Cite this article as:

Hao Lü, Min Gan, Xiaohui Fan, Hangqi Wen, Zhiyun Ji, Zengqing Sun, Yuncan Cao, and Haorui Li, Reduction swelling behavior of ultra-high-grade pellets for hydrogen-based shaft furnaces and its mitigation strategies, Int. J. Miner. Metall. Mater., (2026). https://doi.org/10.1007/s12613-025-3291-7
Hao Lü, Min Gan, Xiaohui Fan, Hangqi Wen, Zhiyun Ji, Zengqing Sun, Yuncan Cao, and Haorui Li, Reduction swelling behavior of ultra-high-grade pellets for hydrogen-based shaft furnaces and its mitigation strategies, Int. J. Miner. Metall. Mater., (2026). https://doi.org/10.1007/s12613-025-3291-7
引用本文 PDF XML SpringerLink

氢基竖炉用超高品位球团矿还原膨胀行为及其抑制策略

摘要: 超高品位球团矿氢还原对洁净钢和特种钢的生产具有重要意义,但氢还原过程中面临异常膨胀的难题。本文研究了超高品位球团矿的氢还原膨胀行为,提出通过两步还原抑制其异常膨胀。结果表明:超高品位球团矿高温还原速率快,但会发生异常膨胀,还原膨胀指数最高可达99.4%;低温条件下球团矿还原膨胀指数相对较低,但还原时间长。超高品位球团矿异常膨胀发生在浮氏体还原至金属铁阶段,主要归因于颗粒表面铁晶须的生长。在氢还原过程中,采用两步还原可有效抑制铁晶须的产生,促进多孔铁与层状铁生成,从而在保持快速还原的同时将RSI降低至15%以下。其中,第一步还原应在球团矿异常膨胀的临界温度以下进行,且第一步还原后球团矿还原度应达到60%。提高第二步还原温度不会加剧膨胀,反而能够加快球团矿还原速率。

 

Reduction swelling behavior of ultra-high-grade pellets for hydrogen-based shaft furnaces and its mitigation strategies

Abstract: The hydrogen-based reduction of ultra-high-grade pellets is critical for the production of clean and specialty steels but is challenged by abnormal reduction swelling. This study investigates the swelling behavior of ultra-high-grade pellets during hydrogen reduction and proposes a two-step reduction strategy to suppress abnormal swelling. The results show that during high-temperature reduction, ultra-high-grade pellets exhibit rapid reduction rates but undergo abnormal swelling, with the reduction swelling index (RSI) reaching up to 99.4%. While demonstrating a relatively lower RSI at lower reduction temperatures, the pellets require a prolonged reduction duration. The abnormal swelling of ultra-high-grade pellets occurs when FeO is reduced to Fe, primarily attributed to the growth of iron whiskers on particle surfaces. During hydrogen reduction, the two-step reduction strategy effectively suppresses iron whisker formation and promotes the formation of porous and layered iron, reducing RSI to below 15% while maintaining rapid reduction. The first-step reduction should be conducted below the critical temperature for abnormal swelling, with the reduction degree of the pellet attaining 60% after the first-step reduction. Increasing the temperature of the second-step reduction does not exacerbate swelling but instead accelerates the reduction rate.

 

/

返回文章
返回