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Trygve Lindahl Schanche, Heiko Gaertner, Frida Vollan, Alok Sarkar, Casper van, and der Eijk, Hydrogen reduction of lumpy Nchwaning ore in a fixed-bed reactor, Int. J. Miner. Metall. Mater., (2025). https://doi.org/10.1007/s12613-025-3125-7
Trygve Lindahl Schanche, Heiko Gaertner, Frida Vollan, Alok Sarkar, Casper van, and der Eijk, Hydrogen reduction of lumpy Nchwaning ore in a fixed-bed reactor, Int. J. Miner. Metall. Mater., (2025). https://doi.org/10.1007/s12613-025-3125-7
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块状Nchwaning矿在固定床反应器中的氢还原行为

摘要: 在锰矿石预还原过程中应用氢气,有望替代锰铁合金生产中化石燃料的碳消耗并减少二氧化碳排放。本研究采用固定床反应器,探究了Nchwaning锰矿的预还原行为。通过考察不同温度及不同温度程序下的还原速率,并在还原后对颗粒进行筛分以测定其碎裂程度;还原速率的测定采用向还原气体中添加示踪气体并对尾气进行定量分析的方法。为研究颗粒尺寸对还原速率的影响,对具有不同粒度分布的原料样品进行了还原实验。通过化学分析和X射线衍射技术对原矿及还原产物进行表征,系统探究了粒度分布和温度对脱氧率的影响。结果表明,样品中锰氧化物大多被还原为MnO,而部分铁氧化物及碳酸盐仍未完全反应;减小颗粒尺寸和提高反应温度可显著提升还原程度。

 

Hydrogen reduction of lumpy Nchwaning ore in a fixed-bed reactor

Abstract: The application of hydrogen gas in the pre-reduction of manganese ore may replace fossil carbon consumption and reduce CO2 emissions in manganese ferroalloy production. The pre-reduction behavior of Nchwaning manganese ore was investigated using a fixed-bed reactor. The reduction rates at different temperatures and temperature programs were investigated, and the particles were sieved after reduction to measure the decrepitation. The reduction rate was measured by adding a tracer gas to the reducing gas and quantifying the off-gas. Samples with different particle-size distributions of the input material were reduced to investigate the effect of particle size on the reduction rate. Chemical analyses and X-ray diffraction were used to characterize the raw and reduced materials. The effects of particle size distribution and temperature on the oxygen removal rate were investigated. Manganese oxides were mostly reduced to MnO in the samples, whereas some iron oxides and carbonates remained. The degree of reduction was improved by using smaller particles and increasing the temperature.

 

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