Thermoelectric properties of quaternary Mg2Sn0.4Si0.6-xGex alloys

Hao Yin, Xin-Bing Zhao, Qian Zhang, Tie-Jun Zhu

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    Cite this article as:

    Hao Yin, Xin-Bing Zhao, Qian Zhang, and Tie-Jun Zhu, Thermoelectric properties of quaternary Mg2Sn0.4Si0.6-xGex alloys, Int. J. Miner. Metall. Mater., 16(2009), No. 5, pp.564-567. https://dx.doi.org/10.1016/S1674-4799(09)60097-2
    Hao Yin, Xin-Bing Zhao, Qian Zhang, and Tie-Jun Zhu, Thermoelectric properties of quaternary Mg2Sn0.4Si0.6-xGex alloys, Int. J. Miner. Metall. Mater., 16(2009), No. 5, pp.564-567. https://dx.doi.org/10.1016/S1674-4799(09)60097-2
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    Materials

    Thermoelectric properties of quaternary Mg2Sn0.4Si0.6-xGex alloys

    基金项目: 

    This work was financially supported by the National Natural Science Foundation of China (No.50522203, 50731006) and the National Basic Research Program of China (No.2007CB607502).

      通信作者:

      Xin-Bing Zhao E-mail: zhaoxb@zju.edu.cn

    Quaternary alloys Mg2Sn0.4Si0.6-xGex (x=0, 0.02, 0.05, 0.08 0.1, and 0.2) were prepared using induction melting followed by hot-pressing. Relative densities of the sintered samples were over 97% of the theoretical values. Multiple phases were detected in the samples. It was found that the Seebeck coefficient was sensitive to the content of Mg2Ge and a maximum value of about 350 μV-K-1 was obtained. The introduction of Ge increases the electrical conductivity and the thermal conductivity simultaneously. The mechanism of this phenomenon was discussed. A maximum dimensionless figure of merit, ZT, of about 0.28 was obtained for Mg2Sn0.4Si0.55Ge0.05 at 550 K.

     

    Materials

    Thermoelectric properties of quaternary Mg2Sn0.4Si0.6-xGex alloys

    Author Affilications
    • Funds: 

      This work was financially supported by the National Natural Science Foundation of China (No.50522203, 50731006) and the National Basic Research Program of China (No.2007CB607502).

    • Received: 07 October 2008;
    Quaternary alloys Mg2Sn0.4Si0.6-xGex (x=0, 0.02, 0.05, 0.08 0.1, and 0.2) were prepared using induction melting followed by hot-pressing. Relative densities of the sintered samples were over 97% of the theoretical values. Multiple phases were detected in the samples. It was found that the Seebeck coefficient was sensitive to the content of Mg2Ge and a maximum value of about 350 μV-K-1 was obtained. The introduction of Ge increases the electrical conductivity and the thermal conductivity simultaneously. The mechanism of this phenomenon was discussed. A maximum dimensionless figure of merit, ZT, of about 0.28 was obtained for Mg2Sn0.4Si0.55Ge0.05 at 550 K.

     

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