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Volume 31 Issue 12
Dec.  2024

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Yanxin Qiao, Tianyu Wang, Zhilin Chen, Jun Wang, Chengtao Li,  and Jian Chen, Corrosion techniques and strategies for used fuel containers with copper corrosion barriers under deep geological disposal conditions: A review, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2582-2606. https://doi.org/10.1007/s12613-024-2949-x
Cite this article as:
Yanxin Qiao, Tianyu Wang, Zhilin Chen, Jun Wang, Chengtao Li,  and Jian Chen, Corrosion techniques and strategies for used fuel containers with copper corrosion barriers under deep geological disposal conditions: A review, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2582-2606. https://doi.org/10.1007/s12613-024-2949-x
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综述

深地质处置条件下乏燃料处置容器用纯铜的腐蚀技术和策略:综述


  • 通讯作者:

    乔岩欣    E-mail: yxqiao@just.edu.cn

    陈健    E-mail: jchen496@uwo.ca

文章亮点

  • (1) 系统介绍了深层地质处置条件下核废料处置容器用纯铜的腐蚀问题;
  • (2) 对目前核废料处置容易用材料的腐蚀检测技术与方法进行了归纳和总结;
  • (3) 对目前国际上核废料处置领域的研究成果进行了调研,并对该领域的发展前景进行了展望。
  • 核能利用产生的高放射性核废料的安全处置是一个十分常见且具有一定挑战性的问题。目前永久处置高放废物的可行方法包括将其装入耐腐蚀容器,然后将其深埋在地质储存库中。在此过程中,研究的重点在于保证容器的耐久性和完整性。本文介绍了在深部地质处置环境下使用铜(Cu)作为腐蚀屏障来控制核废料容器腐蚀的各种技术和策略。总体来说,这些防腐蚀技术和方法已经被应用在实际生产中,并成功地解决了一些铜处置容器在深地质储存库永久处置过程中遇到的腐蚀问题。例如铜的腐蚀机制表现为表面粗糙化;铜涂层缺陷处的腐蚀损伤累计可能导致涂层分层失效;硫化物膜的形态、结构和性质因地下水化学而异等。这篇综述的主要目的是对核废料容器(UFC)在受到深层地质储存库条件影响时所遇到的腐蚀环境变化进行广泛的研究并侧重于解决潜在的腐蚀问题和预测UFC的服役寿命。
  • Review

    Corrosion techniques and strategies for used fuel containers with copper corrosion barriers under deep geological disposal conditions: A review

    + Author Affiliations
    • Safe emplacement of high-level nuclear waste (HLNW) arising from the utilization of nuclear power is a frequently encountered and considerably challenging issue. The widely accepted and feasible approach for the permanent disposal of HLNW involves housing it in a corrosion-resistant container and subsequently burying it deep in a geologic repository. The focus lies on ensuring the durability and integrity of the container in this process. This review introduces various techniques and strategies employed in controlling the corrosion of used fuel containers (UFCs) using copper (Cu) as corrosion barrier in the context of deep geological disposal. Overall, these corrosion prevention techniques and methods have been effectively implemented and employed to successfully mitigate the corrosion challenges encountered during the permanent disposal of Cu containers (e.g., corrosion mechanisms and corrosion parameters) in deep geologic repositories. The primary objective of this review is to provide an extensive examination of the alteration in the corrosion environment encountered by the UFCs when subjected to deep geologic repository conditions and focusing on addressing the potential corrosion scenarios.
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