Cui Wang, Chen-yang Xu, Zheng-jian Liu, Yao-zu Wang, Rong-rong Wang, and Li-ming Ma, Effect of organic binders on the activation and properties of indurated magnetite pellets, Int. J. Miner. Metall. Mater., 28(2021), No. 7, pp. 1145-1152. https://doi.org/10.1007/s12613-020-2055-7
Cite this article as:
Cui Wang, Chen-yang Xu, Zheng-jian Liu, Yao-zu Wang, Rong-rong Wang, and Li-ming Ma, Effect of organic binders on the activation and properties of indurated magnetite pellets, Int. J. Miner. Metall. Mater., 28(2021), No. 7, pp. 1145-1152. https://doi.org/10.1007/s12613-020-2055-7
Research Article

Effect of organic binders on the activation and properties of indurated magnetite pellets

+ Author Affiliations
  • Corresponding author:

    Zheng-jian Liu    E-mail: liuzhengjian@ustb.edu.cn

  • Received: 16 January 2020Revised: 30 March 2020Accepted: 1 April 2020Available online: 3 April 2020
  • In the ironmaking process, the addition of an organic binder to replace a portion of bentonite has the potential to improve the performance of pellets. The interaction between original bentonite (OB) and organic binder was investigated. Results indicated that the micromorphology of organic composite bentonite (OCB) became porous and the infrared difference spectrum exhibited a curved shape. In addition, the residual burning rates of OB and organic binder were determined to be 82.72% and 2.30%, respectively. Finally, the influence of OCB on the properties of pellets was investigated. The compressive strength of OCB-added green pellets (14.7 N per pellet) was better than that of OB-added pellets (10.3 N per pellet). Moreover, the range of melting temperature of OCB-added green pellets (173°C) was narrower than that of OB-added pellets (198°C). The compressive strength of OCB-added green pellets increased from 2156 to 3156 N per pellet with the increase in roasting temperature from 1200 to 1250°C.

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  • [1]
    H. Q. Zhang and J. T. Fu, Oxidation behavior of artificial magnetite pellets, Int. J. Miner. Metall. Mater., 24(2017), No. 6, p. 603. doi: 10.1007/s12613-017-1442-1
    [2]
    J. Chen, Y. Jiao, and X. Wang, Thermodynamic studies on gas-based reduction of vanadium titano-magnetite pellets, Int. J. Miner. Metall. Mater., 26(2019), 7, p. 822. doi: 10.1007/s12613-019-1795-8
    [3]
    T.C. Eisele and S.K. Kawatra, A review of binders in iron ore pelletization, Miner. Process. Extr. Metall. Rev., 24(2003), No. 1, p. 1. doi: 10.1080/08827500306896
    [4]
    U. Srivastava, S.K. Kawatra, and T.C. Eisele, Study of organic and inorganic binders on strength of iron oxide pellets, Metall. Mater. Trans. B, 44(2013), No. 4, p. 1000. doi: 10.1007/s11663-013-9838-4
    [5]
    G.J. Cheng, Z.X. Gao, H. Yang, and X.X. Xue, Effect of diboron trioxide on the crushing strength and smelting mechanism of high-chromium vanadium–titanium magnetite pellets, Int. J. Miner. Metall. Mater., 24(2017), No. 11, p. 1228. doi: 10.1007/s12613-017-1515-1
    [6]
    A.B. Kotta, A. Patra, M. Kumar, and S.K. Karak, Effect of molasses binder on the physical and mechanical properties of iron ore pellets, Int. J. Miner. Metall. Mater., 26(2019), No. 1, p. 41. doi: 10.1007/s12613-019-1708-x
    [7]
    S.K. Kawatra and S.J. Ripke, Laboratory studies for improving green ball strength in bentonite-bonded magnetite concentrate pellets, Int. J. Miner. Process., 72(2003), No. 1, p. 429.
    [8]
    H. Liu, B. Xie, Y.L. Qin, and M.D. Alba, Effect of Bentonite on the pelleting properties of iron concentrate, J. Chem., 2017(2017), p. 1.
    [9]
    Y.L. Zhou and S.K. Kawatra, Humic substance-based binder in iron ore pelletization: A review, Miner. Process. Extr. Metall. Rev., 38(2017), No. 5, p. 321. doi: 10.1080/08827508.2017.1328598
    [10]
    I.U. Bhuiyan, J. Mouzon, B. Schröppel, A. Kaech, I. Dobryden, S.P. Forsmo, and J. Hedlund, Microstructure of bentonite in iron ore green pellets, Microsc. Microanal., 20(2014), No. 1, p. 33. doi: 10.1017/S1431927613013950
    [11]
    R.R. Wang, J.L. Zhang, Y.R. Liu, A.Y. Zheng, Z.J. Liu, X.L. Liu, and Z.G. Li, Thermal performance and reduction kinetic analysis of cold-bonded pellets with CO and H2 mixtures, Int. J. Miner. Metall. Mater., 25(2018), No. 7, p. 752. doi: 10.1007/s12613-018-1623-6
    [12]
    Y.B. Zhang, Y.L. Zhou, B.B. Liu, G.H. Li, and T. Jiang, Roasting characteristics of specularite pellets with modified humic acid based (MHA) binder under different oxygen atmospheres, Powder Technol., 261(2014), p. 279. doi: 10.1016/j.powtec.2014.04.053
    [13]
    F.M. Linhares, C.C.F. Victor, L.R. Lemos, and M.C. Bagatini, Effect of three different binders and pellet feed on granulation behaviour of sintering mixtures, Ironmaking Steelmaking, 47(2020), No. 9, p. 911.
    [14]
    Y.B. Yang, G.X. Huang, T. Jiang, Z.C. Huang, Y. Luo, and Y.L. Huang, Application of organic binder as substitutes for bentonite in pellet preparation, J. Cent. South Univ. Sci. Technol., 38(2007), No. 5, p. 850.
    [15]
    G.Z. Qiu, T. Jiang, Z.C. Huang, D.Q. Zhu, and X.H. Fan, Characterization of preparing cold bonded pellets for direct reduction using an organic binder, ISIJ Int., 43(2003), No. 1, p. 20. doi: 10.2355/isijinternational.43.20
    [16]
    A. Ammasi and J. Pal, Replacement of bentonite in hematite ore pelletisation using a combination of sodium lignosulphonate and copper smelting slag, Ironmaking Steelmaking, 43(2016), No. 3, p. 203. doi: 10.1179/1743281215Y.0000000033
    [17]
    O. Sivrikaya, A.I. Arol, T. Eisele, and S.K. Kawatra, The effect of calcined colemanite addition on the mechanical strength of magnetite pellets produced with organic binders, Miner. Process. Extr. Metall. Rev., 34(2013), No. 4, p. 210. doi: 10.1080/08827508.2012.657021
    [18]
    S. K. Kawatra and J. A. Halt, Binding effects in hematite and magnetite concentrates, Int. J. Miner. Process., 99(2011), No. 1, p. 39.
    [19]
    X.H. Fan, Y. Wang, M. Gan, L.S. Yuan, L.Q. Dai, and G.G. Zhao, Strength enhancement of oxide pellet with organic binder, J. Iron Steel Res., 20(2008), No. 5, p. 5.
    [20]
    D.Q. Zhu, V. Mendes, T. Chun, J. Pan, Q.H. Li, J. Li, and G.Z. Qiu, Direct reduction behaviors of composite binder magnetite pellets in coal-based grate-rotary kiln process, ISIJ Int., 51(2011), No. 2, p. 214. doi: 10.2355/isijinternational.51.214
    [21]
    F.N. Ridha, V. Manovic, E.J. Anthony, and A. MacChi, The morphology of limestone-based pellets prepared with kaolin-based binders, Mater. Chem. Phys., 138(2013), No. 1, p. 78. doi: 10.1016/j.matchemphys.2012.11.007
    [22]
    Y.B. Zhang, M.M. Lu, Z.J. Su, J. Wang, Y.K. Tu, X.J. Chen, C.T. Cao, F.Q. Gu, S. Liu, and T. Jiang, Interfacial reaction between humic acid and Ca-Montmorillonite: Application in the preparation of a novel pellet binder, Appl. Clay Sci., 180(2019), No. 6, art. No. 105177.
    [23]
    S.L. De Moraes, J.R.B. De Lima, J.B.F. Neto, C. Fredericci, and E.M. Saccoccio, Binding mechanism in green iron ore pellets with an organic binder, Miner. Process. Extr. Metall. Rev., 41(2020), No. 4, p. 247. doi: 10.1080/08827508.2019.1604521
    [24]
    D.Q. Zhu, S.A. Xiong, J.Pan, and X.L. Zhou, Improving pelletization of magnetite concentrate by organic complex bentonite and its industrial application, J. Cent. South Univ. Sci. Technol., 42(2011), No. 2, p. 279.
    [25]
    S. Kumar and S. Suman, Compressive strength of fired pellets using organic binder: response surface approach for analyzing the performance, Trans. Indian Inst. Met., 71(2018), No. 7, p. 1629. doi: 10.1007/s12666-018-1297-9
    [26]
    Y.L. Zhou and S.K. Kawatra, Pelletization using humic substance-based binder, Miner. Process. Extr. Metall. Rev., 38(2017), No. 2, p. 83. doi: 10.1080/08827508.2016.1262859
    [27]
    B.B. Ivanova, D.L. Tsalev, and M.G. Arnaudov, Validation of reducing-difference procedure for the interpretation of non-polarized infrared spectra of n-component solid mixtures, Talanta, 69(2006), No. 4, p. 822. doi: 10.1016/j.talanta.2005.11.026
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