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Ying Ren, and Lifeng Zhang, In-situ observation of nonmetallic inclusions in steel using confocal scanning laser microscopy: A review, Int. J. Miner. Metall. Mater.,(2025). https://dx.doi.org/10.1007/s12613-025-3103-0
Ying Ren, and Lifeng Zhang, In-situ observation of nonmetallic inclusions in steel using confocal scanning laser microscopy: A review, Int. J. Miner. Metall. Mater.,(2025). https://dx.doi.org/10.1007/s12613-025-3103-0
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高温共聚焦扫描激光显微镜在钢中非金属夹杂物原位观察中的应用:综述

摘要: 本文综述了利用共聚焦扫描激光显微镜在钢中非金属夹杂物中应用研究,特别是各种夹杂物的碰撞、夹杂物在液态渣中的溶解以及夹杂物与钢液之间的反应。固态夹杂物表现出较高的碰撞倾向,而纯液态夹杂物由于与钢液的接触角小于90°,导致其吸引力较小,碰撞次数极少。复合夹杂物在钢液中的碰撞不在本研究范围内,应在未来的研究中进行评估。液态渣中较高的CaO/Al₂O₃和CaO/SiO₂比值促进了以Al₂O₃为基础的夹杂物溶解。为了提高夹杂物的溶解度,应防止渣中固态相的形成。为了准确模拟夹杂物在液态渣中的溶解,有必要在钢-渣界面进行夹杂物溶解的原位观察。通过结合共聚焦扫描激光显微镜和扫描电子显微镜-能谱仪,观察并分析了夹杂物在钢中溶解元素的改性过程中成分和形态的演变。尽管MnS和TiN析出相的原位观察相关研究已较为广泛,但对钢在凝固和加热过程中氧化物夹杂物演变的原位观察却鲜有报道。温度、加热和冷却速率以及夹杂物特性对针状铁素体形成的影响已广泛研究。在3–5 K/s的冷却速率下,文献报道的不同夹杂物诱导AF生长速率的顺序为:Ti–O < Ti–Ca–Zr–Al–O < Mg–O < Ti–Zr–Al–O < Mn–Ti–Al–O < Ti–Al–O < Zr–Ti–Al–O。

 

In-situ observation of nonmetallic inclusions in steel using confocal scanning laser microscopy: A review

Abstract: The characteristics of nonmetallic inclusions formed during steel production have a significant influence on steel performance. In this paper, studies on inclusions using confocal scanning laser microscopy (CSLM) are reviewed and summarized, particularly the collision of various inclusions, dissolution of inclusions in liquid slag, and reactions between inclusions and steel. Solid inclusions exhibited a high collision tendency, whereas pure liquid inclusions exhibited minimal collisions because of the small attraction force induced by their < 90° contact angle with molten steel. The collision of complex inclusions in molten steel was not included in the scope of this study and should be evaluated in future studies. Higher CaO/Al2O3 and CaO/SiO2 ratios in liquid slag promoted the dissolution of Al2O3-based inclusions. The formation of solid phases in the slag should be prevented to improve dissolution of inclusions. To accurately simulate the dissolution of inclusions in liquid slag, in-situ observation of the dissolution of inclusions at the steel–slag interface is necessary. Using a combination of CSLM and scanning electron microscopy–energy dispersive spectroscopy, the composition and morphological evolution of the inclusions during their modification by the dissolved elements in steel were observed and analyzed. Although the in-situ observation of MnS and TiN precipitations has been widely studied, the in-situ observation of the evolution of oxide inclusions in steel during solidification and heating processes has rarely been reported. The effects of temperature, heating and cooling rates, and inclusion characteristics on the formation of acicular ferrites (AFs) have been widely studied. At a cooling rate of 3–5 K/s, the order of AF growth rate induced by different inclusions, as reported in literature, is Ti–O < Ti–Ca–Zr–Al–O < Mg–O < Ti–Zr–Al–O < Mn–Ti–Al–O < Ti–Al–O < Zr–Ti–Al–O. Further comprehensive experiments are required to investigate the quantitative relationship between the formation of AFs and inclusions.

 

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