advanced
Article Contents
Turn off MathJax
Related articles
Article Navigation >  International Journal of Minerals, Metallurgy and Materials  > 2020 > Accepted Manuscript

Cite this article as:
shu

Research Article

Liquid-liquid extraction of phosphorus from sulfuric acid solution using benzyl-di-methyl amine

+ Author Affiliations
  • Received: 18 May 2020; Revised: 5 July 2020; Accepted: 21 July 2020; Available online: 24 July 2020
  • This study addresses the liquid-liquid extraction behavior of phosphorus from a sulfuric acid solution using benzyl-di-methyl amine (BDMA) in kerosene. The extraction equilibria investigated with varied BDMA concentration could reveal the formation of ¯(3[BDMA].[H3PO4]) into the organic phase. The thermodynamic properties determined at the different temperatures indicated that the process exhibits exothermic nature with a calculated enthalpy (ΔH°) of −24.0 kJ/mol. The organic-to-aqueous phase ratio (O/A) was varied to elucidate the quantitative extraction of phosphorus. The McCabe–Thiele diagram plotted for the extraction isotherm was validated for the requirement of three counter-current stages in extraction at an O/A ratio, 2.0/3.5. The back-extraction of phosphorus from the loaded organic phase was quantitatively achieved by contacting 4.0 mol/L H2SO4 solution in three stages of counter-current contact at an O/A ratio, 3/2. The study can potentially be applied to phosphorus removal from sulphuric acid leach solution of monazite processing and many other solutions.
  • 加载中

    •  

  • [1] Sajjad Ali,Yaseen Iqbal,Inamullah Khan,Ansar Ullah,Muhammad Sadiq,Muhammad Fahad, and Khizar Hussain Shah, Hydrometallurgical leaching and Kinetic modeling of low grade manganese ore with banana peel in sulfuric acid, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-020-2069-1
    [2] Shu-qiang Jiao,Han-dong Jiao,Wei-li Song,Ming-yong Wang, and Ji-guo Tu, A review on liquid metals as cathodes for molten salt/oxide electrolysis, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-020-1971-x
    [3] Xiao-yi Shen,Hong-mei Shao,Ji-wen Ding,Yan Liu,Hui-min Gu, and Yu-chun Zhai, Zinc extraction from zinc oxidized ore using (NH4)2SO4 roasting−leaching process, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-020-2015-2
    [4] Miryala Sushma and Masato Murakami, Special variation of infiltration-growth processed bulk YBCO fabricated using new liquid source: Ba3Cu5O8 (1:1.3) and YbBa2Cu3Oy , Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-020-2213-y
    [5] Bao Liu,Shuo Wang,Cheng-yan Wang,Bao-zhong Ma, and Yong-qiang Chen, Electrochemical behavior and corrosion resistance of IrO2–ZrO2 binary oxide coatings for promoting oxygen evolution in sulfuric acid solution, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-019-1847-0
    [6] Fei Cao,Wei Wang,De-zhou Wei, and Wen-gang Liu, Separation of tungsten and molybdenum with solvent extraction using functionalized ionic liquid tricaprylmethylammonium bis(2,4,4-trimethylpentyl) phosphinate, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-020-2172-3
    [7] Sergei Galyshev, Andrew Gomzin, Rida Gallyamova, Igor Khodos, and  Fanil Musin, On the liquid-phase technology of carbon fiber/aluminum matrix composites, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-019-1877-7
    [8] Jon Derek Loftis and  Tarek M. Abdel-Fattah, Nanoscale electropolishing of high-purity nickel with an ionic liquid, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-019-1773-1
    [9] Peijia Lin, Jiajia Wu, Junmo Ahn, and  Jaeheon Lee, Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-019-1832-7
    [10] Hendrik Setiawan, Himawan Tri Bayu Murti Petrus, and  Indra Perdana, Reaction kinetics modeling for lithium and cobalt recovery from spent lithium-ion batteries using acetic acid, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-019-1713-0
    [11] Yi-hong Li, Yan-ping Bao, Rui Wang, Li-feng Ma, and  Jian-sheng Liu, Modeling study on the flow patterns of gas-liquid flow for fast decarburization during the RH process, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-018-1558-y
    [12] Xing Zhao, Hong-liang Zhao, Li-feng Zhang, and  Li-qiang Yang, Gas-liquid mass transfer and flow phenomena in the Peirce-Smith converter: a water model study, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-018-1544-4
    [13] Zhi-yong Liu, Ying Cheng, Yan-xiang Li, Xu Zhou, Xiang Chen, and  Ning-zhen Wang, Shape formation of closed-cell aluminum foam in solid–liquid–gas coexisting state, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-018-1647-y
    [14] Yong-tao Zhang, Zhi-gang Dan, Ning Duan, and  Bao-ping Xin, Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-018-1649-9
    [15] Nathália Vieceli, Carlos A. Nogueira, Manuel F. C. Pereira, Fernando O. Durão, Carlos Guimarães, and  Fernanda Margarido, Optimization of an innovative approach involving mechanical activation and acid digestion for the extraction of lithium from lepidolite, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-018-1541-7
    [16] Jin-lin Yang, Ji-guang Liu, Han-xin Xiao, and  Shao-jian Ma, Sulfuric acid leaching of high iron-bearing zinc calcine, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-017-1513-3
    [17] Pei-yang Shi, Cheng-jun Liu, Qing Zhao, and  Hao-nan Shi, Study on mechanisms of different sulfuric acid leaching technologies of chromite, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-017-1486-2
    [18] Zela T. Ichlas and  Don C. Ibana, Process development for the direct solvent extraction of nickel and cobalt from nitrate solution:aluminum, cobalt, and nickel separation using Cyanex 272, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-017-1376-7
    [19] Qing Zhao, Cheng-jun Liu, Bao-kuan Li, and  Mao-fa Jiang, Decomposition mechanism of chromite in sulfuric acid-dichromic acid solution, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-017-1528-9
    [20] F. Maddah, M. Alitabar, and  H. Yoozbashizadeh, Reductive leaching of indium from the residue of neutral leaching by using oxalic acid in sulfuric acid solution, Int. J. Miner. Metall. Mater., https://doi.org/10.1007/s12613-020-1974-7
  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Cite this Article
PDF
XML

Share Article

Article Metrics

Article views(454) PDF downloads(10) Cited by()

Proportional views

Liquid-liquid extraction of phosphorus from sulfuric acid solution using benzyl-di-methyl amine

  • Corresponding author:

    Hyunjung Kim    E-mail: kshjkim@jbnu.ac.kr

  • 1. Department of Mineral Resources and Energy Engineering, Jeonbuk National University, Jeonju, Jeonbuk 54896, Republic of Korea
  • 2. Center for Advanced Chemistry, Institute of Research and Development, Duy Tan University, Da Nang 550000, Vietnam
  • 3. Faculty of Natural Sciences, Duy Tan University, Da Nang 550000, Vietnam
    Received: 18 May 2020
    Revised: 5 July 2020
    Accepted: 21 July 2020
    Available online: 24 July 2020

Abstract: This study addresses the liquid-liquid extraction behavior of phosphorus from a sulfuric acid solution using benzyl-di-methyl amine (BDMA) in kerosene. The extraction equilibria investigated with varied BDMA concentration could reveal the formation of ¯(3[BDMA].[H3PO4]) into the organic phase. The thermodynamic properties determined at the different temperatures indicated that the process exhibits exothermic nature with a calculated enthalpy (ΔH°) of −24.0 kJ/mol. The organic-to-aqueous phase ratio (O/A) was varied to elucidate the quantitative extraction of phosphorus. The McCabe–Thiele diagram plotted for the extraction isotherm was validated for the requirement of three counter-current stages in extraction at an O/A ratio, 2.0/3.5. The back-extraction of phosphorus from the loaded organic phase was quantitatively achieved by contacting 4.0 mol/L H2SO4 solution in three stages of counter-current contact at an O/A ratio, 3/2. The study can potentially be applied to phosphorus removal from sulphuric acid leach solution of monazite processing and many other solutions.

    HTML

Catalog

    About IJMMM

    For Authors

    Browse IJMMM

    Copyright © 2019 Editorial Office of International Journal of Minerals, Metallurgy and Materials 京ICP备07030729号

    Supported by: Beijing Renhe Information Technology Co. Ltd  Email: info@rhhz.net  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return