiba, et al., Synthesis of high-entropy layered oxide epitaxial thin films: LiCr_1/6Mn_1/6Fe_1/6Co_1/6Ni_1/6Cu_1/6O₂, Cryst. Growth Des., 22(2022), No. 2, p. 1116. doi: 10.1021/acs.cgd.1c01076
[125]	T. Kawaguchi, X. Bian, T. Hatakeyama, H.Y. Li, and T. Ichitsubo, Influences of enhanced entropy in layered rocksalt oxide cathodes for lithium-ion batteries, ACS Appl. Energy Mater., 5(2022), No. 4, p. 4369. doi: 10.1021/acsaem.1c03968
[126]	J. Song, F.H. Ning, Y.X. Zuo, et al., Entropy stabilization strategy for enhancing the local structural adaptability of Li-rich cathode materials, Adv. Mater., 35(2023), No. 7, art. No. 2208726. doi: 10.1002/adma.202208726
[127]	Z.Y. Lun, B. Ouyang, D.H. Kwon, et al., Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries, Nat. Mater., 20(2021), No. 2, p. 214. doi: 10.1038/s41563-020-00816-0
[128]	S.Y. Zhou, Y.X. Sun, T. Gao, J.H. Liao, S.X. Zhao, and G.Z. Cao, Enhanced Li⁺ diffusion and lattice oxygen stability by the high entropy effect in disordered-rocksalt cathodes, Angew. Chem. Int. Ed., 62(2023), No. 42, art. No. e202311930. doi: 10.1002/anie.202311930
[129]	X.Y. Zhao and G. Ceder, Zero-strain cathode materials for Li-ion batteries, Joule, 6(2022), No. 12, p. 2683. doi: 10.1016/j.joule.2022.11.012
[130]	X.Y. Zhao, Y.S. Tian, Z.Y. Lun, et al., Design principles for zero-strain Li-ion cathodes, Joule, 6(2022), No. 7, p. 1654. doi: 10.1016/j.joule.2022.05.018
[131]	I. Konuma, D. Goonetilleke, N. Sharma, et al., A near dimensionally invariable high-capacity positive electrode material, Nat. Mater., 22(2023), No. 2, p. 225. doi: 10.1038/s41563-022-01421-z
[132]	A. Bano, M. Noked, and D.T. Major, Theoretical insights into high-entropy Ni-rich layered oxide cathodes for low-strain Li-ion batteries, Chem. Mater., 35(2023), No. 20, p. 8426. doi: 10.1021/acs.chemmater.3c01182
[133]	D.C. Chen, J. Ahn, and G.Y. Chen, An overview of cation-disordered lithium-excess rocksalt cathodes, ACS Energy Lett., 6(2021), No. 4, p. 1358.
[134]	R.J. Clément, Z. Lun, and G. Ceder, Cation-disordered rocksalt transition metal oxides and oxyfluorides for high energy lithium-ion cathodes, Energy Environ. Sci., 13(2020), No. 2, p. 345. doi: 10.1039/C9EE02803J
[135]	K. Zhou, Y.N. Li, Y. Ha, et al., A nearly zero-strain Li-rich rock-salt oxide with multielectron redox reactions as a cathode for Li-ion batteries, Chem. Mater., 34(2022), No. 21, p. 9711. doi: 10.1021/acs.chemmater.2c02519
[136]	J. Lee, A. Urban, X. Li, D. Su, G. Hautier, and G. Ceder, Unlocking the potential of cation-disordered oxides for rechargeable lithium batteries, Science, 343(2014), No. 6170, p. 519. doi: 10.1126/science.1246432
[137]	M. Nakajima and N. Yabuuchi, Lithium-excess cation-disordered rocksalt-type oxide with nanoscale phase segregation: Li_1.25Nb_0.25V_0.5O₂, Chem. Mater., 29(2017), No. 16, p. 6927. doi: 10.1021/acs.chemmater.7b02343
[138]	R.J. Qi, I. Konuma, B.D.L. Campéon, Y. Kaneda, M. Kondo, and N. Yabuuchi, Highly graphitic carbon coating on Li_1.25Nb_0.25V_0.5O₂ derived from a precursor with a perylene core for high-power battery applications, Chem. Mater., 34(2022), No. 4, p. 1946. doi: 10.1021/acs.chemmater.1c04426
[139]	C. Zhan, T.P. Wu, J. Lu, and K. Amine, Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes–A critical review, Energy Environ. Sci., 11(2018), No. 2, p. 243. doi: 10.1039/C7EE03122J
[140]	W.S. Li, Review—An unpredictable hazard in lithium-ion batteries from transition metal ions: Dissolution from cathodes, deposition on anodes and elimination strategies, J. Electrochem. Soc., 167(2020), No. 9, art. No. 090514. doi: 10.1149/1945-7111/ab847f
[141]	G.J. Ross, J.F. Watts, M.P. Hill, and P. Morrissey, Surface modification of poly(vinylidene fluoride) by alkaline treatment 1. The degradation mechanism, Polymer, 41(2000), No. 5, p. 1685. doi: 10.1016/S0032-3861(99)00343-2
[142]	Y. You, H. Celio, J.Y. Li, A. Dolocan, and A. Manthiram, Modified high-nickel cathodes with stable surface chemistry against ambient air for lithium-ion batteries, Angew. Chem. Int. Ed., 57(2018), No. 22, p. 6480. doi: 10.1002/anie.201801533
[143]	M.J. Herzog, N. Gauquelin, D. Esken, J. Verbeeck, and J. Janek, Facile dry coating method of high-nickel cathode material by nanostructured fumed alumina (Al₂O₃) improving the performance of lithium-ion batteries, Energy Technol., 9(2021), No. 4, art. No. 2100028. doi: 10.1002/ente.202100028
[144]	D.Z. Hu, Y.F. Su, L. Chen, et al., The mechanism of side reaction induced capacity fading of Ni-rich cathode materials for lithium ion batteries, J. Energy Chem., 58(2021), p. 1. doi: 10.1016/j.jechem.2020.09.031
[145]	L.T. Dou, P. Hu, C.Q. Shang, et al., Enhanced electrochemical performance of LiNi_0.8Co_0.1Mn_0.1O₂ with SiO₂ surface coating via homogeneous precipitation, ChemElectroChem, 8(2021), No. 22, p. 4321. doi: 10.1002/celc.202101230
[146]	Y.Y. Li, X.F. Li, J.H. Hu, et al., ZnO interface modified LiNi_0.6Co_0.2Mn_0.2O₂ toward boosting lithium storage, Energy Environ. Mater., 3(2020), No. 4, p. 522. doi: 10.1002/eem2.12080
[147]	Q.L. Fan, K.J. Lin, S.D. Yang, et al., Constructing effective TiO₂ nano-coating for high-voltage Ni-rich cathode materials for lithium ion batteries by precise kinetic control, J. Power Sources, 477(2020), art. No. 228745. doi: 10.1016/j.jpowsour.2020.228745
[148]	Y.R. Bak, Y. Chung, J.H. Ju, M.J. Hwang, Y. Lee, and K.S. Ryu, Structure and electrochemical performance of LiNi_0.8Co_0.15Al_0.05O₂ cathodes before and after treatment with Co₃(PO₄)₂ or AlPO₄ by in situ chemical method, J. New Mater. Electrochem. Syst., 14(2011), No. 4, p. 203. doi: 10.14447/jnmes.v14i4.90
[149]	D.J. Lee, B. Scrosati, and Y.K. Sun, Ni₃(PO₄)₂-coated Li[Ni_0.8Co_0.15Al_0.05]O₂ lithium battery electrode with improved cycling performance at 55°C, J. Power Sources, 196(2011), No. 18, p. 7742. doi: 10.1016/j.jpowsour.2011.04.007
[150]	Y.Q. Chu, Y.B. Mu, L.F. Zou, et al., Thermodynamically stable dual-modified LiF&FeF₃ layer empowering Ni-rich cathodes with superior cyclabilities, Adv. Mater., 35(2023), No. 21, art. No. 2212308. doi: 10.1002/adma.202212308
[151]	G.R. Hu, X.Y. Qi, K.H. Hu, et al., A facile cathode design with a LiNi_0.6Co_0.2Mn_0.2O₂ core and an AlF₃-activated Li_1.2Ni_0.2Mn_0.6O₂ shell for Li-ion batteries, Electrochim. Acta, 265(2018), p. 391. doi: 10.1016/j.electacta.2018.01.176
[152]	K.S. Ryu, S.H. Lee, and Y.J. Park, Electrochemical properties of LiNi_0.8Co_0.16Al_0.04O₂ and surface modification with Co₃(PO₄)₂ as cathode materials for lithium battery, Bull. Korean Chem. Soc., 29(2008), No. 9, p. 1737. doi: 10.5012/bkcs.2008.29.9.1737
[153]	Z.K. Zhao, S. Chen, D.B. Mu, et al., Understanding the surface decoration on primary particles of nickel-rich layered LiNi_0.6Co_0.2Mn_0.2O₂ cathode material with lithium phosphate, J. Power Sources, 431(2019), p. 84. doi: 10.1016/j.jpowsour.2019.05.046
[154]	Q.M. Gan, N. Qin, Z.Y. Wang, et al., Revealing mechanism of Li₃PO₄ coating suppressed surface oxygen release for commercial Ni-rich layered cathodes, ACS Appl. Energy Mater., 3(2020), No. 8, p. 7445. doi: 10.1021/acsaem.0c00859
[155]	J.L. Fu, D.B. Mu, B.R. Wu, et al., Enhanced electrochemical performance of LiNi_0.6Co_0.2Mn_0.2O₂ cathode at high cutoff voltage by modifying electrode/electrolyte interface with lithium metasilicate, Electrochim. Acta, 246(2017), p. 27. doi: 10.1016/j.electacta.2017.06.038
[156]	D. Wang, X.H. Li, Z.X. Wang, et al., Multifunctional Li₂O–2B₂O₃ coating for enhancing high voltage electrochemical performances and thermal stability of layered structured LiNi_0.5Co_0.2Mn_0.3O₂ cathode materials for lithium ion batteries, Electrochim. Acta, 174(2015), p. 1225. doi: 10.1016/j.electacta.2015.06.111
[157]	C.C. Zhang, S.Y. Liu, J.M. Su, et al., Revealing the role of NH₄VO₃ treatment in Ni-rich cathode materials with improved electrochemical performance for rechargeable lithium-ion batteries, Nanoscale, 10(2018), No. 18, p. 8820. doi: 10.1039/C8NR01707G
[158]	M.H. Park, M. Noh, S.H. Lee, et al., Flexible high-energy Li-ion batteries with fast-charging capability, Nano Lett., 14(2014), No. 7, p. 4083. doi: 10.1021/nl501597s
[159]	K. Sahni, M. Ashuri, Q.R. He, et al., H₃PO₄ treatment to enhance the electrochemical properties of Li(Ni_1/3Mn_1/3Co_1/3)O₂ and Li(Ni_0.5Mn_0.3Co_0.2)O₂ cathodes, Electrochim. Acta, 301(2019), p. 8. doi: 10.1016/j.electacta.2019.01.153
[160]	X.H. Xiong, D. Ding, Y.F. Bu, et al., Enhanced electrochemical properties of a LiNiO₂-based cathode material by removing lithium residues with (NH₄)₂HPO₄, J. Mater. Chem. A, 2(2014), No. 30, p. 11691. doi: 10.1039/C4TA01282H
[161]	G. Kaur and B.D. Gates, Review-surface coatings for cathodes in lithium ion batteries: From crystal structures to electrochemical performance, J. Electrochem. Soc., 169(2022), No. 4, art. No. 043504. doi: 10.1149/1945-7111/ac60f3
[162]	X.Y. Qu, H. Huang, T. Wan, et al., An integrated surface coating strategy to enhance the electrochemical performance of nickel-rich layered cathodes, Nano Energy, 91(2022), art. No. 106665. doi: 10.1016/j.nanoen.2021.106665
[163]	L.F. Wang, G.C. Liu, R. Wang, et al., Regulating surface oxygen activity by perovskite-coating-stabilized ultrahigh-nickel layered oxide cathodes, Adv. Mater., 35(2023), No. 11, art. No. 2209483. doi: 10.1002/adma.202209483
[164]	H. Sheng, X.H. Meng, D.D. Xiao, et al., An air-stable high-nickel cathode with reinforced electrochemical performance enabled by convertible amorphous Li₂CO₃ modification, Adv. Mater., 34(2022), No. 12, art. No. 2108947. doi: 10.1002/adma.202108947
[165]	Y.B. Shen, X.Y. Zhang, L.C. Wang, et al., A universal multifunctional rare earth oxide coating to stabilize high-voltage lithium layered oxide cathodes, Energy Storage Mater., 56(2023), p. 155. doi: 10.1016/j.ensm.2023.01.015
[166]	X.Y. Zheng, R.H. Yu, J. Sun, et al., Precursor-oriented ultrathin Zr-based gradient coating on Ni-riched cathodes, Nano Energy, 105(2023), art. No. 108000. doi: 10.1016/j.nanoen.2022.108000
[167]	Z.H. Chen, Y. Qin, K. Amine, and Y.K. Sun, Role of surface coating on cathode materials for lithium-ion batteries, J. Mater. Chem., 20(2010), No. 36, p. 7606. doi: 10.1039/c0jm00154f
[168]	J.H. Shim, Y.M. Kim, M. Park, J. Kim, and S.H. Lee, Reduced graphene oxide-wrapped nickel-rich cathode materials for lithium ion batteries, ACS Appl. Mater. Interfaces, 9(2017), No. 22, p. 18720. doi: 10.1021/acsami.7b02654
[169]	Y. Yoon, S. Shin, and M.W. Shin, Fundamental understanding of the effect of a polyaniline coating layer on cation mixing and chemical states of LiNi_0.9Co_0.085Mn_0.015O₂ for Li-ion batteries, ACS Appl. Polym. Mater., 5(2023), No. 2, p. 1344. doi: 10.1021/acsapm.2c01872
[170]	B.Z. You, Z.X. Wang, F. Shen, et al., Research progress of single-crystal nickel-rich cathode materials for lithium ion batteries, Small Meth., 5(2021), No. 8, art. No. 2100234. doi: 10.1002/smtd.202100234
[171]	H. Huang, L.P. Zhang, H.Y. Tian, et al., Pulse high temperature sintering to prepare single-crystal high nickel oxide cathodes with enhanced electrochemical performance, Adv. Energy Mater., 13(2023), No. 3, art. No. 2203188. doi: 10.1002/aenm.202203188
[172]	A.H. Ran, S.X. Chen, M. Cheng, et al., A single-crystal nickel-rich material as a highly stable cathode for lithium-ion batteries, J. Mater. Chem. A, 10(2022), No. 37, p. 19680. doi: 10.1039/D2TA01186G
[173]	J.T. Hu, L.Z. Li, Y.J. Bi, et al., Locking oxygen in lattice: A quantifiable comparison of gas generation in polycrystalline and single crystal Ni-rich cathodes, Energy Storage Mater., 47(2022), p. 195. doi: 10.1016/j.ensm.2022.02.025
[174]	X.B. Kong, Y.G. Zhang, J.Y. Li, et al., Single-crystal structure helps enhance the thermal performance of Ni-rich layered cathode materials for lithium-ion batteries, Chem. Eng. J., 434(2022), art. No. 134638. doi: 10.1016/j.cej.2022.134638
[175]	A. Neubrand and J. Rödel, Gradient materials: An overview of a novel concept, Int. J. Mater. Res., 88(2021), No. 5, p. 358.
[176]	P.Y. Hou, H.Z. Zhang, Z.Y. Zi, L.Q. Zhang, and X.J. Xu, Core–shell and concentration-gradient cathodes prepared via co-precipitation reaction for advanced lithium-ion batteries, J. Mater. Chem. A, 5(2017), No. 9, p. 4254. doi: 10.1039/C6TA10297B
[177]	R. Lin, S.M. Bak, Y. Shin, et al., Hierarchical nickel valence gradient stabilizes high-nickel content layered cathode materials, Nat. Commun., 12(2021), No. 1, art. No. 2350. doi: 10.1038/s41467-021-22635-w
[178]	A. Purwanto, C.S. Yudha, U. Ubaidillah, H. Widiyandari, T. Ogi, and H. Haerudin, NCA cathode material: Synthesis methods and performance enhancement efforts, Mater. Res. Express, 5(2018), No. 12, art. No. 122001. doi: 10.1088/2053-1591/aae167
[179]	D. Aurbach, K. Gamolsky, B. Markovsky, Y. Gofer, M. Schmidt, and U. Heider, On the use of vinylene carbonate (VC) as an additive to electrolyte solutions for Li-ion batteries, Electrochim. Acta, 47(2002), No. 9, p. 1423. doi: 10.1016/S0013-4686(01)00858-1
[180]	R. Dugas, A. Ponrouch, G. Gachot, R. David, M.R. Palacin, and J.M. Tarascon, Na reactivity toward carbonate-based electrolytes: The effect of FEC as additive, J. Electrochem. Soc., 163(2016), No. 10, p. A2333. doi: 10.1149/2.0981610jes
[181]	R. Sahore, A. Tornheim, C. Peebles, et al., Methodology for understanding interactions between electrolyte additives and cathodes: A case of the tris(2, 2, 2-trifluoroethyl)phosphite additive, J. Mater. Chem. A, 6(2018), No. 1, p. 198. doi: 10.1039/C7TA08289D
[182]	A. Hofmann, M. Migeot, E. Thißen, et al., Electrolyte mixtures based on ethylene carbonate and dimethyl sulfone for Li-ion batteries with improved safety characteristics, ChemSusChem, 8(2015), No. 11, p. 1892. doi: 10.1002/cssc.201500263
[183]	K. Beltrop, S. Klein, R. Nölle, et al., Triphenylphosphine oxide as highly effective electrolyte additive for graphite/NMC811 lithium ion cells, Chem. Mater., 30(2018), No. 8, p. 2726. doi: 10.1021/acs.chemmater.8b00413
[184]	B.W. Deng, H. Wang, X. Li, et al., Effects of charge cutoff potential on an electrolyte additive for LiNi_0.6Co_0.2Mn_0.2O₂–mesocarbon microbead full cells, Energy Technol., 7(2019), No. 4, art. No. 1800981. doi: 10.1002/ente.201800981
[185]	Z.Y. Luo, H. Zhang, L. Yu, D.H. Huang, and J.Q. Shen, Improving long-term cyclic performance of LiNi_0.8Co_0.15Al_0.05O₂ cathode by introducing a film forming additive, J. Electroanal. Chem., 833(2019), p. 520. doi: 10.1016/j.jelechem.2018.12.041
[186]	H.Q. Pham, Y.H. Thi Tran, J. Han, and S.W. Song, Roles of nonflammable organic liquid electrolyte in stabilizing the interface of the LiNi_0.8Co_0.1Mn_0.1O₂ cathode at 4.5 V and improving the battery performance, J. Phys. Chem. C, 124(2020), No. 1, p. 175. doi: 10.1021/acs.jpcc.9b09960
[187]	Y.M. Lee, K.M. Nam, E.H. Hwang, et al., Interfacial origin of performance improvement and fade for 4.6 V LiNi_0.5Co_0.2Mn_0.3O₂ battery cathodes, J. Phys. Chem. C, 118(2014), No. 20, p. 10631. doi: 10.1021/jp501670g
[188]	Y. Han, S.H. Jung, H. Kwak, et al., Single- or poly-crystalline Ni-rich layered cathode, sulfide or halide solid electrolyte: Which will be the winners for all-solid-state batteries?, Adv. Energy Mater., 11(2021), No. 21, art. No. 2100126. doi: 10.1002/aenm.202100126
[189]	W. Jiang, X.X. Zhu, R.Z. Huang, et al., Revealing the design principles of Ni-rich cathodes for all-solid-state batteries, Adv. Energy Mater., 12(2022), No. 13, art. No. 2103473. doi: 10.1002/aenm.202103473
[190]	S.H. Jung, U.H. Kim, J.H. Kim, et al., Ni-rich layered cathode materials with electrochemo-mechanically compliant microstructures for all-solid-state Li batteries, Adv. Energy Mater., 10(2020), No. 6, art. No. 1903360. doi: 10.1002/aenm.201903360
[191]	L.S. Li, H.H. Duan, J. Li, L. Zhang, Y.F. Deng, and G.H. Chen, Toward high performance all-solid-state lithium batteries with high-voltage cathode materials: Design strategies for solid electrolytes, cathode interfaces, and composite electrodes, Adv. Energy Mater., 11(2021), No. 28, art. No. 2003154. doi: 10.1002/aenm.202003154
[192]	X.S. Liu, B.Z. Zheng, J. Zhao, et al., Electrochemo-mechanical effects on structural integrity of Ni-rich cathodes with different microstructures in all solid-state batteries, Adv. Energy Mater., 11(2021), No. 8, art. No. 2003583. doi: 10.1002/aenm.202003583
[193]	Y. Ma, J.H. Teo, F. Walther, et al., Advanced nanoparticle coatings for stabilizing layered Ni-rich oxide cathodes in solid-state batteries, Adv. Funct. Mater., 32(2022), No. 23, art. No. 2111829. doi: 10.1002/adfm.202111829
[194]	S.X. Deng, X. Li, Z.H. Ren, et al., Dual-functional interfaces for highly stable Ni-rich layered cathodes in sulfide all-solid-state batteries, Energy Storage Mater., 27(2020), p. 117. doi: 10.1016/j.ensm.2020.01.009

Relative Articles

Cited By

Proportional views

数据统计

姓名
邮箱
手机号码
标题
留言内容
验证码

留言板

数据统计

分享

计量

富镍层状氧化物及锂离子电池正极材料研究进展

中文摘要

Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells

Abstract

References

数据统计

Catalog