Xiao-liang Zhang, Jue Kou, Chun-bao Sun, Rui-yang Zhang, Min Su, and Shuo-fu Li, Mineralogical characterization of copper sulfide tailings using automated mineral liberation analysis: A case study of the Chambishi Copper Mine tailings, Int. J. Miner. Metall. Mater., 28(2021), No. 6, pp. 944-955. https://doi.org/10.1007/s12613-020-2093-1
Cite this article as:
Xiao-liang Zhang, Jue Kou, Chun-bao Sun, Rui-yang Zhang, Min Su, and Shuo-fu Li, Mineralogical characterization of copper sulfide tailings using automated mineral liberation analysis: A case study of the Chambishi Copper Mine tailings, Int. J. Miner. Metall. Mater., 28(2021), No. 6, pp. 944-955. https://doi.org/10.1007/s12613-020-2093-1
Research Article

Mineralogical characterization of copper sulfide tailings using automated mineral liberation analysis: A case study of the Chambishi Copper Mine tailings

+ Author Affiliations
  • Corresponding authors:

    Jue Kou    E-mail: koujue@ustb.edu.cn

    Chun-bao Sun    E-mail: suncb@ustb.edu.cn

  • Received: 18 February 2020Revised: 6 May 2020Accepted: 9 May 2020Available online: 13 May 2020
  • As ore grades constantly decline, more copper tailings, which still contain a considerable amount of unrecovered copper, are expected to be produced as a byproduct of froth flotation. This research reveals the occurrence mechanism of copper minerals in typical copper sulfide tailings using quantitative mineral liberation analysis (MLA) integrated with scanning electron microscopy–energy dispersive spectroscopy (SEM–EDS). A comprehensive mineralogical characterization was carried out, and the results showed that almost all copper minerals were highly disseminated within coarse gangue particles, except for 9.2wt% chalcopyrite that occurred in the 160–180 μm size fraction. The predominant copper-bearing mineral was chalcopyrite, which was closely intergrown with orthoclase and muscovite rather than quartz. The flotation tailings sample still contained 3.28wt% liberated chalcopyrite and 3.13wt% liberated bornite because of their extremely fine granularity. The SEM–EDS analysis further demonstrated that copper minerals mainly occurred as fine dispersed and fully enclosed structures in gangue minerals. The information obtained from this research could offer useful references for recovering residual copper from flotation tailings.

  • loading
  • [1]
    M.E. Schlesinger, M.J. King, K.C. Sole, and W.G. Davenport, Extractive Metallurgy of Copper, Elsevier, Amsterdam, 2011.
    [2]
    K.J. Nyembwe, E. Fosso-Kankeu, F. Waanders, and K.D. Nyembwe, Structural, compositional and mineralogical characterization of carbonatitic copper sulfide: Run of mine, concentrate and tailings, Int. J. Miner. Metall. Mater., 26(2019), No. 2, p. 143. doi: 10.1007/s12613-019-1718-8
    [3]
    Y. Li, N. Kawashima, J. Li, A.P. Chandra, and A.R. Gerson, A review of the structure. and fundamental mechanisms and kinetics of the leaching of chalcopyrite, Adv. Colloid Interface Sci., 197-198(2013), p. 1. doi: 10.1016/j.cis.2013.03.004
    [4]
    D. Mesa and P.R. Brito-Parada, Scale-up in froth flotation: A state-of-the-art review, Sep. Purif. Technol., 210(2019), p. 950. doi: 10.1016/j.seppur.2018.08.076
    [5]
    B. Feng, C.H. Zhong, L.Z. Zhang, Y.T. Guo, T. Wang, and Z.Q. Huang, Effect of surface oxidation on the depression of sphalerite by locust bean gum, Miner. Eng., 146(2020), art. No. 106142. doi: 10.1016/j.mineng.2019.106142
    [6]
    M.M. Antonijević, M.D. Dimitrijević, Z.O. Stevanović, S.M. Serbula, and G.D. Bogdanovic, Investigation of the possibility of copper recovery from the flotation tailings by acid leaching, J. Hazard. Mater., 158(2008), No. 1, p. 23. doi: 10.1016/j.jhazmat.2008.01.063
    [7]
    B.S. Han, B. Altansukh, K. Haga, Z. Stevanović, R. Jonović, L. Avramović, D. Urosević, Y. Takasaki, N. Masuda, D. Ishiyama, and A. Shibayama, Development of copper recovery process from flotation tailings by a combined method of high-pressure leaching-solvent extraction, J. Hazard. Mater., 352(2018), p. 192. doi: 10.1016/j.jhazmat.2018.03.014
    [8]
    J. Alcalde, U. Kelm, and D. Vergara, Historical assessment of metal recovery potential from old mine tailings: A study case for porphyry copper tailings, Chile, Miner. Eng., 127(2018), p. 334. doi: 10.1016/j.mineng.2018.04.022
    [9]
    Z.G. Yin, W. Sun, Y.H. Hu, C.H. Zhang, Q.J. Guan, and K.P. Wu, Evaluation of the possibility of copper recovery from tailings by flotation through bench-scale, commissioning, and industrial tests, J. Cleaner Prod., 171(2018), p. 1039. doi: 10.1016/j.jclepro.2017.10.020
    [10]
    J. Pazhoohan, H. Beiki, and M. Esfandyari, Experimental investigation and adaptive neural fuzzy inference system prediction of copper recovery from flotation tailings by acid leaching in a batch agitated tank, Int. J. Miner. Metall. Mater., 26(2019), No. 5, p. 538. doi: 10.1007/s12613-019-1762-4
    [11]
    S.H. Yin, L.M. Wang, A.X. Wu, E. Kabwe, X. Chen, and R.F. Yan, Copper recycle from sulfide tailings using combined leaching of ammonia solution and alkaline bacteria, J. Cleaner Prod., 189(2018), p. 746. doi: 10.1016/j.jclepro.2018.04.116
    [12]
    K. Nakajima, I. Daigo, K. Nansai, K. Matsubae, W. Takayanagi, M. Tomita, and Y. Matsuno, Global distribution of material consumption: Nickel, copper, and iron, Resour. Conserv. Recycl., 133(2018), p. 369. doi: 10.1016/j.resconrec.2017.08.029
    [13]
    H.K. Hansen, J.B. Yianatos, L.M. Ottosen, Speciation and leachability of copper in mine tailings from porphyry copper mining: influence of particle size, Chemosphere, 60(2005), No. 10, p. 1497. doi: 10.1016/j.chemosphere.2005.01.086
    [14]
    S. Jannesar Malakooti, S.Z. Shafaei Tonkaboni, M. Noaparast, F. Doulati Ardejani, and R. Naseh, Characterisation of the Sarcheshmeh copper mine tailings, Kerman province, southeast of Iran, Environ. Earth Sci., 71(2014), No. 5, p. 2267. doi: 10.1007/s12665-013-2630-6
    [15]
    M. Asghari, F. Nakhaei, and O. VandGhorbany, Copper recovery improvement in an industrial flotation circuit: A case study of Sarcheshmeh copper mine, Energy Sources Part A, 41(2019), No. 6, p. 761. doi: 10.1080/15567036.2018.1520356
    [16]
    I. Mackay, E. Mendez, I. Molina, A.R. Videla, J.J. Cilliers, and P.R. Brito-Parada, Dynamic froth stability of copper flotation tailings, Miner. Eng., 124(2018), p. 103. doi: 10.1016/j.mineng.2018.05.005
    [17]
    R.F. Zhu, G.H. Gu, Z.X. Chen, Y.H. Wang, and S.Y. Song, A new collector for effectively increasing recovery in copper oxide ore-staged flotation, Minerals, 9(2019), No. 10, p. 595. doi: 10.3390/min9100595
    [18]
    B. Feng, W.P. Zhang, Y.T. Guo, J.X. Peng, X.H. Ning, and H.H. Wang, Synergistic effect of acidified water glass and locust bean gum in the flotation of a refractory copper sulfide ore, J. Cleaner Prod., 202(2018), p. 1077. doi: 10.1016/j.jclepro.2018.08.214
    [19]
    S. Northey, S. Mohr, G.M. Mudd, Z. Weng, and D. Giurco, Modelling future copper ore grade decline based on a detailed assessment of copper resources and mining, Resour. Conserv. Recycl., 83(2014), p. 190. doi: 10.1016/j.resconrec.2013.10.005
    [20]
    B. Golding and S.D. Golding, Metals, Energy and Sustainability, Springer, Cham, 2017, p. 21.
    [21]
    R.B. Gordon, Production residues in copper technological cycles, Resour. Conserv. Recycl., 36(2002), No. 2, p. 87. doi: 10.1016/S0921-3449(02)00019-8
    [22]
    C.C. Lü, Y.L. Wang, P. Qian, Y. Liu, G.Y. Fu, J. Ding, S.F. Ye, and Y.F. Chen, Separation of chalcopyrite and pyrite from a copper tailing by ammonium humate, Chin. J. Chem. Eng., 26(2018), No. 9, p. 1814. doi: 10.1016/j.cjche.2018.02.014
    [23]
    A.C. Brown, World-class sediment-hosted stratiform copper deposits: Characteristics, genetic concepts and metallotects, Aust. J. Earth Sci., 44(1997), No. 3, p. 317. doi: 10.1080/08120099708728315
    [24]
    R.R. McGowan, S. Roberts, and A.J. Boyce, Origin of the Nchanga copper—Cobalt deposits of the Zambian Copperbelt, Miner. Deposita, 40(2006), No. 6, p. 617.
    [25]
    J.L.H. Cailteux, A.B. Kampunzu, C. Lerouge, A.K. Kaputo, and J.P. Milesi, Genesis of sediment-hosted stratiform copper-cobalt deposits, central African Copperbelt, J. Afr. Earth Sci., 42(2005), No. 1-5, p. 134. doi: 10.1016/j.jafrearsci.2005.08.001
    [26]
    J.K. Wen, B.W. Chen, H. Shang, and G.C. Zhang, Research progress in biohydrometallurgy of rare metals and heavy nonferrous metals with an emphasis on China, Rare Met., 35(2016), No. 6, p. 433. doi: 10.1007/s12598-016-0739-y
    [27]
    X.D. Hao, X.D. Liu, Q. Yang, H.W. Liu, H.Q. Yin, G.Z. Qiu, and Y.L. Liang, Comparative study on bioleaching of two different types of low-grade copper tailings by mixed moderate thermophiles, Trans. Nonferrous Met. Soc. China, 28(2018), No. 9, p. 1847. doi: 10.1016/S1003-6326(18)64829-0
    [28]
    J.B. Chen, R.J. Li, and L.H. Yu, The way of the survey and assessment of copper tailings resources and their application, J. Nat. Resour., 27(2012), No. 8, p. 1373.
    [29]
    L. Pérez-Barnuevo, E. Pirard, and R. Castroviejo, Automated characterisation of intergrowth textures in mineral particles. A case study, Miner. Eng., 52(2013), p. 136. doi: 10.1016/j.mineng.2013.05.001
    [30]
    Y. Gu, R.P. Schouwstra, and C. Rule, The value of automated mineralogy, Miner. Eng., 58(2014), p. 100. doi: 10.1016/j.mineng.2014.01.020
    [31]
    R. Sousa, B. Simons, K. Bru, A.B. de Sousa, G. Rollinson, J. Andersen, M. Martin, and M.M. Leite, Use of mineral liberation quantitative data to assess separation efficiency in mineral processing—Some case studies, Miner. Eng., 127(2018), p. 134. doi: 10.1016/j.mineng.2018.08.004
    [32]
    P.Y. Zhang, L.M. Ou, L.M. Zeng, W.G. Zhou, and H.T. Fu, MLA-based sphalerite flotation optimization: Two-stage roughing, Powder Technol., 343(2019), p. 586. doi: 10.1016/j.powtec.2018.11.085
    [33]
    L. Liu, Q. Tan, L. Liu, and J.C. Cao, Comparison of different comminution flowsheets in terms of minerals liberation and separation properties, Miner. Eng., 125(2018), p. 26. doi: 10.1016/j.mineng.2018.05.023
    [34]
    T. Leißner, K. Bachmann, J. Gutzmer, and U.A. Peuker, MLA-based partition curves for magnetic separation, Miner. Eng., 94(2016), p. 94. doi: 10.1016/j.mineng.2016.05.015
    [35]
    Z. Li, Y.H. Fu, C. Yang, W. Yu, L.J. Liu, J.Z. Qu, and W. Zhao, Mineral liberation analysis on coal components separated using typical comminution methods, Miner. Eng., 126(2018), p. 74. doi: 10.1016/j.mineng.2018.06.028
    [36]
    D.H. Hoang, A. Hassanzadeh, U.A. Peuker, and M. Rudolph, Impact of flotation hydrodynamics on the optimization of fine-grained carbonaceous sedimentary apatite ore beneficiation, Powder Technol., 345(2019), p. 223. doi: 10.1016/j.powtec.2019.01.014
    [37]
    C.L. Xu, C.B. Zhong, R.L. Lyu, Y.Y. Ruan, Z.Y. Zhang, and R.A. Chi, Process mineralogy of Weishan rare earth ore by MLA, J. Rare Earths, 37(2019), No. 3, p. 334. doi: 10.1016/j.jre.2018.06.008
    [38]
    B. Babel, M. Penz, E. Schach, S. Boehme, and M. Rudolph, Reprocessing of a southern Chilean Zn tailing by flotation—A case study, Minerals, 8(2018), No. 7, p. 295. doi: 10.3390/min8070295
    [39]
    K. Berkh, D. Rammlmair, M. Drobe, and J. Meima, Case study: Geochemistry and mineralogy of copper mine tailings in Northern Central-Chile, [in] 14th International Congress for Applied Mineralogy, Belgorod, 2019, p. 37..
    [40]
    B. Forsyth, M. Edraki, and T. Baumgartl, The evolution of tailings seepage chemistry at one of Australia’s largest and longest operating mines, [in] 10th International Conference on AcidRock Drainage and Annual IMWA Conference, Santiago, 2015, p. 1.
    [41]
    L. Wang and M.Y. Wang, Research on copper dissemination state from old tailings in a copper mine, Nonferrous Met. (Miner. Process. Sect.), 2012, No. 6, p. 1.
    [42]
    D. Naumov, L. Stamenov, S. Gaydardzhiev, and H. Bouzahzah, Coupling mineralogy with physicochemical parameters in view copper flotation efficiency improvement, Physicochem. Probl. Miner. Process., 55(2019), No. 3, p. 701.
    [43]
    M. Lu, D.H. Xie, W.H. Gui, L.H. Wu, C.Y. Chen, and C.H. Yang, A cascaded recognition method for copper rougher flotation working conditions, Chem. Eng. Sci., 175(2018), p. 220. doi: 10.1016/j.ces.2017.09.048
    [44]
    F. Kukurugya, A. Rahfeld, R. Möckel, P. Nielsen, L. Horckmans, J. Spooren, and K. Broos, Recovery of iron and lead from a secondary lead smelter matte by magnetic separation, Miner. Eng., 122(2018), p. 17. doi: 10.1016/j.mineng.2018.03.030
    [45]
    D. Sandmann and J. Gutzmer, Use of mineral liberation analysis (MLA) in the characterization of lithium-bearing micas, J. Miner. Mater. Charact. Eng., 1(2013), No. 6, p. 285.
    [46]
    B. Schulz, G. Merker, and J. Gutzmer, Automated SEM mineral liberation analysis (MLA) with generically labelled EDX spectra in the mineral processing of rare earth element ores, Minerals, 9(2019), No. 9, p. 527. doi: 10.3390/min9090527
    [47]
    A. Bakalarz, M. Duchnowska, and A. Luszczkiewicz, Influence of liberation of sulphide minerals on flotation of sedimentary copper ore, [in] E3S Web of Conferences, Paris, 2017, art. No. 01025.
    [48]
    O. Sracek, M. Mihaljevič, B. Kříbek, V. Majer, and F. Veselovský, Geochemistry and mineralogy of Cu and Co in mine tailings at the Copperbelt, Zambia, J. Afr. Earth Sci., 57(2010), No. 1-2, p. 14. doi: 10.1016/j.jafrearsci.2009.07.008
    [49]
    T.T. Jacobs, Process Mineralogical Characterisation of the Kansanshi Copper Ore, NW Zambia [Dissertation], University of Cape Town, Cape Town, 2016.
    [50]
    P. Vallejos, J. Yianatos, L. Vinnett, and L. Bergh, Characterization of the industrial flotation process based on size-liberation relationships, Miner. Eng., 121(2018), p. 189. doi: 10.1016/j.mineng.2018.01.019
    [51]
    A. Norori-McCormac, P.R. Brito-Parada, K. Hadler, K. Cole, and J.J. Cilliers, The effect of particle size distribution on froth stability in flotation, Sep. Purif. Technol., 184(2017), p. 240. doi: 10.1016/j.seppur.2017.04.022
    [52]
    A.M. Gaudin, R. Schuhmann Jr., and A.W. Schlechten, Flotation kinetics. II. The effect of size on the behavior of galena particles, J. Phys. Chem., 46(1942), No. 8, p. 902. doi: 10.1021/j150422a013
    [53]
    A. Bahrami, M. Mirmohammadi, Y. Ghorbani, F. Kazemi, M. Abdollahi, and A. Danesh, Process mineralogy as a key factor affecting the flotation kinetics of copper sulfide minerals, Int. J. Miner. Metall. Mater., 26(2019), No. 4, p. 430. doi: 10.1007/s12613-019-1733-9
    [54]
    D. Kossoff, W.E. Dubbin, M. Alfredsson, S.J. Edwards, M.G. Macklin, and K.A. Hudson-Edwards, Mine tailings dams: Characteristics, failure, environmental impacts, and remediation, Appl. Geochem., 51(2014), p. 229. doi: 10.1016/j.apgeochem.2014.09.010
    [55]
    S. Hashmi, B. Ward, A. Plouffe, T. Ferbey, and M. Leybourne, Geochemical and mineralogical dispersal in till from the Mount Polley Cu–Au porphyry deposit, central British Columbia, Canada, Geol. Surv. Can., (2014), art. No. 7589.
    [56]
    C. Kennedy, S.J. Day, and C.D. Anglin, Geochemistry of tailings from the Mount Polley Mine, British Columbia, [in] Proceedings Tailings and Mine Waste 2016, Keystone, 2016, p. 857.
    [57]
    A.F. Cropp, W.R. Goodall, and D.J. Bradshaw, The influence of textural variation and gangue mineralogy on recovery of copper by flotation from porphyry ore—A review, [in] The Second AusIMM International Geometallurgy Conference, Brisbane, 2013, p.279.
    [58]
    C.B. Zhong, C.L. Xu, R.L. Lyu, Z.Y. Zhang, X.Y. Wu, and R.A. Chi, Enhancing mineral liberation of a Canadian rare earth ore with microwave pretreatment, J. Rare Earths, 36(2018), No. 2, p. 215. doi: 10.1016/j.jre.2017.08.007
    [59]
    M. Camalan, M. Çavur, and Ç. Hoşten, Assessment of chromite liberation spectrum on microscopic images by means of a supervised image classification, Powder Technol., 322(2017), p. 214. doi: 10.1016/j.powtec.2017.08.063
    [60]
    M.J. Mankosa, J.N. Kohmuench, L. Christodoulou, and G.H. Luttrell, Recovery of values from a porphory copper tailings stream, [in] The XXVIII International Mineral Processing Congress, Quebec, 2016, p. 11.
    [61]
    S. Agheli, A. Hassanzadeh, B.V. Hassas, and M. Hasanzadeh, Effect of pyrite content of feed and configuration of locked particles on rougher flotation of copper in low and high pyritic ore types, Int. J. Min. Sci. Technol., 28(2018), No. 2, p. 167. doi: 10.1016/j.ijmst.2017.12.002
    [62]
    S.M. Bulatovic, D.M. Wyslouzil, and C. Kant, Operating practices in the beneficiation of major porphyry copper/molybdenum plants from Chile: Innovated technology and opportunities, a review, Miner. Eng., 11(1998), No. 4, p. 313. doi: 10.1016/S0892-6875(98)00011-9
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)  / Tables(2)

    Share Article

    Article Metrics

    Article Views(3398) PDF Downloads(143) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return