Abstract: W/Cu Functionally Graded Materials (FGM) was designed not only for reducing the thermal stress caused by the mismatch of thermal expansion coefficients, but also for combining the features of W, Mo-high plasma-erosion resistance and the advantages of Cu-high heat conductivity and ductility. Four different fabrication processes for W/Cu or Mo/Cu, including hot-pressing, Cu infiltration of sintered porosity-graded W skeleton, spark plasma sintering and plasma spraying, were investigated and compared. It was found that the hot-pressing process is difficult to keep the designed composition gradient, while the other three processes are successful in making W/Cu or Mo/Cu FGM. Meanwhile, microstructures and composition gradients are analyzed with SEM and EDAX.