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Article Navigation >  International Journal of Minerals, Metallurgy and Materials  > 2020 > Accepted Manuscript

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Research Article

Investigation of dielectric relaxations and conduction mechanism in Aurivillius ceramic Bi5Ti3FeO15

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  • Received: 11 January 2020; Revised: 23 April 2020; Accepted: 7 May 2020; Available online: 9 May 2020
  • Aurivillius Bi5Ti3FeO15 (BTFO) ceramic is synthesized by the generic solid-state reaction route. The room temperature X-ray diffraction (XRD) study confirms that the compound is having single-phase without any impurity. Surface morphology of the prepared sample ensures that the presence of microstructural grains with size around 0.2 to 2 µm is observed. Dielectric properties of sample are investigated as a function of frequency of about 100 Hz to 1 MHz at various temperatures (303 K ≤ T ≤ 773 K). The Nyquist plots of impedance data exhibit a semi-circular arc in high temperature region, which is explained by the equivalent electrical circuit (R1C1) (R2QC2). Our results indicate that resistance as well as capacitance of grain boundary is more prominent over the grains. Analysis of ac conductivity data is done by using Jonscher universal power law (σac=σdc+Aωn) which confirms that the conduction process is dominated by the hopping mechanism. The activation energies calculated for relaxation and conduction processes are very close to each other (0.32 eV to 0.53 eV) by which we conclude that the same type of charge carriers are involved in both the processes.
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Investigation of dielectric relaxations and conduction mechanism in Aurivillius ceramic Bi5Ti3FeO15

  • Corresponding author:

    A. K. Singh    E-mail: singhanil@nitrkl.ac.in

  • 1. Department of Physics and Astronomy, National Institute of Technology Rourkela, Rourkela-769008, Odisha, India
  • 2. UGC-DAE Consortium for Scientific Research Mumbai Centre, BARC, Mumbai-400085, India
    Received: 11 January 2020
    Revised: 23 April 2020
    Accepted: 7 May 2020
    Available online: 9 May 2020

Abstract: Aurivillius Bi5Ti3FeO15 (BTFO) ceramic is synthesized by the generic solid-state reaction route. The room temperature X-ray diffraction (XRD) study confirms that the compound is having single-phase without any impurity. Surface morphology of the prepared sample ensures that the presence of microstructural grains with size around 0.2 to 2 µm is observed. Dielectric properties of sample are investigated as a function of frequency of about 100 Hz to 1 MHz at various temperatures (303 K ≤ T ≤ 773 K). The Nyquist plots of impedance data exhibit a semi-circular arc in high temperature region, which is explained by the equivalent electrical circuit (R1C1) (R2QC2). Our results indicate that resistance as well as capacitance of grain boundary is more prominent over the grains. Analysis of ac conductivity data is done by using Jonscher universal power law (σac=σdc+Aωn) which confirms that the conduction process is dominated by the hopping mechanism. The activation energies calculated for relaxation and conduction processes are very close to each other (0.32 eV to 0.53 eV) by which we conclude that the same type of charge carriers are involved in both the processes.

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