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Mehdi Boroujerdnia, and Ali Obeydavi, Effect of nitrogen addition on the structural, mechanical and corrosion properties of FeCoCrMnNiNx high-entropy nitride ceramic thin films, Int. J. Miner. Metall. Mater.,(2025). https://dx.doi.org/10.1007/s12613-024-3037-y
Mehdi Boroujerdnia, and Ali Obeydavi, Effect of nitrogen addition on the structural, mechanical and corrosion properties of FeCoCrMnNiNx high-entropy nitride ceramic thin films, Int. J. Miner. Metall. Mater.,(2025). https://dx.doi.org/10.1007/s12613-024-3037-y
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添加氮对FeCoCrMnNiNx高熵氮化陶瓷薄膜结构、力学和腐蚀性能的影响

摘要: 本文采用磁控溅射法制备了FeCoCrMnNiNx高熵氮化陶瓷薄膜,研究了氮含量对薄膜性能的影响。N2的加入影响了薄膜的微观结构及力学和腐蚀性能。与添加1 sccm N2的FeCoCrMnNi薄膜相比,2 sccm和3 sccm的N2添加量分别达到5.45at%和6.34at%,使固溶体的晶体结构转变为非晶结构。氮的加入引起了表面形态的剧烈变化,形成了一个更光滑、更均匀的表面,不包含花椰菜单元。原子力显微镜图像分析表明,氮的加入使样品表面粗糙度从5.58 nm降低到1.82 nm。在CoCrFeMnNi薄膜中添加N2有助于提高其硬度和强度等力学性能,而杨氏模量则降低。在1 sccm N2条件下,FeCoCrMnNi薄膜由硬度(8.75 ± 0.5)GPa,杨氏模量为(257.37 ± 11.4)GPa,分别达到硬度(12.67±1.2)GPa和杨氏模量(194.39±12.4)GPa。在304SUS上涂覆CoCrFeMnNi薄膜提高了耐腐蚀性,而与不含氮的CoCrFeMnNi薄膜相比,向CoCrFeMonNi薄膜中添加氮也提高了其耐腐蚀性。

 

Effect of nitrogen addition on the structural, mechanical and corrosion properties of FeCoCrMnNiNx high-entropy nitride ceramic thin films

Abstract: FeCoCrMnNiNx high entropy nitride ceramics thin films were prepared using the magnetron sputtering method, and the effects of nitrogen content on the thin films’ properties were later examined. The addition of N2 affected the microstructures of the thin films and their mechanical and corrosion properties. Compared with the FeCoCrMnNi thin films with 1-sccm N2, the addition of 2 and 3 sccm of N2 by as much as 5.45at% and 6.34at% changed the solid solution’s crystalline structure into an amorphous structure. The addition of nitrogen caused drastic changes to the surface morphology, creating a smoother and more uniform surface without cauliflower units. The atomic force microscopy image analysis indicated that the addition of nitrogen reduced the surface roughness from 5.58 to 1.82 nm. Adding N2 to the CoCrFeMnNi thin film helped increase its mechanical properties, such as hardness and strength, while the Young’s modulus decreased. The hardness of (8.75 ± 0.5) GPa and the reduced Young’s modulus of (257.37 ± 11.4) GPa of the FeCoCrMnNi thin film reached (12.67 ± 1.2) and (194.39 ± 12.4) GPa, respectively, with 1 sccm N2. The applied coating of the CoCrFeMnNi thin film on 304SUS increased the corrosion resistance, whereas the addition of nitrogen to the CoCrFeMnNi thin film also improved its corrosion resistance compared with that of the CoCrFeMnNi thin film without nitrogen.

 

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