摘要:
Kinetics of carbothermic reduction of manganese oxide and the catalyticeffect of La
2O
3 on the reduction have been studied by the measurement of mass loss in N
2 atmosphere at different temperatures and followed by SEM analysis. It is concluded that the kinetics of carbothermic reduction of manganese oxide is divided into three stages:gas diffusion controlling stage, carbon gasification con-trolling stage and solid state diffusion controlling stage. La
2O
3 has catalytic effect on the reduction. The catalytic effect of La
2O
3 increases withthe added amount of La
2O
3. SEM analysis shows that the catalytic mechanism is that La
2O
3promotes the transfer of oxygen ions so that carbon gasifying is catalyzed and thus carbothermic reduction of MnO
2 is catalyzed.