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Jian Zhu, Shuhao Zhao, Zhen Li, Yi Xu, Shuai Wu, and Xidong Hui, Microstructures, mechanical properties and corrosion resistances of FCC CoCrFeNiTi high-entropy alloys prepared by pre-alloyed powder mixing and vacuum laser-directed energy deposition, Int. J. Miner. Metall. Mater., (2026). https://doi.org/10.1007/s12613-025-3289-1
Jian Zhu, Shuhao Zhao, Zhen Li, Yi Xu, Shuai Wu, and Xidong Hui, Microstructures, mechanical properties and corrosion resistances of FCC CoCrFeNiTi high-entropy alloys prepared by pre-alloyed powder mixing and vacuum laser-directed energy deposition, Int. J. Miner. Metall. Mater., (2026). https://doi.org/10.1007/s12613-025-3289-1
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基于预合金粉末混合和真空激光定向能量沉积工艺制备的 FCC 型 CoCrFeNiTi 多元合金的微观结构、机械性能和耐腐蚀性

摘要: 本研究采用真空激光调控定向能量沉积技术(V-LDED),将等原子比 CoCrFeNi 预合金粉末与 CoCrFeNiTi 粉末进行配比混粉,制备CoCrFeNiTixx = 0.1、0.2、0.3)系列高熵合金(HEAs)。随着Ti添加量升高,高熵合金晶格畸变加剧、晶粒细化、析出相含量增多,但合金仍以面心立方(FCC)晶体结构为主要物相。随Ti元素掺入,合金的强度与塑性呈现先上升后下降的变化趋势。CoCrFeNiTi0.3(Ti0.3)合金综合力学性能最优:拉伸屈服强度604 MPa,抗拉极限强度882 MPa,塑性伸长率13.5%,相较于CoCrFeNi合金,屈服强度提升了124%,抗拉强度提升了83%。CoCrFeNiTi0.2(Ti0.2)合金耐腐蚀性最优,其自腐蚀电位Ecorr、腐蚀电流密度Icorr、界面阻抗Rc、电荷转移阻抗Rct分别为−0.208 V、4.889 × 10−7 A/cm2、7.03 × 103 Ω/cm2、8.50 × 105 Ω/cm2,这是因为Ti元素在CoCrFeNi HEAs中能够增强钝化膜的防护效果。结果表明,Ti的添加对合金耐蚀性能的多重影响机制,主要源于钝化膜的生成行为、组分构成以及析出相的析出密度。

 

Microstructures, mechanical properties and corrosion resistances of FCC CoCrFeNiTi high-entropy alloys prepared by pre-alloyed powder mixing and vacuum laser-directed energy deposition

Abstract: In this study, vacuum laser-engineered directed energy deposition (V-LDED) was employed to fabricate CoCrFeNiTix (x = 0.1, 0.2, 0.3) high-entropy alloys (HEAs) by strategically mixing equiatomic pre-alloyed CoCrFeNi and CoCrFeNiTi powders. With increasing Ti content, the lattice distortion of the HEAs intensified, grains were refined, and precipitate content increased; however, the face-centered cubic (FCC) structure remained the predominant structure. The strength and plasticity of the HEAs initially increased and then decreased with the addition of Ti. The CoCrFeNiTi0.3 (Ti0.3) alloy exhibited the best mechanical properties, with a tensile yield strength (TYS) of 604 MPa, an ultimate tensile strength (UTS) of 882 MPa, and a plastic elongation of 13.5%. Compared to the Ti-free alloy, the TYS and UTS were increased by 124% and 83%, respectively. The CoCrFeNiTi0.2 (Ti0.2) alloy showed the best corrosion resistance with the corrosion potential (Ecorr), corrosion current density (Icorr), passivated film resistor (Rc), and charge transfer resistance (Rct) values of –0.208 V, 4.889 × 10–7 A/cm2, 7.03 × 103 Ω/cm2, and 8.50 × 105 Ω/cm2, respectively. The addition of Ti increased the Cr and Ti contents in the passive film, which are easily passivated elements. The multiple effects of Ti on the corrosion resistance were mainly attributed to the formation and composition of the passive film and density of the precipitates.

 

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