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Haonan Si, Xuan Zhao, Qingliang Liao, and Yue Zhang, Optical absorption performance of (C4H9NH3)2(CH3NH3)3Pb4I13-based two-dimensional perovskite solar cells with periodic nanostructure, Int. J. Miner. Metall. Mater., (2026). https://doi.org/10.1007/s12613-025-3310-8
Haonan Si, Xuan Zhao, Qingliang Liao, and Yue Zhang, Optical absorption performance of (C4H9NH3)2(CH3NH3)3Pb4I13-based two-dimensional perovskite solar cells with periodic nanostructure, Int. J. Miner. Metall. Mater., (2026). https://doi.org/10.1007/s12613-025-3310-8
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周期性纳米结构调控(C4H9NH3)2(CH3NH3)3Pb4I13二维钙钛矿电池光吸收性能

摘要: 二维层状金属卤化物钙钛矿具有优异的电学、光学性能及良好的稳定性,是极具潜力的光电半导体材料。然而其高折射率特性制约了二维钙钛矿的光吸收性能。本研究利用周期性纳米结构调控二维钙钛矿的光吸收能力,采用时域有限差分法系统分析二维钙钛矿太阳能电池的理论效率。重点探究了晶格排列、结构形貌及几何参数对光吸收性能的影响规律,揭示了二维钙钛矿中周期性纳米结构的光管理机理,阐明了纳米结构与光吸收性能的构效关系,为钙钛矿光电器件性能提升提供了重要的理论指导。

 

Optical absorption performance of (C4H9NH3)2(CH3NH3)3Pb4I13-based two-dimensional perovskite solar cells with periodic nanostructure

Abstract: Two-dimensional layered metal-halide perovskites possess exceptional electronic and optical properties along with remarkable stability, making them a highly promising class of organic–inorganic hybrid semiconductor materials. Owing to their multi-quantum-well structure and high refractive index, effective light management is crucial for optimizing the performance of two-dimensional perovskites. This study utilizes the trapping effect of periodic nanostructures to effectively modulate the light-absorption capacity of two-dimensional perovskites. The theoretical efficiency of two-dimensional perovskite solar cells is systematically analyzed using the finite-difference time-domain method, with a particular focus on the influences of the lattice arrangement, structural morphology, and geometric parameters. Furthermore, the underlying mechanism of light management by periodic nanostructures in two-dimensional perovskites is elucidated, and the structure–property relationship between nanostructures and light-absorption performance is estabished. These findings offer crucial theoretical insights that can guide the enhancement of the performance of perovskite photovoltaic devices.

 

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