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Haohang Ji, Shenghui Guo, Lei Gao, Li Yang, Hengwei Yan, and Hongbo Zeng, Revolutionizing titanium production: A comprehensive review of thermochemical and molten salt electrolysis processes, Int. J. Miner. Metall. Mater., (2025). https://doi.org/10.1007/s12613-025-3210-y
Haohang Ji, Shenghui Guo, Lei Gao, Li Yang, Hengwei Yan, and Hongbo Zeng, Revolutionizing titanium production: A comprehensive review of thermochemical and molten salt electrolysis processes, Int. J. Miner. Metall. Mater., (2025). https://doi.org/10.1007/s12613-025-3210-y
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钛生产革命:热化学与熔盐电解工艺的综合评述

摘要: 钛具备高比强度、耐高温、耐低温等卓越性能,被称为未来金属。受制于钛元素活跃的化学活性,钛金属存在制备流程长、生产成本高等问题,被欧盟列入低类别的关键原材料。现行Kroll工艺的奠基人曾经预言,使用熔盐电解的方法将可以低成本的获得金属钛。在2000年左右,熔盐电解制钛迎来了一波技术研发的浪潮。但钛的电解过程中会发生多种中间反应和歧化反应,电解制钛的效率和产品纯度始终难以达到工业化标准。目前,钛金属制备技术的发展脉络逐渐分为热还原、熔盐电解、钛合金制备等研究方向。本文使用Web of Science与Derwent专利库所检索2000年至今的2.3万条数据为样本,采用文献计量+专利挖掘+技术经济模型,对“热还原—熔盐电解—钛合金制备”三大板块进行逐年解析,量化技术热点演化轨迹,总结了现有技术遇到的困难和解决思路,期望能激发业内对于低成本钛制备技术的新一轮讨论及研发潮流。

 

Revolutionizing titanium production: A comprehensive review of thermochemical and molten salt electrolysis processes

Abstract: Titanium exhibits outstanding properties, particularly, high specific strength and resistance to both high and low temperatures, earning it a reputation as the metal of the future. However, because of the highly reactive nature of titanium, metallic titanium production involves extensive procedures and high costs. Considering its advantages and limitations, the European Union has classified titanium metal as a critical raw material (CRM) of low category. The Kroll process is predominantly used to produce titanium; however, molten salt electrolysis (MSE) is currently being explored for producing metallic titanium at a low cost. Since 2000, electrolytic titanium production has undergone a wave of technological advancements. However, because of the intermediate and disproportionation reactions in the electrolytic titanium production process, the process efficiency and titanium purity according to industrial standards could not be achieved. Consequently, metallic titanium production has gradually diversified into employing technologies such as thermal reduction, MSE, and titanium alloy preparation. This study provides a comprehensive review of research advances in titanium metal preparation technologies over the past two decades, highlighting the challenges faced by the existing methods and proposing potential solutions. It offers useful insights into the development of low-cost titanium preparation technologies.

 

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