Cite this article as: |
Basavaraj, Pavankumar R. Sondar, and Subray R. Hegde, Effect of spheroidization of cementite in ductile cast iron, Int. J. Miner. Metall. Mater., 28(2021), No. 3, pp. 404-411. https://doi.org/10.1007/s12613-020-2041-0 |
Basavaraj E-mail: basavaraj.1si10me030@gmail.com
The research aims to provide an alternative to austempering treatment of ductile cast iron with a simple and cost-effective heat-treatment process. This goal was accomplished by applying a simple one-step spheroidization heat treatment to the as-cast ductile iron, which would normally possess a coarse pearlitic microstructure to a significant extent. Spheroidization experiments involving isothermal holding below the lower critical temperature (A1) were conducted followed by standard mechanical testing and microstructural characterization for an experimental ductile iron. After improving the spheroidization holding time at a given temperature, the work shows that the ductility and toughness of an as-cast ductile iron can be improved by 90% and 40%, respectively, at the cost of reducing the tensile strength by 8%. Controlled discretization of the continuous cementite network in pearlitic matrix of the ductile iron is deemed responsible for the improved properties. The work also shows that prolonged holding time during spheroidization heat treatment leads to degradation of mechanical properties due to the inhomogenous microstructure formation caused by heterogeneous decomposition and cementite clustering in the material. The main outcome of this work is the demonstration of ductile cast iron’s necking behavior due to spheroidization heat treatment.
[1] |
D.M. Stefanescu, A history of cast iron, [in] D.M. Stefanescu, ed., Cast Iron Science and Technology, ASM Handbook, Vol. 1A, ASM International, Materials Park, OH, 2017, p. 3.
|
[2] |
M. de Bouw, I. Wouters, J. Vereecken, and L. Lauriks, Iron and steel varieties in building industry between 1860 and 1914 – A complex and confusing situation resolved, Constr. Build. Mater., 23(2009), No. 8, p. 2775. doi: 10.1016/j.conbuildmat.2009.03.009
|
[3] |
F. Iacoviello, V.D. Cocco, and G. Favaro, Pearlitic ductile cast iron: Mechanical properties gradient analysis in graphite elements, Procedia Struct. Integrity, 9(2018), p. 9. doi: 10.1016/j.prostr.2018.06.004
|
[4] |
C.R. Gagg and P.R. Lewis, The rise and fall of cast iron in Victorian structures – A case study review, Eng. Fail. Anal., 18(2011), No. 8, p. 1963. doi: 10.1016/j.engfailanal.2011.07.013
|
[5] |
C. Labrecque and M. Gagné, Ductile iron: Fifty years of continuous development, Can. Metall. Q., 37(1998), No. 5, p. 343.
|
[6] |
J.J. Cui and L.Q. Chen, Microstructure and abrasive wear resistance of an alloyed ductile iron subjected to deep cryogenic and austempering treatments, J. Mater. Sci. Technol., 33(2017), No. 12, p. 1549. doi: 10.1016/j.jmst.2017.08.003
|
[7] |
J.J. Cui and L.Q. Chen, Microstructures and mechanical properties of a wear-resistant alloyed ductile iron austempered at various temperatures, Metall. Mater. Trans. A, 46(2015), No. 8, p. 3627. doi: 10.1007/s11661-015-2928-y
|
[8] |
C.H. Hsu and T.L. Chuang, Influence of stepped austempering process on the fracture toughness of austempered ductile iron, Metall. Mater. Trans. A, 32(2001), No. 10, p. 2509. doi: 10.1007/s11661-001-0040-y
|
[9] |
R.C. Voigt and Y.H. Lee, Properties and application of austempered ductile irons, [in] Y.H. Kabil and M.E. Said, eds., Current Advances in Mechanical Design and Production IV, Pergamon Press, Oxford, 1989, p. 29.
|
[10] |
A. Trudel and M. Gagné, Effect of composition and heat treatment parameters on the characteristics of austempered ductile irons, Can. Metall. Q., 36(1997), No. 5, p. 289. doi: 10.1179/cmq.1997.36.5.289
|
[11] |
B. Stouģhton and R.D. Billinger, The spheroidizing of cementite, Ind. Eng. Chem., 18(1926), No. 8, p. 785. doi: 10.1021/ie50200a004
|
[12] |
D.H. Shin, S.Y. Han, K.T. Park, Y.S. Kim, and Y.N. Paik, Spheroidization of low carbon steel processed by equal channel angular pressing, Mater. Trans., 44(2003), No. 8, p. 1630. doi: 10.2320/matertrans.44.1630
|
[13] |
Z.Q. Lv, B. Wang, Z.H. Wang, S.H. Sun, and W.T. Fu, Effect of cyclic heat treatments on spheroidizing behavior of cementite in high carbon steel, Mater. Sci. Eng. A, 574(2013), p. 143. doi: 10.1016/j.msea.2013.02.059
|
[14] |
K. Tokaji, T. Horie, and Y. Enomoto, Effects of microstructure and carbide spheroidization on fatigue behaviour in high V–Cr–Ni cast irons, Int. J. Fatigue, 28(2006), No. 3, p. 281. doi: 10.1016/j.ijfatigue.2005.05.009
|
[15] |
L.C. Casteletti, P.E.B. Kinap, and P.A.P. Nascente, Heat treatments for obtaining spheroidal cementite in ductile cast iron, Int. J. Mater. Prod. Technol., 24(2005), No. 1-4, p. 375.
|