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2007年  第14卷  第2期

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Mineral
Characteristics and evolution of ore-forming fluids of the Chongjiang copper deposit in the Gangdise porphyry copper belt, Tibet
Yuling Xie, Jiuhua Xu, Guangming Li, Zhiming Yang, Longsheng Yi
2007, 14(2): 97-102. doi: 10.1016/S1005-8850(07)60020-6
中文摘要(204) PDF(9) SpringerLink
摘要:
Petrography, microthermometry, and scanning electron microscope/energy dispersive spectrometer (SEM/EDS) studies were performed on the fluid inclusions in the ore-beating quartz veins and quartz phenocrysts in the porphyry of the Chongjiang porphyry copper deposit. The analyses of the fluid inclusions indicate that the ore-forming fluids were exsolved from magma. They are near-saturated, supercritical, rich in volatile constituents, and have the capture temperature of 362-389℃ and salinities of 17.7wt%- 18.9wt% NaC1 eq. With the decreasing of temperature and pressure, the supercritical fluids were separated into a low salinity vapor phase and a high salinity liquid phase. During quartz-sericitization, the high salinity fluid boiled and separated into a low salinity vapor phase and a high salinity liquid phase. The high salinity inclusions that formed in the boiling process had daughter mineral melting temperatures higher than the homogenization temperatures of the vapor and liquid phases. The late fluids that are responsible for argillization are of lower temperature and salinity.
Mineral
Adsorbability of Mycobacterium phlei on hematite surface
Huifen Yang, Qiang Zhang, Zhuan Jiang
2007, 14(2): 103-106. doi: 10.1016/S1005-8850(07)60021-8
中文摘要(156) PDF(10) SpringerLink
摘要:
The adsorption of microorganisms on the mineral surface is the base of microorganisms that are considered as mineral processing reagents. The principles of the use of a highly hydrophobic and negatively charged bacterium, Mycobacterium phlei, as a flocculating-flotating agent for finely divided hematite were investigated. The flocculating-floating recovery is strongly dependent on the pH and the dosage of the bacterium. Generally the pH should be controlled over the range of 5.5-7, and the dosage should be controlled about 16 mg/L. The infrared spectrometry analysis indicates that the six functional groups of M. phlei, substituted aromatic compound groups, -(CH2)n-groups, -CH2(-CH3) groups, carbonyl groups, aromatic hydrocarbon groups, and carboxyl groups, are on the hematite surface, among which the first five ones contribute physical adsorption and only the carboxyl groups provide chemisorption. Microscopic analysis reveals that the dimensions and tight aggregation degree of the flocs of hematite particles formed by M. phlei are also impacted by the pH and the content of M. phlei in flotation.
Metallurgy
Extraction of gold, palladium, and platinum from acidic media with cyclic sulfoxide derivative
Songping Wu, Guobang Gu
2007, 14(2): 107-111. doi: 10.1016/S1005-8850(07)60022-X
中文摘要(334) PDF(10) SpringerLink
摘要:
The extraction of gold (Ⅲ), palladium (Ⅱ), and platinum (Ⅳ) from the acidic media with the cyclic sulfoxide derivative of α-dodecyl-tetrahydrothiophene 1-oxide (dtmso) was investigated. Gold (Ⅲ), palladium (Ⅱ), and platinum (Ⅳ) could be separated from the acidic media with suitable sulfoxide concentration and acidity. The extraction reaction of gold (Ⅲ), palladium (Ⅱ) or platinum (Ⅳ) is exothermic when dtmso is used as an extracting reagent. The coordination number was studied by the slope method. The results indicate that, in high acidity, the dtmso coordination number for extracting gold (Ⅲ) or palladium (Ⅱ) is 3, and that for platinum (Ⅳ) is 2. UV and FT-IR spectra were used to analyze the structure of the complex. Gold (Ⅲ) is coordinated with the oxygen atom in S=O group in dtmso, and palladium (Ⅱ) or platinum (Ⅳ) is coordinated with the sulfur atom in S=O group in dtmso.
Metallurgy
Nature of large (Ti, Nb)(C, N) particles precipitated during the solidification of Ti, Nb HSLA steel
Xiaojun Zhuo, Xinhua Wang, Wanjun Wang, Hae-Geon Lee
2007, 14(2): 112-117. doi: 10.1016/S1005-8850(07)60023-1
中文摘要(278) PDF(22) SpringerLink
摘要:
To investigate the microsegregation phenomena and complex (Ti, Nb)(C, N) precipitation behavior during continuous casting, a unidirectional solidification unit was employed to simulate the solidification process. The samples of Ti, Nb-addition steels after unidirectional solidification were examined using field emission scanning electron microscope (FE-SEM) and electron probe X-ray microanalyzer (EPMA). In such specimens, dendrite structure and mushy zone can be detected along the solidification direction. It shows that the addition of titanium, niobium to high-strength low-alloyed (HSLA) steel results in undesirable (Ti, Nb)(C, N) precipitation because of microsegregation. The effect of cooling rate on (Ti, Nb)(C, N) precipitation was investigated. The composition of large precipitates was determined using FE-SEM with EDS. Large (Ti, Nb)(C, N) precipitates could be divided into three kinds according to the composition and morphology. With the cooling rate increasing, Ti-rich (Ti, Nb)(C, N) precipitates are transformed to Nb-rich (Ti, Nb)(C, N) precipitates.
Metallurgy
Orthogonal analysis of water model study on the optimization of flow control devices in a six-strand tundish
Zhengyan Wei, Yanping Bao, Jianhua Liu, Wenxu Gong, Baoming Wang
2007, 14(2): 118-124. doi: 10.1016/S1005-8850(07)60024-3
中文摘要(225) PDF(8) SpringerLink
摘要:
Improper flow control devices in a multi-strand tundish can cause some problems, for example, liquid steel cannot reach every nozzle at the same time and the liquid steel in nozzles far away from the entry zone has a lower temperature. The water model experiment of a six-strand tundish of Tianjin Iron & Steel Co. Ltd. was performed, a new "U" type baffle was obtained, and its parameters were defined by perpendicular analysis. The "U" baffle can not only improve those imperfections, but also prolong the residence time of nonmetallic inclusions, which is good for their flotation and separation.
Metallurgy
LATS refining ladle slag modifying with CaO-CaF2
Hongming Wang, Guirong Li, Zhongming Ren, Bo Li, Xuejun Zhang, Guomin Shi
2007, 14(2): 125-129. doi: 10.1016/S1005-8850(07)60025-5
中文摘要(283) PDF(12) SpringerLink
摘要:
To reduce the slag sticking onto the snorkel of the ladle during the ladle alloying treatment station (LATS) process, CaO-CaF2 (the mass ratio of CaO/CaF2 is 1:1) was employed as the modifier of the LATS refining ladle slag. The effect of CaO-CaF2 on the melting point, viscosity, and desulfurizing capability of the ladle slag was investigated. The melting point of the unmodified ladle slag is 1439℃. When adding 20wt% CaO-CaF2, the melting point is decreased to 1327℃. At 1500℃. the viscosity of the unmodified ladle slag is 6.5 Pa.s, which can be decreased lower than 2 Pa.s by adding more than 10wt% CaO-CaF2. The experimental results of desulfurization of the melts show that the desulfurizing power of the ladle slag can be enhanced by adding CaO-CaF2.
Materials
Modeling of microstructural evolution during dynamic recrystallization in coarse Nb microalloyed austenite
Ling Zhang, Wangyue Yang, Zuqing Sun
2007, 14(2): 130-135. doi: 10.1016/S1005-8850(07)60026-7
中文摘要(244) PDF(9) SpringerLink
摘要:
The aim of the current study was to investigate the microstructural evolution during dynamic recrystallization in coarse Nb microalloyed austenite in thin slab direct rolling (TSDR) processing. A model was developed to predict the change of the austenite grain size during the dynamic recrystallization, by using the law of mixtures. The equations initially developed for partial static recrystallization were used for partial dynamic recrystallization, by adjusting the value of the constant. The results show that the change of the austenite grain size can be reasonably described by using the equations developed according to the law of mixtures.
Materials
Study on laser welded heat-affected zone in new ultralow carbon bainitic steel
Lin Zhao, Wuzhu Chen, Xudong Zhang, Jiguo Shan
2007, 14(2): 136-140. doi: 10.1016/S1005-8850(07)60027-9
中文摘要(201) PDF(9) SpringerLink
摘要:
800 MPa grade ultralow carbon bainitic (NULCB) steel is the recently developed new generation steel, which was produced by thermo mechanical controlled processing & relaxation-precipitation controlling transformation (TMCP&RPC) technique. The microstructure and the mechanical properties of the heat-affected zone (HAZ) in NULCB steel under laser welding conditions were investigated by using a Gleeble-1500 thermal simulator. The experimental results indicate that the simplex microstructure in the HAZ is granular bainite that consists of bainite-ferrite (BF) lath and M-A constituent when the cooling time from 800 to 500℃ (t8/5) is 0.3-30 s, and the M-A constituent consists of twinned martensite and residual austenite. As t8/5 increases, the hardness and tensile strength of HAZ decreases, but they are higher than that of the base metal, indicating the absence of softened zone after laser welding. The impact toughness of HAZ increases at first and then decreases when t8/5 increases. The impact energy of HAZ is much higher than that of the base metal when t8/5 is between 3 and 15 s. It indicates that excellent low temperature toughness can be obtained under appropriate laser welding conditions.
Materials
Effect of P/M value on the preforms and microstructures of spray formed 70Si30Al alloy
Yanguang Wei, Baiqing Xiong, Yongan Zhang, Hongwei Liu, Feng Wang, Baohong Zhu
2007, 14(2): 141-145. doi: 10.1016/S1005-8850(07)60028-0
中文摘要(162) PDF(7) SpringerLink
摘要:
A novel 70Si30Al alloy was prepared by the spray forming process for electronic packaging materials. The effect of the ratio of atomization pressure to metal melt mass flux rate (P/M) on the preforms and microstructures of the spray-deposited 70Si30Al alloy was studied. The results indicate that the PIM value has a considerable influence on the formation of the preforms and the optimal value is in the range of 0.209-0.231 MPa/(kg.min-1). The microstructure of the spray formed 70Si30AI alloy is fine and homogenous. The primary silicon phases distributing in the aluminum matrix evenly are fine and irregular. The aluminum matrix is divided into two groups: supersaturated α-Al phase or α-Al phase and Al-Si pseudoeutectic phase or Al-Si eutectic phase.
Materials
Three-dimensional analysis of the modified sloping cooling/shearing process
Renguo Guan, Luolian Zhang, Chao Wang, Jinglin Wen, Jianzhong Cui
2007, 14(2): 146-150. doi: 10.1016/S1005-8850(07)60029-2
中文摘要(187) PDF(7) SpringerLink
摘要:
A self-designed setup of modified sloping cooling/shearing process was made to prepare the semisolid Al-3wt%Mg alloy. A three-dimensional simulation model was established for the analysis of preparing the semisolid Al-3wt%Mg alloy. Through simulation and experiment, it is shown that the sloping angle of the plate greatly affects temperature and velocity distributions, and the temperature and velocity of the alloy at the exit of the sloping plate increase with the increase of the sloping angle. The alloy temperature decreases linearly from the pouring mouth to the exit. The alloy temperature at the exit increases obviously with the increase of pouring temperature. To prepare the semisolid Al-3wt%Mg alloy with good quality, the sloping angle θ=45° is reasonable, and the pouring temperature is suggested to be designed above 650-660℃ but under 700℃.
Materials
Microstructure evolution of Al-4Cu-Mg alloy during semi-solid treatment
Haitao Jiang, Zhenli Mi, Di Tang, Miaoquan Li
2007, 14(2): 151-156. doi: 10.1016/S1005-8850(07)60030-9
中文摘要(182) PDF(8) SpringerLink
摘要:
The microstructure of a cold-deformed Al-4Cu-Mg alloy during semi-solid treatment was investigated, which shows that grain detachment and grain spheroidization processes during the semi-solid treatment are very important to control the fabricated semi-solid microstructures. For the two different processes, the driving force comes from the external heat source and the reduction in total interfacial area, respectively. The evolution models of microstructure morphology in the two processes were presented based on microstructure observations. It can be found that these models are useful to provide a reasonable estimated critical time of the evolution of microstructure during the semi-solid treatment.
Materials
Design and optimization of W/Cu divertor mock-ups
Qiang Li, Weiping Shen
2007, 14(2): 157-159. doi: 10.1016/S1005-8850(07)60031-0
中文摘要(233) PDF(7) SpringerLink
摘要:
Tungsten is a promising candidate for plasma-facing materials to cover the surface of the divertor plate in the design of an international thermonuclear experimental reactor (ITER). Copper as a heat sink material serves to transfer heat excellently. Divertor mock-ups with W/Cu graded interlayers were designed to reduce thermal stresses. Thermally induced stresses and temperature in a W/Cu divertor mock-up were analyzed using the finite element method. The graded structures with different exponents p and thicknesses were designed and discussed. The conclusions drawn from these analyses are that thermal stresses reach the minimum and the temperature is suitable when exponent p is 1.5 and the thickness of five graded interlayers is 5 mm.
Materials
Effect of annealing on the characteristics of Au/Ni50Fe50 bilayer films grown on glass
Hao Qian, Hong Qiu, Xiaobai Chen, Yue Tian, Ping Wu, Fengping Wang, Liqing Pan
2007, 14(2): 160-166. doi: 10.1016/S1005-8850(07)60032-2
中文摘要(187) PDF(9) SpringerLink
摘要:
Sputter-deposited Au/NisoFeso bilayer films were annealed in a vacuum of 5×10-4 Pa at 523 to 723 K for 30 or 90 min. The characteristics of the bilayer films were determined by Auger electron spectroscopy, field emission scanning electron microscopy, X-ray diffractometry, a four-point probe technique, and an alternating gradient magnetometer. When the annealing temperature and time reached 723 K and 90 min, Ni and Fe atoms markedly diffused into the Au layer. The grain size of the Au layer did not change markedly with the annealing condition. As the annealing time was 30 min and the annealing temperature exceeded 573 K, the resistance of the bilayer film increased with increasing the annealing temperature. Furthermore, the resistance of the bilayer film annealed at 723 K for 90 min was lower than that of the bilayer film annealed at 723 K for 30 min. All the bilayer films showed magnetic hysteresis loops. The as-deposited bilayer film showed a hard magnetization. The bilayer film represented an easy magnetization with increasing the annealing temperature. The Au/Ni50Fe50 film that annealed at 723 K for 90 min had the lowest saturation magnetization.
Materials
Tribological properties of electroless Ni-P-SiC composite coatings in rolling/sliding contact under boundary lubrication
Wei-Long Liu, Shu-Hue Hsieh, Shen-Jenn Hwang, Ting-Kan Tsai, Wen-Jauh Chen
2007, 14(2): 167-172. doi: 10.1016/S1005-8850(07)60033-4
中文摘要(223) PDF(7) SpringerLink
摘要:
Ni-P-SiC composite coatings were prepared under a given bath composition and operation parameters of electroless plating. The tribological properties of the Ni-P-SiC composite coatings after annealing at 400℃ for 1 h were tested in rolling/sliding contact under boundary lubrication condition using a two-roller tribometer. The measurement contained friction coefficient, contact surface temperature, contact electrical resistance, and wear rate of the Ni-P-SiC composite coatings under various slide to roll ratios, loads, and rolling speeds. For the simultaneous examination of the effect of the chosen parameters on the tribological properties of the Ni-P-SiC composite coatings, an orthogonal regression experimental design method was used.
Materials
Comparative experiment on layered Li(Ni1/3Co1/3Mn1/3)O2 as the alternative material for LiCoO2
Jingjing Liu, Weihua Qiu, Lingyan Yu, Hailei Zhao, Tao Li
2007, 14(2): 173-177. doi: 10.1016/S1005-8850(07)60034-6
中文摘要(232) PDF(141) SpringerLink
摘要:
The characteristics and electrochemical properties of the layered Li(Ni1/3Co1/3Mn1/3)O2 have been investigated by using the X-ray diffraction (XRD), scanning electron microscopy (SEM), and cyclic voltammograms (CV). The Li(Ni1/3Co1/3Mn1/3)O2 powders were synthesized by coprecipitation method. The as-synthesized Li(Ni1/3Co1/3Mn1/3)O2 has well-shaped crystals with a uniform particle size distribution at ~500 nm. A reversible discharge capacity of 165 mAh/g at a current of 40 mA/g between 2.7-4.35 V, with stable cycling performance has been obtained. Moreover, the discharge capacity rises up to 190 mAh/g, when the cutoff voltage increases to 4.6 V. The excellent cycling performance at a higher cutoff operating voltage (up to 4.8 V) could be attributed to the well-retention of the microstructure of synthesized Li(Ni1/3Co1/3Mn1/3)O2 powders. Comparatively, LiCoO2 suffered structure degradation at a higher cutoff voltage. However, the high rate properties of Li(Ni1/3Co1/3Mn1/3)O2 is not as good as LiCoO2, so its electrical conductivity must be improved.
Materials
Carbonation of low heat portland cement paste precured in water for different time
Deping Chen, Etsuo Sakai, Masaki Daimon, Yoko Ohba
2007, 14(2): 178-184. doi: 10.1016/S1005-8850(07)60035-8
中文摘要(280) PDF(8) SpringerLink
摘要:
The carbonation technique was applied to accelerate the hydration of low heat portland cement (LHC). Before carbonation, the demoulded pastes were precured in water for 0, 2, 7, and 21 d, respectively. The results show that precuring time in water strongly influences the carbonation process. The phenolphthalein test indicates that the paste precured in water for a shorter time is more quickly carbonated than that for a longer time. The content of calcium hydroxide increases with increasing the precuring time in water, whereas, the amount of absorbed carbon dioxide changes contrarily. Scanning electron microscope (SEM) observation shows that portlandite always fills up big air bubbles in the paste during precuring in water, and the mercury intrusion porosimetry (MIP) results show that there are less large capillary pores in the paste precured in water for a longer time. It is found that the paste without precuring in water has more carbon dioxide absorption during curing in carbon dioxide atmosphere, and its total pore volume decreases remarkably with an increase in the carbonation time than that precured in water. X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) surface area analyses indicate that the carbonate products are vaterite and calcite; CxSHy formed from carbonation has low BET surface area in comparison with that of C-S-H formed from curing in water.
Materials
Processing investigation and optimization for hybrid thermoplastic composites
M Tufail
2007, 14(2): 185-189. doi: 10.1016/S1005-8850(07)60036-X
中文摘要(243) PDF(8) SpringerLink
摘要:
A thermoplastic based composite material is suitable for automobile and aerospace applications. The recyclability of thermoplastic and clean processing further enhance its use. The only limitation encountered in using this material is its high-melt viscosity. Various techniques have been developed to overcome this problem. Commingled materials are one of such methods adopted for making proper use of thermoplastic. A major problem observed during the use of a commingled material is its de-commingling, wherein, the uniform distribution of fiber and thermoplastic yam gets disturbed and affects the final quality of the composite. The effects of the braiding process on laminate quality were investigated. Flat plaques were produced by braiding the commingled yam, using a 48-carrier braiding machine. The braids (and control woven samples) were subsequently heated and consolidated in a nonisothermal compression molding operation. Prior to the manufacture of the ‘best quality’ plaques, a series of moldings were produced under different consolidation conditions, to study the dependence of properties on the process variables. This enabled a processing window to be established for each material and helped to separate the respective effects of yam handling, textile processing, and consolidation on laminate properties.
Materials
Study and application of crown feedback control in hot strip rolling
Xiaodong Wang, Anrui He, Quan Yang, Zhi Xie, Hongtao Yang
2007, 14(2): 190-194. doi: 10.1016/S1005-8850(07)60037-1
中文摘要(210) PDF(8) SpringerLink
摘要:
Crown feedback control is one part of the automatic shape control (ASC) system. On the basis of large simulation researches conducted, a linear crown feedback control model was put forward and applied in actual strip rolling. According to its successful operation in the ASP 1700 hot strip mill of Angang Group for one year and also from the statistical results of several crown measurements, it can be definitely said that this control model is highly effective and shows stable performance. The control effectiveness of different gauges of strips with the feedback control is found to increase by 10%-30% compared with that without feedback control.

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