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Guanzhao Jiang, Liangliang Zhao, Shunchuan Wu, Haiyong Cheng, Wei Sun, and Hong Li, Improvement in workability of new green hemihydrate phosphogypsum-based filling materials: Methods, mechanism, and practice, Int. J. Miner. Metall. Mater., (2025). https://doi.org/10.1007/s12613-024-3082-6
Guanzhao Jiang, Liangliang Zhao, Shunchuan Wu, Haiyong Cheng, Wei Sun, and Hong Li, Improvement in workability of new green hemihydrate phosphogypsum-based filling materials: Methods, mechanism, and practice, Int. J. Miner. Metall. Mater., (2025). https://doi.org/10.1007/s12613-024-3082-6
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新型绿色半水磷石膏充填材料工作性能改善:方法、机理和实践

摘要: 半水磷石膏(HPG)基充填材料已成为低成本早强型绿色充填材料的新选择,并且为磷石膏的规模化利用提供了有前景的解决方案。然而,HPG基充填材料工作性差而引发的堵管事故已成为充填过程中的主要安全隐患。迫切需要一种经济可行的方法来提高HPG充填料浆工作性。首先,本研究发现,在综合分析保水性、流动性和流动稳定性的基础上,HPG粉磨处理比提高浓度(59wt%–65wt%)和添加尾矿(20wt%–100wt%)更高效地提高了HPG料浆工作性。然后,基于微观分析定量描述了颗粒尺寸、颗粒形态、水膜和颗粒间相互作用对HPG料浆工作性的耦合影响。此外,还首次发现了颗粒从坚硬的镶嵌式结构向松软的堆叠结构转变的直接证据。实践中,充填材料应采用粉磨20分钟的HPG与0wt%–200wt%的磷尾矿混合来制备,以此确保HPG充填材料工作性和力学性能令人满意。本研究成果为解决HPG料浆的稳定输送问题提供了实用可行的方法。

 

Improvement in workability of new green hemihydrate phosphogypsum-based filling materials: Methods, mechanism, and practice

Abstract: Hemihydrate phosphogypsum (HPG)-based filling materials have become a new low-cost green alternative for early strength filling materials. They also provide a promising solution for the large-scale utilization of phosphogypsum. However, pipe plugging, which is caused by the poor workability of HPG-based filling materials, has become a major safety hazard in the filling process. Determining an economical and practicable method is urgently needed to improve the workability of HPG slurry work. First, this work found that grinding treatment was much more effective than increasing concentration (59wt%–65wt%) and adding tailings (20wt%–100wt%) in enhancing the workability of HPG slurry based on a comprehensive analysis of water retention, fluidity, and flow stability. Then, the combined effects of particle size, particle morphology, water film, and interparticle interactions on the workability of HPG slurry were quantitatively described through a microanalysis. Moreover, the first direct evidence for the transformation from robust embedded structures to soft stacking structures was presented. In practice, the filling materials should be prepared by grinding HPG for 20 min and mixing with 0wt%–200wt% phosphorus tailings to achieve satisfactory workability and mechanical performance. The results of this study provide practical and feasible methods for addressing the stable transportation problem of HPG slurry.

 

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