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Yan Liu, Kaiyang Guo, Yuanmeng Ge, Wenzheng Yan, Kai Gu, Yapeng Tian, and Xinwei Cui, Structural engineering of MXenes towards high electrochemical performance in supercapacitors, Int. J. Miner. Metall. Mater., (2025). https://doi.org/10.1007/s12613-025-3146-2
Yan Liu, Kaiyang Guo, Yuanmeng Ge, Wenzheng Yan, Kai Gu, Yapeng Tian, and Xinwei Cui, Structural engineering of MXenes towards high electrochemical performance in supercapacitors, Int. J. Miner. Metall. Mater., (2025). https://doi.org/10.1007/s12613-025-3146-2
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MXene结构工程助力超级电容器高电化学性能的研究进展

摘要: 在多种储能器件中,超级电容器(SCs)因其高功率密度和优异的循环稳定性而备受关注。MXene作为一种新兴的二维材料,凭借其独特的层状结构和丰富的表面官能团,近年来成为研究热点。与其他电极材料相比,MXene具备前驱体可调、结构稳定性高以及优异导电性能等优势,因此在超级电容器中的应用潜力更为突出。然而,MXene材料的倍率性能与电化学反应活性仍存在不足,层间堆叠问题亦严重制约其实际应用。为提升其电化学性能,研究者提出了多种改性策略。由于MXene电极的结构调控通常通过构建离子传输通道以暴露更多活性位点,因此也不可避免地影响其堆积密度。因此,在提升体积比电容的同时实现快速离子传输,成为MXene基超级电容器在可穿戴与微型器件中应用的关键挑战。本文综述了近年来MXene在制备方法和结构调控方面的最新进展,重点探讨如何在保证高体积电容的同时提升离子传输性能,为其在微器件和可穿戴器件中的拓展应用提供理论参考与技术支持。

 

Structural engineering of MXenes towards high electrochemical performance in supercapacitors

Abstract: Supercapacitors (SCs) stand out among various energy storage devices owing to their high power density and long-term cycling stability. As new two-dimensional material, MXenes have become a research hotspot in recent years owing to their unique structure and rich surface functional groups. Compared with other materials, MXenes are more promising for SCs owing to their tunable precursors, structural stability, and excellent electrical conductivity. However, the rate performance and electrochemical reaction activity of MXene materials are poor, and stacking severely limits their application. Therefore, various modification strategies are employed to improve the electrochemical performance of MXene materials. As the modification strategy of MXene electrode materials often involves increasing the number of ion transport channels to expose more active sites, the packing density is also affected to different degrees. Therefore, achieving a balance between high volumetric capacitance and rapid ion transport has become a key issue for the application of MXene-based SCs in wearable devices and microdevices. In this paper, the latest progress in the preparation methods and modification strategies of MXenes in recent years is reviewed with the aim of achieving both high volumetric capacitance and high ion transport for expanding the application of MXene-based SCs in microdevices and wearable devices.

 

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