聚吡咯涂层三层蛋黄壳Fe<sub>2</sub>O<sub>3</sub>负极材料及其在锂离子电池中的卓越综合性能

何震; 刘嘉明; 魏雨倩; 宋云飞; 杨武鑫; 杨奥博; 王宇鑫; 李波

doi:10.1007/s12613-024-2954-0

Volume 31 Issue 12

Dec. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(12): 2737-2748

Zhen He, Jiaming Liu, Yuqian Wei, Yunfei Song, Wuxin Yang, Aobo Yang, Yuxin Wang, and Bo Li, Polypyrrole-coated triple-layer yolk–shell Fe₂O₃ anode materials with their superior overall performance in lithium-ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2737-2748. https://doi.org/10.1007/s12613-024-2954-0

Cite this article as:

Zhen He, Jiaming Liu, Yuqian Wei, Yunfei Song, Wuxin Yang, Aobo Yang, Yuxin Wang, and Bo Li, Polypyrrole-coated triple-layer yolk–shell Fe2O3 anode materials with their superior overall performance in lithium-ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2737-2748. https://doi.org/10.1007/s12613-024-2954-0

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研究论文

聚吡咯涂层三层蛋黄壳Fe₂O₃负极材料及其在锂离子电池中的卓越综合性能

1)
江苏科技大学材料科学与工程学院, 镇江 212000, 中国
2)
Department of Chemical & Materials Engineering, the University of Auckland, Auckland 1010, New Zealand

通讯作者:
王宇鑫 E-mail: ywan943@163.com

李波 E-mail: bli219@aucklanduni.ac.nz

文章亮点

(1) 通过一种创新的原位合成方法成功制备了具有三层蛋黄壳结构的纳米材料

(2) 聚吡咯均匀涂覆层显著提升了其导电性能并增强了整体结构的稳定性

(3) 三层蛋黄壳复合结构能够适应基体在充放电过程中的体积膨胀

(4) 通过电极材料结构优化实现了具有超高稳定性和快速充放电能力

中文摘要

氧化铁(Fe₂O₃)作为一种极具吸引力的阳极候选材料，在迅速扩展的储能市场中崭露头角。然而作为电极材料，它在循环过程中会经历显著的体积变化，导致电池循环寿命大幅缩短。本文创新性地合成了均匀涂覆导电聚吡咯层(Fe₂O₃@Ppy-TLY)的三层蛋黄壳结构Fe₂O₃，为制备高性能Fe₂O₃阳极材料开辟了新途径。均匀的聚吡咯涂层不仅引入了更多的反应位点和吸附位点，还在充放电过程中保持了结构的稳定性。作为锂离子电池的电极材料，Fe₂O₃@Ppy-TLY 展现出卓越的锂存储性能，包括高可逆比容量（在1 C下循环500次后仍能保持1375.11 mAh⋅g⁻¹的放电容量）、优异的循环稳定性（在6000次循环后仍能保持 544.33 mAh⋅g⁻¹），以及优异的大电流充放电性能（在15 C下循环10000次后仍能保持156.75 mAh⋅g⁻¹的可逆容量）。本研究展示了Fe₂O₃阳极设计的创新进展，旨在提升其在储能领域的应用性能。

关键词:

Research Article

Polypyrrole-coated triple-layer yolk–shell Fe₂O₃ anode materials with their superior overall performance in lithium-ion batteries

+ Author Affiliations

Abstract

Abstract

Iron oxide (Fe₂O₃) emerges as a highly attractive anode candidate among rapidly expanding energy storage market. Nonetheless, its considerable volume changes during cycling as an electrode material result in a vast reduced battery cycle life. In this work, an approach is pioneered for preparing high-performance Fe₂O₃ anode materials, by innovatively synthesizing a triple-layer yolk–shell Fe₂O₃ uniformly coated with a conductive polypyrrole (Ppy) layer (Fe₂O₃@Ppy-TLY). The uniform polypyrrole coating introduces more reaction sites and adsorption sites, and maintains structure stability through charge-discharge process. In the uses as lithium-ion battery electrodes, Fe₂O₃@Ppy-TLY demonstrates high reversible specific capacity (maintaining a discharge capacity of 1375.11 mAh·g⁻¹ after 500 cycles at 1 C), exceptional cycling stability (retaining the steady charge-discharge performance at 544.33 mAh·g⁻¹ after 6000 ultrafast charge-discharge cycles at a 10 C current density), and outstanding high current charge-discharge performance (retaining a reversible capacity of 156.75 mAh·g⁻¹ after 10000 cycles at 15 C), thereby exhibiting superior lithium storage performance. This work introduces innovative advancements for Fe₂O₃ anode design, aiming to enhance its performance in energy storage fields.
- Fe₂O₃;
- structure design;
- anode material;
- lithium-ion battery

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References(52)

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聚吡咯涂层三层蛋黄壳Fe₂O₃负极材料及其在锂离子电池中的卓越综合性能

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Polypyrrole-coated triple-layer yolk–shell Fe₂O₃ anode materials with their superior overall performance in lithium-ion batteries

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聚吡咯涂层三层蛋黄壳Fe2O3负极材料及其在锂离子电池中的卓越综合性能

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Polypyrrole-coated triple-layer yolk–shell Fe2O3 anode materials with their superior overall performance in lithium-ion batteries

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聚吡咯涂层三层蛋黄壳Fe₂O₃负极材料及其在锂离子电池中的卓越综合性能

Polypyrrole-coated triple-layer yolk–shell Fe₂O₃ anode materials with their superior overall performance in lithium-ion batteries