Study on sulphide capacity of CaO-SiO2-Al2O3-MgO-FetO slags

Chengli Wang, Qing Lu, Shuhui Zhang, Fumin Li

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    Cite this article as:

    Chengli Wang, Qing Lu, Shuhui Zhang, and Fumin Li, Study on sulphide capacity of CaO-SiO2-Al2O3-MgO-FetO slags, J. Univ. Sci. Technol. Beijing , 13(2006), No. 3, pp.213-217. https://dx.doi.org/10.1016/S1005-8850(06)60045-5
    Chengli Wang, Qing Lu, Shuhui Zhang, and Fumin Li, Study on sulphide capacity of CaO-SiO2-Al2O3-MgO-FetO slags, J. Univ. Sci. Technol. Beijing , 13(2006), No. 3, pp.213-217. https://dx.doi.org/10.1016/S1005-8850(06)60045-5
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    Metallurgy

    Study on sulphide capacity of CaO-SiO2-Al2O3-MgO-FetO slags

    基金项目: 

    This project was financially supported by the National Natural Science Foundation of China (No.50574036) and Natural Science Foun-dation of HeBei Province, China (No.502267).

      通信作者:

      Qing Lu E-mail: lq@heut.edu.cn

    The sulphide capacity of CaO-SiO2-Al2O3-MgO-FetO slags was studied at 1773 K using gas-slag equilibrium techniques. Utilizing a Pt crucible, the slag was equilibrated with a mixture of gases, namely, CO, CO2, SO2 and N2 to provide the partial pressure of oxygen and sulphur. It was shown that at fixed FetO and Al2O3 contents and a fixed {(%CaO)+(%MgO)}/(%SiO2) ratio, the sulphide capacity decreases with increasing MgO content. At a constant (%CaO)/(%SiO2) ratio and constant MgO and Al2O3 contents, increasing the FetO content of the slags also results in an increase of the sulphide capacity. The rising basicity of (%CaO)/(%SiO2) from 1.0 to 1.4 at fixed MgO, FetO and Al2O3 contents significantly increases the sulphide capacity.

     

    Metallurgy

    Study on sulphide capacity of CaO-SiO2-Al2O3-MgO-FetO slags

    Author Affilications
    • Funds: 

      This project was financially supported by the National Natural Science Foundation of China (No.50574036) and Natural Science Foun-dation of HeBei Province, China (No.502267).

    • Received: 16 June 2005;
    The sulphide capacity of CaO-SiO2-Al2O3-MgO-FetO slags was studied at 1773 K using gas-slag equilibrium techniques. Utilizing a Pt crucible, the slag was equilibrated with a mixture of gases, namely, CO, CO2, SO2 and N2 to provide the partial pressure of oxygen and sulphur. It was shown that at fixed FetO and Al2O3 contents and a fixed {(%CaO)+(%MgO)}/(%SiO2) ratio, the sulphide capacity decreases with increasing MgO content. At a constant (%CaO)/(%SiO2) ratio and constant MgO and Al2O3 contents, increasing the FetO content of the slags also results in an increase of the sulphide capacity. The rising basicity of (%CaO)/(%SiO2) from 1.0 to 1.4 at fixed MgO, FetO and Al2O3 contents significantly increases the sulphide capacity.

     

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