Abstract: Sodium chromate solubility is determined in the range of NaOH concentrations from 450 to 810 g/L and solution temperatures from 30 to 110℃. The optimized conditions to separate sodium chromate from NaOH in leached solution are resolved. It is first found the method to efficiently separate sodium chromate from NaOH and sodium aluminate in crude sodium chromate. Bench-scale studies on the separating are performed. Finally, good separation results are achieved.