MOF-derived porous graphitic carbon with optimized plateau capacity and rate capability for high performance lithium ion capacitors

The development of anode materials with high rate capability and long charge-discharge plateau is the key to improve performance of lithium-ion capacitors (LICs). Herein, the porous graphitic carbon (PGC-1300) derived from a new triplyinterpenetrated cobalt metal-organic framework (Co-MOF) is prepared through the facile and robust carbonization at 1300 ^oC and washing by HCl solution. The as-prepared PGC-1300 features an optimized graphitization degree and porous framework, which not only contributes to high plateau capacity (105 mAh g^-1 below 0.2 V at 0.05 A g^-1), but also supplies more convenient pathways for ions and increases the rate capability (128.5 mAh g^-1 at 3.2 A g^-1). According to the kinetics analyses, it can be found that diffusion regulated surface induced capacitive process and Li-ions intercalation process are coexisted for lithium ion storage. Additionally, LIC PGC-1300//AC constructed with pre-lithiated PGC-1300 anode and activated carbon (AC) cathode exhibits an increased energy density of 102.8 Wh kg^-1, a power density of 6017.1 W kg^-1, together with the excellent cyclic stability (91.6% retention after 10000 cycles at 1 A g^-1).