Li-fan Wang, Meng-meng Geng, Xia-nan Ding, Chen Fang, Yu Zhang, Shan-shan Shi, Yong Zheng, Kai Yang, Chun Zhan, and Xin-dong Wang, Research progress of the electrochemical impedance technique applied to the high-capacity lithium-ion battery, Int. J. Miner. Metall. Mater., 28(2021), No. 4, pp. 538-552. https://doi.org/10.1007/s12613-020-2218-6
Cite this article as:
Li-fan Wang, Meng-meng Geng, Xia-nan Ding, Chen Fang, Yu Zhang, Shan-shan Shi, Yong Zheng, Kai Yang, Chun Zhan, and Xin-dong Wang, Research progress of the electrochemical impedance technique applied to the high-capacity lithium-ion battery, Int. J. Miner. Metall. Mater., 28(2021), No. 4, pp. 538-552. https://doi.org/10.1007/s12613-020-2218-6
Invited Review

Research progress of the electrochemical impedance technique applied to the high-capacity lithium-ion battery

+ Author Affiliations
  • Corresponding author:

    Xin-dong Wang    E-mail: echem@ustb.edu.cn

  • Received: 23 July 2020Revised: 28 October 2020Accepted: 2 November 2020Available online: 4 November 2020
  • The world’s energy system is changing dramatically. Li-ion battery, as a powerful and highly effective energy storage technique, is crucial to the new energy revolution for its continuously expanding application in electric vehicles and grids. Over the entire lifetime of these power batteries, it is essential to monitor their state of health not only for the predicted mileage and safety management of the running electric vehicles, but also for an “end-of-life” evaluation for their repurpose. Electrochemical impedance spectroscopy (EIS) has been widely used to diagnose the health state of batteries quickly and nondestructively. In this review, we have outlined the working principles of several electrochemical impedance techniques and further evaluated their application prospects to achieve the goal of nondestructive testing of battery health. EIS can scientifically and reasonably perform real-time monitoring and evaluation of electric vehicle power batteries in the future and play an important role in vehicle safety and battery gradient utilization.
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  • [1]
    W.D. Li, E.M. Erickson, and A. Manthiram, High-nickel layered oxide cathodes for lithium-based automotive batteries, Nat. Energy, 5(2020), No. 1, p. 26. doi: 10.1038/s41560-019-0513-0
    [2]
    W. Huang, D.T. Boyle, Y.Z. Li, Y.B. Li, A. Pei, H. Chen, and Y. Cui, Nanostructural and electrochemical evolution of the solid-electrolyte interphase on CuO nanowires revealed by cryogenic-electron microscopy and impedance spectroscopy, ACS Nano, 13(2019), No. 1, p. 737. doi: 10.1021/acsnano.8b08012
    [3]
    V.V. Viswanathan and M. Kintner-Meyer, Second use of transportation batteries: Maximizing the value of batteries for transportation and grid services, IEEE Trans. Veh. Technol., 60(2011), No. 7, p. 2963. doi: 10.1109/TVT.2011.2160378
    [4]
    D.M. Cheng, J. Zhou, J. Li, C.G. Du, and H. Zhang, Analysis in power battery gradient utilization of electric vehicle, Adv. Mater. Res., 347-353(2011), p. 555. doi: 10.4028/www.scientific.net/AMR.347-353.555
    [5]
    J. Vetter, P. Novák, M.R. Wagner, C. Veit, K.C. Möller, J.O. Besenhard, M. Winter, M. Wohlfahrt-Mehrens, C. Vogler, and A. Hammouche, Ageing mechanisms in lithium-ion batteries, J. Power Sources, 147(2005), No. 1-2, p. 269. doi: 10.1016/j.jpowsour.2005.01.006
    [6]
    J. Groot, State-of-health Estimation of Li-ion Batteries: Cycle Life Test Methods [Dissertation], Chalmers University of Technology, 2012.
    [7]
    C. Schlasza, P. Ostertag, D. Chrenko, R. Kriesten, and D. Bouquain, Review on the aging mechanisms in Li-ion batteries for electric vehicles based on the FMEA method, 2014 IEEE Transp. Electrif. Conf. Expo Components, Syst. Power Electron.-From Technol. to Bus. Public Policy, ITEC 2014, (2014), p. 1.
    [8]
    J. Neubauer and A. Pesaran, The ability of battery second use strategies to impact plug-in electric vehicle prices and serve utility energy storage applications, J. Power Sources, 196(2011), No. 23, p. 10351. doi: 10.1016/j.jpowsour.2011.06.053
    [9]
    E. Locorotondo, V. Cultrera, L. Pugi, L. Berzi, M. Pasquali, N. Andrenacci, G. Lutzemberger, and M. Pierini, Electrical lithium battery performance model for second life applications, [in] 2020 IEEE International Conference on Environment and Electrical Engineering and 2020 IEEE Industrial and Commercial Power Systems Europe (EEEIC / I&CPS Europe), Madrid, Spain, 2020, doi: 10.1109/EEEIC/ICPSEurope49358.2020.9160496.
    [10]
    H.F. Dai, X.Z. Wei, and Z.C. Sun, State and parameter estimation of a HEV Li-ion battery pack using adaptive kalman filter with a new SOC-OCV concept, [in] 2009 International Conference on Measuring Technology and Mechatronics Automation, Zhangjiajie, 2009, p. 375.
    [11]
    G. Nagasubramanian, Two- and three-electrode impedance studies on 18650 Li-ion cells, J. Power Sources, 87(2000), No. 1-2, p. 226. doi: 10.1016/S0378-7753(99)00469-3
    [12]
    J. Li, E. Murphy, J. Winnick, and P.A. Kohl, Studies on the cycle life of commercial lithium ion batteries during rapid charge-discharge cycling, J. Power Sources, 102(2001), No. 1-2, p. 294. doi: 10.1016/S0378-7753(01)00821-7
    [13]
    E. Locorotondo, V. Cultrera, L. Pugi, L. Berzi, M. Pasquali, N. Andrenacci, G. Lutzemberger, and M. Pierini, Impedance spectroscopy characterization of lithium batteries with different ages in second life application, [in] 2020 IEEE International Conference on Environment and Electrical Engineering and 2020 IEEE Industrial and Commercial Power Systems Europe (EEEIC / I&CPS Europe), Madrid, Spain, 2020, doi: 10.1109/EEEIC/ICPSEurope49358.2020.9160616.
    [14]
    L. Berzi, V. Cultrera, M. Delogu, M. Dolfi, E. Locorotondo, F. Del Pero, S. Morosi, L. Pugi, and A. Tanturli, A model for system integration of second life battery, renewable energy generation and mobile network station, [in] 2020 IEEE International Conference on Environment and Electrical Engineering and 2020 IEEE Industrial and Commercial Power Systems Europe (EEEIC / I&CPS Europe), Madrid, Spain, 2020, doi: 10.1109/EEEIC/ICPSEurope49358.2020.9160747.
    [15]
    T. Osaka, T. Momma, D. Mukoyama, and H. Nara, Proposal of novel equivalent circuit for electrochemical impedance analysis of commercially available lithium ion battery, J. Power Sources, 205(2012), p. 483. doi: 10.1016/j.jpowsour.2012.01.070
    [16]
    D. Mukoyama, T. Momma, H. Nara, and T. Osaka, Electrochemical impedance analysis on degradation of commercially available lithium ion battery during charge-discharge cycling, Chem. Lett., 41(2012), No. 4, p. 444. doi: 10.1246/cl.2012.444
    [17]
    N. Togasaki, T. Yokoshima, Y. Oguma, and T. Osaka, Prediction of overcharge-induced serious capacity fading in nickel cobalt aluminum oxide lithium-ion batteries using electrochemical impedance spectroscopy, J. Power Sources, 461(2020), art. No. 228168. doi: 10.1016/j.jpowsour.2020.228168
    [18]
    S.S. Zhang, K. Xu, and T.R. Jow, EIS study on the formation of solid electrolyte interface in Li-ion battery, Electrochim. Acta, 51(2006), No. 8-9, p. 1636. doi: 10.1016/j.electacta.2005.02.137
    [19]
    F. Huet, A review of impedance measurements for determination of the state-of-charge or state-of-health of secondary batteries, J. Power Sources, 70(1998), No. 1, p. 59. doi: 10.1016/S0378-7753(97)02665-7
    [20]
    T. Hang, D. Mukoyama, H. Nara, N. Takami, T. Momma, and T. Osaka, Electrochemical impedance spectroscopy analysis for lithium-ion battery using Li4Ti5O12 anode, J. Power Sources, 222(2013), p. 442. doi: 10.1016/j.jpowsour.2012.09.010
    [21]
    E. Barsoukov, J.H. Kim, J.H. Kim, C.O. Yoon, and H. Lee, Kinetics of lithium intercalation into carbon anodes: In situ impedance investigation of thickness and potential dependence, Solid State Ionics, 116(1999), No. 3-4, p. 249.
    [22]
    H. Nara, T. Yokoshima, and T. Osaka, Technology of electrochemical impedance spectroscopy for an energy-sustainable society, Curr. Opin. Electrochem., 20(2020), p. 66. doi: 10.1016/j.coelec.2020.02.026
    [23]
    R. Srinivasan, B.G. Carkhuff, M.H. Butler, and A.C. Baisden, Instantaneous measurement of the internal temperature in lithium-ion rechargeable cells, Electrochim. Acta, 56(2011), No. 17, p. 6198. doi: 10.1016/j.electacta.2011.03.136
    [24]
    E. Azzarello, E. Masi, and S. Mancuso, Electrochemical impedance spectroscopy (EIS) study of LiNi1/3Co1/3Mn1/3O2 for Li-ion batteries, Int. J,Electrochem. Sci., 7(2012), p. 345.
    [25]
    D. Aurbach, K. Gamolsky, B. Markovsky, G. Salitra, Y. Gofer, U. Heider, R. Oesten, and M. Schmidt, The study of surface phenomena related to electrochemical lithium intercalation into LixMOy host materials (M=Ni, Mn), J. Electrochem. Soc., 147(2000), No. 4, p. 1322. doi: 10.1149/1.1393357
    [26]
    S.S. Zhang, K. Xu, and T.R. Jow, Understanding formation of solid electrolyte interface film on LiMn2O4 electrode, J. Electrochem. Soc., 149(2002), No. 12, p. A1521. doi: 10.1149/1.1516220
    [27]
    S.S. Zhang, K. Xu, and T.R. Jow, Formation of solid electrolyte interface in lithium nickel mixed oxide electrodes during the first cycling, Electrochem. Solid-State Lett., 5(2002), No. 5, p. A92. doi: 10.1149/1.1464506
    [28]
    R. Mingant, J. Bernard, and V. Sauvant-Moynot, Novel state-of-health diagnostic method for Li-ion battery in service, Appl. Energy, 183(2016), p. 390. doi: 10.1016/j.apenergy.2016.08.118
    [29]
    T. Yokoshima, D. Mukoyama, K. Nakazawa, Y. Gima, H. Isawa, H. Nara, T. Momma, and T. Osaka, Application of electrochemical impedance spectroscopy to ferri/ferrocyanide redox couple and lithium ion battery systems using a square wave as signal input, Electrochim. Acta, 180(2015), p. 922. doi: 10.1016/j.electacta.2015.08.083
    [30]
    S.M. Park and J.S. Yoo, Electrochemical impedance spectroscopy for better electrochemical measurements, Anal. Chem., 75(2003), No. 21, p. 455A.
    [31]
    B.Y. Chang, and S.M. Park, Fourier transform analysis of chronoamperometric currents obtained during staircase voltammetric experiments, Anal. Chem., 79(2007), No. 13, p. 4892. doi: 10.1021/ac070169w
    [32]
    S.M. Park, J.S. Yoo, B.Y. Chang, and E.S. Ahn, Novel instrumentation in electrochemical impedance spectroscopy and a full description of an electrochemical system, Pure Appl. Chem., 78(2006), No. 5, p. 1069. doi: 10.1351/pac200678051069
    [33]
    T. Yokoshima, D. Mukoyama, H. Nara, S. Maeda, K. Nakazawa, T. Momma, and T. Osaka, Impedance measurements of kilowatt-class lithium ion battery modules/cubicles in energy storage systems by square-current electrochemical impedance spectroscopy, Electrochim. Acta, 246(2017), p. 800. doi: 10.1016/j.electacta.2017.05.076
    [34]
    S.M. Park and J.S. Yoo, Apparatus and Method for Measuring Electrochemical Impedance at High Speed, United States Patent, Appl. 6339334 B1, 2002.
    [35]
    Y. Hoshi, N. Yakabe, K. Isobe, T. Saito, I. Shitanda, and M. Itagaki, Wavelet transformation to determine impedance spectra of lithium-ion rechargeable battery, J. Power Sources, 315(2016), p. 351. doi: 10.1016/j.jpowsour.2016.03.048
    [36]
    J. Hoja and G. Lentka, Method using square-pulse excitation for high-impedance spectroscopy of anticorrosion coatings, IEEE Trans. Instrum. Meas., 60(2011), No. 3, p. 957. doi: 10.1109/TIM.2010.2060219
    [37]
    M. Itagaki, M. Ueno, Y. Hoshi, and I. Shitanda, Simultaneous determination of electrochemical impedance of lithium-ion rechargeable batteries with measurement of charge-discharge curves by wavelet transformation, Electrochim. Acta, 235(2017), p. 384. doi: 10.1016/j.electacta.2017.03.077
    [38]
    J.H. Zhang, Impedance measurement and analysis for battery based on wavelet transformation, J. Jiamusi Univ. (Natural Science Edition), 36(2018), No. 1, p. 144.
    [39]
    M. Itagaki, Y. Gamano, Y. Hoshi, and I. Shitanda, Determination of electrochemical impedance of lithium ion battery from time series data by wavelet transformation-uncertainty of resolutions in time and frequency domains, Electrochim. Acta, 332(2020), art. No. 135462. doi: 10.1016/j.electacta.2019.135462
    [40]
    J. Wang, Y.Y. Yu, B. Li, P. Zhang, J.X. Huang, F. Wang, S.Y. Zhao, C.L. Gan, and J.B. Zhao, Thermal synergy effect between LiNi0.5Co0.2Mn0.3O2 and LiMn2O4 enhances the safety of blended cathode for lithium ion batteries, ACS Appl. Mater. Interfaces, 8(2016), No. 31, p. 20147. doi: 10.1021/acsami.6b06976
    [41]
    S. Lee and J. Kim, Discrete wavelet transform-based denoising technique for advanced state-of-charge estimator of a lithium-ion battery in electric vehicles, Energy, 83(2015), p. 462. doi: 10.1016/j.energy.2015.02.046
    [42]
    J. Huang, J.B. Zhang, Z. Li, S.L. Song, and N.N. Wu, Exploring differences between charge and discharge of LiMn2O4/Li half-cell with dynamic electrochemical impedance spectroscopy, Electrochim. Acta, 131(2014), p. 228. doi: 10.1016/j.electacta.2014.02.030
    [43]
    D. Chenvidhya, K. Kirtikara, and C. Jivacate, A new characterization method for solar cell dynamic impedance, Sol. Energy Mater. Sol. Cells, 80(2003), No. 4, p. 459. doi: 10.1016/j.solmat.2003.06.011
    [44]
    M. Itagaki, A. Ono, K. Watanabe, H. Katayama, and K. Noda, Analysis on organic film degradation by dynamic impedance measurements, Corros. Sci., 48(2006), No. 11, p. 3802. doi: 10.1016/j.corsci.2006.01.011
    [45]
    J. Huang, Z. Li, and J.B. Zhang, Dynamic electrochemical impedance spectroscopy reconstructed from continuous impedance measurement of single frequency during charging/discharging, J. Power Sources, 273(2015), p. 1098. doi: 10.1016/j.jpowsour.2014.07.067
    [46]
    T. Holm, S. Sunde, F. Seland, and D.A. Harrington, Understanding reaction mechanisms using dynamic electrochemical impedance spectroscopy: Methanol oxidation on Pt, Electrochim. Acta, 323(2019), art. No. 134764. doi: 10.1016/j.electacta.2019.134764
    [47]
    J. Huang, H. Ge, Z. Li, and J.B. Zhang, Dynamic electrochemical impedance spectroscopy of a three-electrode lithium-ion battery during pulse charge and discharge, Electrochim. Acta, 176(2015), p. 311. doi: 10.1016/j.electacta.2015.07.017
    [48]
    H.L. Liang, S. Yuan, L.Y. Shi, Y. Zhao, Z.Y. Wang, and J.F. Zhu, Highly-ordered microstructure and well performance of LiNi0.6Mn0.2Co0.2O2 cathode material via the continuous microfluidic synthesis, Chem. Eng. J., 394(2020), art. No. 124846. doi: 10.1016/j.cej.2020.124846
    [49]
    M. Itagaki, N. Kobari, S. Yotsuda, K. Watanabe, S. Kinoshita, and M. Ue, In situ electrochemical impedance spectroscopy to investigate negative electrode of lithium-ion rechargeable batteries, J. Power Sources, 135(2004), No. 1-2, p. 255. doi: 10.1016/j.jpowsour.2004.04.004
    [50]
    M. Itagaki, N. Kobari, S. Yotsuda, K. Watanabe, S. Kinoshita, and M. Ue, LiCoO2 electrode/electrolyte interface of Li-ion rechargeable batteries investigated by in situ electrochemical impedance spectroscopy, J. Power Sources, 148(2005), p. 78. doi: 10.1016/j.jpowsour.2005.02.007
    [51]
    M. Darab, P.K. Dahlstrøm, M.S. Thomassen, F. Seland, and S. Sunde, Dynamic electrochemical impedance spectroscopy of Pt/C-based membrane-electrode assemblies subjected to cycling protocols, J. Power Sources, 242(2013), p. 447. doi: 10.1016/j.jpowsour.2013.05.105
    [52]
    T. Pongklang, D. Chenvidhya, K. Kirtikara, S. Chuangchote, and N. Silsirivanich, Voltage and frequency dependent impedances of dye-sensitized solar cell, Energy Procedia, 52(2014), p. 536. doi: 10.1016/j.egypro.2014.07.107
    [53]
    P. Shafiei Sabet, A.J. Warnecke, F. Meier, H. Witzenhausen, E. Martinez-Laserna, and D.U. Sauer, Non-invasive yet separate investigation of anode/cathode degradation of lithium-ion batteries (nickel–cobalt–manganese vs. graphite) due to accelerated aging, J. Power Sources, 449(2020), art. No. 227369. doi: 10.1016/j.jpowsour.2019.227369
    [54]
    P. Shafiei Sabet and D.U. Sauer, Separation of predominant processes in electrochemical impedance spectra of lithium-ion batteries with nickel–manganese–cobalt cathodes, J. Power Sources, 425(2019), p. 121. doi: 10.1016/j.jpowsour.2019.03.068
    [55]
    Y. Zheng, Y.B. He, K. Qian, B.H. Li, X.D. Wang, J.L. Li, S.W. Chiang, C. Miao, F.Y. Kang, and J.B. Zhang, Deterioration of lithium iron phosphate/graphite power batteries under high-rate discharge cycling, Electrochim. Acta, 176(2015), p. 270. doi: 10.1016/j.electacta.2015.06.096
    [56]
    S.S. Zhang, K. Xu, and T.R. Jow, The low temperature performance of Li-ion batteries, J. Power Sources, 115(2003), No. 1, p. 137. doi: 10.1016/S0378-7753(02)00618-3
    [57]
    Z.T. Dong, Y. Li, K.L. Ren, S.Q. Yang, Y.M. Zhao, Y.J. Yuan, L. Zhang, and S.M. Han, Enhanced electrochemical properties of LaFeO3 with Ni modification for MH–Ni batteries, Int. J. Miner. Metall. Mater., 25(2018), No. 10, p. 1201. doi: 10.1007/s12613-018-1672-x
    [58]
    M.A. Iqbal and M. Fedel, Ordering and disordering of in situ grown MgAl-layered double hydroxide and its effect on the structural and corrosion resistance properties, Int. J. Miner. Metall. Mater., 26(2019), No. 12, p. 1570. doi: 10.1007/s12613-019-1844-3
    [59]
    A. Xiao, W.T. Li, and B.L. Lucht, Thermal reactions of mesocarbon microbead (MCMB) particles in LiPF6-based electrolyte, J. Power Sources, 162(2006), No. 2, p. 1282. doi: 10.1016/j.jpowsour.2006.07.054
    [60]
    J.Y. Zhang, X.Q. Yang, G.Q. Zhang, Q.Q. Huang, C.R. Xiao, and C.X. Yang, Investigation on the root cause of the decreased performances in the overcharged lithium iron phosphate battery, Int. J. Energy Res., 42(2018), No. 7, p. 2448. doi: 10.1002/er.4025
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