Xiao-chun Wen, Lei Guo, Qi-peng Bao, and Zhan-cheng Guo, Rapid removal of copper impurity from bismuth–copper alloy melts via super-gravity separation, Int. J. Miner. Metall. Mater., 28(2021), No. 12, pp. 1929-1939. https://doi.org/10.1007/s12613-020-2118-9
Cite this article as:
Xiao-chun Wen, Lei Guo, Qi-peng Bao, and Zhan-cheng Guo, Rapid removal of copper impurity from bismuth–copper alloy melts via super-gravity separation, Int. J. Miner. Metall. Mater., 28(2021), No. 12, pp. 1929-1939. https://doi.org/10.1007/s12613-020-2118-9
Research ArticleCover Article

Rapid removal of copper impurity from bismuth–copper alloy melts via super-gravity separation

+ Author Affiliations
  • Corresponding authors:

    Lei Guo    E-mail: leiguo@ustb.edu.cn

    Zhan-cheng Guo    E-mail: zcguo@ustb.edu.cn

  • Received: 26 April 2020Revised: 29 May 2020Accepted: 15 June 2020Available online: 17 June 2020
  • A green method of super-gravity separation, which can enhance the filtration process of bismuth and copper phases, was investigated and discussed for the rapid removal of copper impurity from bismuth–copper alloy melts. After separation by the super-gravity field, the bismuth-rich liquid phases were mainly filtered from the alloy melt along the super-gravity direction, whereas most of the fine copper phases were retained in the opposite direction. With optimized conditions of separation temperature at 280°C, gravity coefficient at 450, and separation time at 200 s, the mass proportion of the separated bismuth from the Bi–2wt%Cu and Bi–10wt%Cu alloys respectively reached 96% and 85% , which indicated the minimal loss of bismuth in the residual. Simultaneously, the removal ratio of impurity copper from the Bi–2wt%Cu and Bi–10wt%Cu alloys reached 88% and 98%, respectively. Furthermore, the separation process could be completed rapidly and is environmentally friendly and efficient.

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  • [1]
    F.K. Ojebuoboh, Bismuth—Production, properties, and applications, JOM, 44(1992), No. 4, p. 46. doi: 10.1007/BF03222821
    [2]
    Y.L. He, R.D. Xu, S.W. He, H.S. Chen, K. Li, Y. Zhu, and Q.F. Shen, Alkaline pressure oxidative leaching of bismuth-rich and arsenic-rich lead anode slime, Int. J. Miner. Metall. Mater., 26(2019), No. 6, p. 689. doi: 10.1007/s12613-019-1776-y
    [3]
    L.G. Wang, Metallurgy of Bismuth, Metallurgical Industry Press, Beijing, 1986, p. 99.
    [4]
    L.S. Chang, E. Rabkin, B.B. Straumal, B. Baretzky, and W. Gust, Thermodynamic aspects of the grain boundary segregation in Cu(Bi) alloys, Acta Mater., 47(1999), No. 15-16, p. 4041. doi: 10.1016/S1359-6454(99)00264-5
    [5]
    O. Akinlade, R.N. Singh, and F. Sommer, Thermodynamic investigation of viscosity in Cu–Bi and Bi–Zn liquid alloys, J. Alloys Compd., 267(1998), No. 1-2, p. 195. doi: 10.1016/S0925-8388(97)00547-1
    [6]
    W.Z. Guo, Study on Crystallization Refining of Crude Bismuth [Dissertation], Central South University, Changsha, 2014, p. 13.
    [7]
    Y. Chen, T. Liao, G.B. Li, B.Z. Chen, and X.C. Shi, Recovery of bismuth and arsenic from copper smelter flue dusts after copper and zinc extraction, Miner. Eng., 39(2012), p. 23. doi: 10.1016/j.mineng.2012.06.008
    [8]
    Y.N. Dai and B. Yang, Vacuum Metallurgy of Non-ferrous Metals, Metallurgical Industry Press, Beijing, 2009, p. 128.
    [9]
    J.T. Gao, L. Guo, Y.W. Zhong, H.R. Ren, and Z.C. Guo, Removal of phosphorus-rich phase from high-phosphorous iron ore by melt separation at 1573 K in a super-gravity field, Int. J. Miner. Metall. Mater., 23(2016), No. 7, p. 743. doi: 10.1007/s12613-016-1288-y
    [10]
    L. Meng, Z. Wang, Y.W. Zhong, K.Y. Chen, and Z.C. Guo, Supergravity separation of Pb and Sn from waste printed circuit boards at different temperatures, Int. J. Miner. Metall. Mater., 25(2018), No. 2, p. 173. doi: 10.1007/s12613-018-1560-4
    [11]
    C. Li, J.T. Gao, Z. Wang, and Z.C. Guo, Separation of fine Al2O3 inclusion from liquid steel with super gravity, Metall. Mater. Trans. B, 48(2017), No. 2, p. 900. doi: 10.1007/s11663-016-0905-5
    [12]
    L.X. Zhao, Z.C. Guo, Z. Wang, and M.Y. Wang, Removal of low-content impurities from Al by super-gravity, Metall. Mater. Trans. B, 41(2010), No. 3, p. 505. doi: 10.1007/s11663-010-9376-2
    [13]
    G.Y. Song, B. Song, Y.H. Yang, Z.B. Yang, and W.B. Xin, Separating behavior of nonmetallic inclusions in molten aluminum under super-gravity field, Metall. Mater. Trans. B, 46(2015), No. 5, p. 2190. doi: 10.1007/s11663-015-0403-1
    [14]
    X. Lan, J.T. Gao, Y. Li, and Z.C. Guo, A green method of respectively recovering rare earths (Ce, La, Pr, Nd) from rare-earth tailings under super-gravity, J. Hazard. Mater., 367(2019), p. 473. doi: 10.1016/j.jhazmat.2018.12.118
    [15]
    Z. Wang, J.T. Gao, A.J. Shi, L. Meng, and Z.C. Guo, Recovery of zinc from galvanizing dross by a method of super-gravity separation, J. Alloys Compd., 735(2018), p. 1997. doi: 10.1016/j.jallcom.2017.11.385
    [16]
    J.T. Gao, Z.L. Huang, Z.W. Wang, and Z.C. Guo, Recovery of crown zinc and metallic copper from copper smelter dust by evaporation, condensation and super-gravity separation, Sep. Purif. Technol., 231(2020), art. No. 115925. doi: 10.1016/j.seppur.2019.115925
    [17]
    Y.H. Yang, B. Song, G.Y. Song, Z.B. Yang, and W.B. Xin, Enriching and separating primary copper impurity from Pb-3 mass pct Cu melt by super-gravity technology, Metall. Mater. Trans. B, 47(2016), No. 5, p. 2714. doi: 10.1007/s11663-016-0714-x
    [18]
    L. Guo, X.C. Wen, Q.P. Bao, and Z.C. Guo, Removal of tramp elements within 7075 alloy by super-gravity aided rheorefining method, Metals, 8(2018), No. 9, art. No. 701. doi: 10.3390/met8090701
    [19]
    C. Li, J.T. Gao, Z. Wang, H.R. Ren, and Z.C. Guo, Separation of Fe-bearing and P-bearing phase from the steelmaking slag by super gravity, ISIJ Int., 57(2017), No. 4, p. 767. doi: 10.2355/isijinternational.ISIJINT-2016-694
    [20]
    Y. Lu, J.T. Gao, F.Q. Wang, and Z.C. Guo, Separation of anosovite from modified titanium-bearing slag melt in a reducing atmosphere by supergravity, Metall. Mater. Trans. B, 48(2017), No. 2, p. 749. doi: 10.1007/s11663-016-0868-6
    [21]
    J.T. Gao, Y.W. Zhong, and Z.C. Guo, Selective precipitation and concentrating of perovskite crystals from titanium-bearing slag melt in supergravity field, Metall. Mater. Trans. B, 47(2016), No. 4, p. 2459. doi: 10.1007/s11663-016-0716-8
    [22]
    X. Lan, J.T. Gao, Z.L. Huang, and Z.C. Guo, Rapid separation of copper phase and iron-rich phase from copper slag at low temperature in a super-gravity field, Metall. Mater. Trans. B, 49(2018), No. 3, p. 1165. doi: 10.1007/s11663-018-1235-6
    [23]
    O. Teppo, J. Niemelä and P. Taskinen, An assessment of the thermodynamic properties and phase diagram of the system Bi-Cu, Thermochim. Acta, 173(1990), p. 137. doi: 10.1016/0040-6031(90)80598-S
    [24]
    Y. Watanabe, Y. Inaguma, H. Sato, and E. Miura-Fujiwara, A novel fabrication method for functionally graded materials under centrifugal force: The centrifugal mixed-powder method, Materials, 2(2009), No. 4, p. 2510. doi: 10.3390/ma2042510
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