Xuemin Qiu, Hongying Yang, Guobao Chen, Linlin Tong, Zhenan Jin, and Qin Zhang, Interface behavior of chalcopyrite during flotation from cyanide tailings, Int. J. Miner. Metall. Mater., 29(2022), No. 3, pp. 439-445. https://doi.org/10.1007/s12613-020-2170-5
Cite this article as:
Xuemin Qiu, Hongying Yang, Guobao Chen, Linlin Tong, Zhenan Jin, and Qin Zhang, Interface behavior of chalcopyrite during flotation from cyanide tailings, Int. J. Miner. Metall. Mater., 29(2022), No. 3, pp. 439-445. https://doi.org/10.1007/s12613-020-2170-5
Research Article

Interface behavior of chalcopyrite during flotation from cyanide tailings

+ Author Affiliations
  • Corresponding author:

    Hongying Yang    E-mail: yanghy@smm.neu.edu.cn

  • Received: 20 June 2020Revised: 10 August 2020Accepted: 25 August 2020Available online: 27 August 2020
  • The interface characteristics of cyanide tailings are different from those of the raw ore. In this study, valuable elements could not be thoroughly recovered via the flotation of cyanide tailings from Shandong, China. The interface and floatability of these tailings were investigated by phase analysis and flotation tests. The chalcopyrite in the cyanide tailings was fine and had a porous surface. The floatability of 68% chalcopyrite was similar to that of galena in the presence of a collector. A layer of fine galena particles compactly wrapped the chalcopyrite. The chalcopyrite recovery sharply decreased as the nonpolar oil residue in cyanide tailings was extracted using alcohol; however, this removal had no effect on the galena. The remaining chalcopyrite in the flotation tailings was covered with an oxidation layer consisting of O, Fe, S, Pb, Cu, Zn, and Si.

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  • [1]
    G.M. Ritcey, Tailings management in gold plants, Hydrometallurgy, 78(2005), No. 1-2, p. 3. doi: 10.1016/j.hydromet.2005.01.001
    [2]
    D.B. Donato, O. Nichols, H. Possingham, M. Moore, P.F. Ricci, and B.N. Noller, A critical review of the effects of gold cyanide-bearing tailings solutions on wildlife, Environ. Int., 33(2007), No. 7, p. 974. doi: 10.1016/j.envint.2007.04.007
    [3]
    S.R. Griffiths, G.B. Smith, D.B. Donato, and C.G. Gillespie, Factors influencing the risk of wildlife cyanide poisoning on a tailings storage facility in the Eastern Goldfields of Western Australia, Ecotoxicol. Environ. Saf., 72(2009), No. 5, p. 1579. doi: 10.1016/j.ecoenv.2009.02.010
    [4]
    R. Hamberg, G. Bark, C. Maurice, and L. Alakangas, Release of arsenic from cyanidation tailings, Miner. Eng., 93(2016), p. 57. doi: 10.1016/j.mineng.2016.04.013
    [5]
    H.Y. Li, H.L. Long, L.B. Zhang, S.H. Yin, S.W. Li, F. Zhu, and H.M. Xie, Effectiveness of microwave-assisted thermal treatment in the extraction of gold in cyanide tailings, J. Hazard. Mater., 384(2020), art. No. 121456. doi: 10.1016/j.jhazmat.2019.121456
    [6]
    H.Y. Li, A.Y. Ma, C. Srinivasakannan, L.B. Zhang, S.W. Li, and S.H. Yin, Investigation on the recovery of gold and silver from cyanide tailings using chlorination roasting process, J. Alloys Compd., 763(2018), p. 241. doi: 10.1016/j.jallcom.2018.05.298
    [7]
    C.C. Lv, J. Ding, P. Qian, Q.C. Li, S.F. Ye, and Y.F. Chen, Comprehensive recovery of metals from cyanidation tailing, Miner. Eng., 70(2015), p. 141. doi: 10.1016/j.mineng.2014.09.007
    [8]
    X.L. Yang, X. Huang, and T.S. Qiu, Recovery of zinc from cyanide tailings by flotation, Miner. Eng., 84(2015), p. 100. doi: 10.1016/j.mineng.2015.10.003
    [9]
    Y.L. Zhang, H.M. Li, and X.J. Yu, Recovery of iron from cyanide tailings with reduction roasting–water leaching followed by magnetic separation, J. Hazard. Mater., 213-214(2012), p. 167. doi: 10.1016/j.jhazmat.2012.01.076
    [10]
    C.C. Lü, J. Ding, G.Y. Fu, Y. Liu, Y.G. Lu, P. Qian, and S.F. Ye, Present situation and prospect of recovering valuable elements from cyanidation tailing, CIESC J., 67(2016), No. 4, p. 1079.
    [11]
    S.C. Qiu, Z. Hu, and X.Y. Qiu, Research status of gold extraction process of roasting cyanide tailings, Precious Met., 40(2019), No. 3, p. 84.
    [12]
    L.G. Sun, Y.C. Chang, X.H. Xu, H.H. Huang, Y. Wang, and L. Zhang, The main technology status and development trend of harmless and resourceful utilization of cyanide tailings, China Resour. Compr. Util., 35(2017), No. 10, p. 59.
    [13]
    J. Wang, W.L. Chen, Z.L. Jiao, and X.Q. Peng, Research progress on recovering gold and silver from cyanide residues, Conserv. Util. Miner. Resour., 4(2014), p. 54.
    [14]
    H. Liu, Y.M. Zhu, Y.W. Ma, Y.X. Han, and Y.J. Li, Study on flotation and recovery technology for pyrite and sphalerite in cyanidation tailings, Multipurpose Util. Miner. Resour., 2017, No. 2, p. 99.
    [15]
    H.H. Huang, L. Wang, Y. Wang, Y. Li, L.G. Sun, and Y.C. Chang, Research on the process mineralogy of certain slag from gold extraction, Gold, 2(2016), p. 64.
    [16]
    X.M. Qiu, H.Y. Yang, G.B. Chen, and S.X. Zhao, Interface characteristics of lead and copper minerals from ultra-fine cyanide tailings, J. Northeast. Univ. Nat. Sci., 1(2019), p. 58.
    [17]
    Y. Zhang, B.N. Jiang, Y.H. Wang, and J.C. Gong, Study on physical phase analysis of lead in cyanidation tailings, Gold, 10(2014), p. 81.
    [18]
    F.S. Yao, Application of large tower mill in cyanide fine grinding of gold concentrate, Gold Sci. Technol., 22(2014), No. 3, p. 82.
    [19]
    J.H. Kyle, P.L. Breuer, K.G. Bunney, and R. Pleysier, Review of trace toxic elements (Pb, Cd, Hg, As, Sb, Bi, Se, Te) and their deportment in gold processing: Part II: Deportment in gold ore processing by cyanidation, Hydrometallurgy, 111-112(2012), p. 10. doi: 10.1016/j.hydromet.2011.09.005
    [20]
    H. Wang, S.M. Wen, G. Han, L. Xu, and Q.C. Feng, Activation mechanism of lead ions in the flotation of sphalerite depressed with zinc sulfate, Miner. Eng., 146(2020), art. No. 106132. doi: 10.1016/j.mineng.2019.106132
    [21]
    W.J. Zhao, D.W. Liu, and Q.C. Feng, Enhancement of salicylhydroxamic acid adsorption by Pb(II) modified hemimorphite surfaces and its effect on floatability, Miner. Eng., 152(2020), art. No. 106373. doi: 10.1016/j.mineng.2020.106373
    [22]
    E. Forbes, Shear, selective and temperature responsive flocculation: A comparison of fine particle flotation techniques, Int. J. Miner. Process., 99(2011), No. 1-4, p. 1. doi: 10.1016/j.minpro.2011.02.001
    [23]
    T. Miettinen, J. Ralston, and D. Fornasiero, The limits of fine particle flotation, Miner. Eng., 23(2010), No. 5, p. 420. doi: 10.1016/j.mineng.2009.12.006
    [24]
    Y.X. Yu, L.Q. Ma, M.L. Cao, and Q. Liu, Slime coatings in froth flotation: A review, Miner. Eng., 114(2017), p. 26. doi: 10.1016/j.mineng.2017.09.002
    [25]
    B. Guo, Y.J. Peng, and R. Espinosa-Gomez, Cyanide chemistry and its effect on mineral flotation, Miner. Eng., 66-68(2014), p. 25. doi: 10.1016/j.mineng.2014.06.010
    [26]
    C.A. Johnson, The fate of cyanide in leach wastes at gold mines: An environmental perspective, Appl. Geochem., 57(2015), p. 194. doi: 10.1016/j.apgeochem.2014.05.023
    [27]
    N. Kuyucak and A. Akcil, Cyanide and removal options from effluents in gold mining and metallurgical processes, Miner. Eng., 50-51(2013), p. 13. doi: 10.1016/j.mineng.2013.05.027
    [28]
    Y.W. Ma, Y.X. Han, Y.M. Zhu, Y.J. Li, and H. Liu, Flotation behaviors and mechanisms of chalcopyrite and galena after cyanide treatment, Trans. Nonferrous Met. Soc. China, 26(2016), No. 12, p. 3245. doi: 10.1016/S1003-6326(16)64457-6
    [29]
    A.D. Bas, E. Koc, E.Y. Yazici, and H. Deveci, Treatment of copper-rich gold ore by cyanide leaching, ammonia pretreatment and ammoniacal cyanide leaching, Trans. Nonferrous Met. Soc. China, 25(2015), No. 2, p. 597. doi: 10.1016/S1003-6326(15)63642-1
    [30]
    J.C. Wilmot, The Chemistry of Cyanide in the Presence of Reduced Sulfur Sources [Dissertation], University of Nebraska–Lincoln, Lincoln, 1997, p.143.
    [31]
    Ü. Akdemir, Shear flocculation of fine hematite particles and correlation between flocculation, flotation and contact angle, Powder Technol., 94(1997), No. 1, p. 1. doi: 10.1016/S0032-5910(97)03216-6
    [32]
    B.A. Wills and J.A. Finch. Wills’ Mineral Processing Technology: An Introduction to the Practical Aspects of Ore Treatment and Mineral Recovery, Butterworth Heinemann, Oxford, 2016, p. 66.
    [33]
    T.S. Qiu, X. Huang, and X.L. Yang, Recovery of copper from cyanidation tailing by flotation, JOM, 68(2016), No. 2, p. 548. doi: 10.1007/s11837-015-1726-8
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