Yao-yu Yin, Yan-bai Shen, Si-kai Zhao, Ang Li, Rui Lu, Cong Han, Bao-yu Cui, and De-zhou Wei, Enhanced detection of ppb-level NO2 by uniform Pt-doped ZnSnO3 nanocubes, Int. J. Miner. Metall. Mater.,(2020). https://doi.org/10.1007/s12613-020-2215-9
Cite this article as:
Yao-yu Yin, Yan-bai Shen, Si-kai Zhao, Ang Li, Rui Lu, Cong Han, Bao-yu Cui, and De-zhou Wei, Enhanced detection of ppb-level NO2 by uniform Pt-doped ZnSnO3 nanocubes, Int. J. Miner. Metall. Mater.,(2020). https://doi.org/10.1007/s12613-020-2215-9
Research Article

Enhanced detection of ppb-level NO2 by uniform Pt-doped ZnSnO3 nanocubes

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  • Received: 7 August 2020Revised: 19 October 2020Accepted: 20 October 2020Available online: 21 October 2020
  • ZnSnO3 nanocubes (ZSNCs) with various Pt concentrations (1at%, 2at%, and 5at%) were synthesized by the high-yield and facile one-pot hydrothermal method. The microstructures of the obtained products were characterized by XRD, FESEM, TEM, EDS and XPS. The results showed that the ZSNCs with perovskite structure are approximately 600 nm in side length, and this size was reduced to 400 nm after Pt doping. PtOx (PtO and PtO2) nanoparticle with the diameter of about 5 nm were uniformly coated on the surface of ZSNCs. NO2 sensing properties showed that 1% Pt-ZSNCs exhibited the highest response to NO2 than pure ZSNCs and Pt-ZSNCs with other Pt concentrations. The maximum response of 1 at% Pt-ZSNCs to 500 ppb NO2 was 16.0 at the optimal operating temperature of 125 °C, which was over 11 times higher than that of pure ZSNCs. The enhanced NO2 sensing mechanisms of Pt-ZSNCs were discussed in consideration of catalytic activities and chemical sensitization of Pt doping.
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