Han Dang, Runsheng Xu, Jianliang Zhang, Mingyong Wang, and Jinhua Li, Cross-upgrading of biomass hydrothermal carbonization and pyrolysis for high quality blast furnace injection fuel production: Physicochemical characteristics and gasification kinetics analysis, Int. J. Miner. Metall. Mater., 31(2024), No. 2, pp. 268-281. https://doi.org/10.1007/s12613-023-2728-0
Cite this article as:
Han Dang, Runsheng Xu, Jianliang Zhang, Mingyong Wang, and Jinhua Li, Cross-upgrading of biomass hydrothermal carbonization and pyrolysis for high quality blast furnace injection fuel production: Physicochemical characteristics and gasification kinetics analysis, Int. J. Miner. Metall. Mater., 31(2024), No. 2, pp. 268-281. https://doi.org/10.1007/s12613-023-2728-0
Research Article

Cross-upgrading of biomass hydrothermal carbonization and pyrolysis for high quality blast furnace injection fuel production: Physicochemical characteristics and gasification kinetics analysis

+ Author Affiliations
  • Corresponding authors:

    Runsheng Xu    E-mail: xu_runsheng@163.com

    Jinhua Li    E-mail: 1304503396@qq.com

  • Received: 4 May 2023Revised: 25 July 2023Accepted: 16 August 2023Available online: 18 August 2023
  • The paper proposes a biomass cross-upgrading process that combines hydrothermal carbonization and pyrolysis to produce high-quality blast furnace injection fuel. The results showed that after upgrading, the volatile content of biochar ranged from 16.19% to 45.35%, and the alkali metal content, ash content, and specific surface area were significantly reduced. The optimal route for biochar production is hydrothermal carbonization–pyrolysis (P-HC), resulting in biochar with a higher calorific value, C=C structure, and increased graphitization degree. The apparent activation energy (E) of the sample ranges from 199.1 to 324.8 kJ/mol, with P-HC having an E of 277.8 kJ/mol, lower than that of raw biomass, primary biochar, and anthracite. This makes P-HC more suitable for blast furnace injection fuel. Additionally, the paper proposes a path for P-HC injection in blast furnaces and calculates potential environmental benefits. P-HC offers the highest potential for carbon emission reduction, capable of reducing emissions by 96.04 kg/t when replacing 40wt% coal injection.
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  • [1]
    J.L. Zhang, H.Y. Fu, Y.X. Liu, et al., Review on biomass metallurgy: Pretreatment technology, metallurgical mechanism and process design, Int. J. Miner. Metall. Mater., 29(2022), No. 6, p. 1133. doi: 10.1007/s12613-022-2501-9
    J. Zhao, H.B. Zuo, J.S. Wang, et al., The mechanism and products for co-thermal extraction of biomass and low-rank coal with NMP, Int. J. Miner. Metall. Mater., 26(2019), No. 12, p. 1512. doi: 10.1007/s12613-019-1872-z
    J.L. Zhang, J. Guo, G.W. Wang, et al., Kinetics of petroleum coke/biomass blends during co-gasification, Int. J. Miner. Metall. Mater., 23(2016), No. 9, p. 1001. doi: 10.1007/s12613-016-1317-x
    H.B. Zuo, W.W. Geng, J.L. Zhang, et al., Comparison of kinetic models for isothermal CO2 gasification of coal char–biomass char blended char, Int. J. Miner. Metall. Mater., 22(2015), No. 4, p. 363. doi: 10.1007/s12613-015-1081-3
    N. Karali, T.F. Xu, and J. Sathaye, Reducing energy consumption and CO2 emissions by energy efficiency measures and international trading: A bottom-up modeling for the U.S. iron and steel sector, Appl. Energy, 120(2014), p. 133. doi: 10.1016/j.apenergy.2014.01.055
    M, Hasanuzzaman, N.A. Rahim, M. Hosenuzzaman, et al., Energy savings in the combustion based process heating in industrial sector, Renewable Sustainable Energy Rev., 16(2012), No. 7, p. 4527. doi: 10.1016/j.rser.2012.05.027
    K. Yan, C.W. Liu, L.P. Liu, et al., Pyrolysis behaviour and combustion kinetics of waste printed circuit boards, Int. J. Miner. Metall. Mater., 29(2022), No. 9, p. 1722. doi: 10.1007/s12613-021-2299-x
    S.N. Xiu and A. Shahbazi, Bio-oil production and upgrading research: A review, Renew. Sustainable Energy Rev., 16(2012), No. 7, p. 4406. doi: 10.1016/j.rser.2012.04.028
    R. Saidur, E.A. Abdelaziz, A. Demirbas, M.S. Hossain, and S. Mekhilef, A review on biomass as a fuel for boilers, Renewable Sustainable Energy Rev., 15(2011), No. 5, p. 2262. doi: 10.1016/j.rser.2011.02.015
    Q. Gao, G. Zhang, H. Zheng, et al., Combustion performance of pulverized coal and corresponding kinetics study after adding the additives of Fe2O3 and CaO, Int. J. Miner. Metall. Mater., 30(2023), No. 2, p. 314. doi: 10.1007/s12613-022-2432-5
    D. Zhang, H. Fan, B. Zhao, et al., Development of biomass power generation technology at home and abroad, Huadian Technol., 43(2021), No. 03, p. 70.
    G. Wang, J. Zhang, J. Shao, et al., Thermal behavior and kinetic analysis of co-combustion of waste biomass/low rank coal blends, Energy Convers. Manage., 124(2016), p. 414. doi: 10.1016/j.enconman.2016.07.045
    P. Wang, G.W. Wang, J.L. Zhang, J.Y. Lee, Y.J. Li, and C. Wang, Co-combustion characteristics and kinetic study of anthracite coal and palm kernel shell char, Appl. Therm. Eng., 143(2018), p. 736. doi: 10.1016/j.applthermaleng.2018.08.009
    Y.S. Sun, Y.X. Han, Y.F. Li, et al., Formation and characterization of metallic iron grains in coal-based reduction of oolitic iron ore, Int. J. Miner. Metall. Mater., 24(2017), No. 2, p. 123. doi: 10.1007/s12613-017-1386-5
    G.W. Wang, J.L. Zhang, J.Y. Lee, et al., Hydrothermal carbonization of maize straw for hydrochar production and its injection for blast furnace, Appl. Energy, 266(2020), art. No. 114818. doi: 10.1016/j.apenergy.2020.114818
    J. Minaret and A. Dutta, Comparison of liquid and vapor hydrothermal carbonization of corn husk for the use as a solid fuel, Bioresour. Technol., 200(2016), p. 804. doi: 10.1016/j.biortech.2015.11.010
    H. Fatehi and X.S. Bai, Structural evolution of biomass char and its effect on the gasification rate, Appl. Energy, 185(2017), p. 998. doi: 10.1016/j.apenergy.2015.12.093
    Z.G. Liu, A. Quek, S. Kent Hoekman, et al., Production of solid biochar fuel from waste biomass by hydrothermal carbonization, Fuel, 103(2013), p. 943. doi: 10.1016/j.fuel.2012.07.069
    T.L. Eberhardt, W.J. Catallo, and T.F. Shupe, Hydrothermal transformation of Chinese privet seed biomass to gas-phase and semi-volatile products, Bioresour. Technol., 101(2010), No. 11, p. 4198. doi: 10.1016/j.biortech.2010.01.064
    M. Goto, R. Obuchi, T. Hirose, et al., Hydrothermal conversion of municipal organic waste into resources, Bioresour. Technol., 93(2004), No. 3, p. 279. doi: 10.1016/j.biortech.2003.11.017
    M.I.G. Miranda, C.I.D. Bica, S.M.B. Nachtigall, et al., Kinetical thermal degradation study of maize straw and soybean hull celluloses by simultaneous DSC–TGA and MDSC techniques, Thermochim. Acta, 565(2013), p. 65. doi: 10.1016/j.tca.2013.04.012
    W. Liang, G.W. Wang, K.X. Jiao, et al., Conversion mechanism and gasification kinetics of biomass char during hydrothermal carbonization, Renew. Energy, 173(2021), p. 318. doi: 10.1016/j.renene.2021.03.123
    H. Guo, Y. Cheng, L. Wang, et al., Experimental study on the effect of moisture on low-rank coal adsorption characteristics, J. Nat. Gas Sci. Eng., 24(2015), p. 245. doi: 10.1016/j.jngse.2015.03.037
    J. Yu, A. Tahmasebi, Y. Han, et al., A review on water in low rank coals: The existence, interaction with coal structure and effects on coal utilization, Fuel Process. Technol., 106(2013), p. 9. doi: 10.1016/j.fuproc.2012.09.051
    S. Dey, Enhancement in hydrophobicity of low rank coal by surfactants—A critical overview, Fuel Process. Technol., 94(2012), No. 1, p. 151. doi: 10.1016/j.fuproc.2011.10.021
    H.B. Jiang, J.L. Zhang, J.X. Fu, et al., Properties and structural optimization of pulverized coal for blast furnace injection, J. Iron Steel Res. Int., 18(2011), No. 3, p. 6. doi: 10.1016/S1006-706X(11)60029-0
    A. Murao, Y. Kashihara, K. Takahashi, et al., Effect of natural gas injection into blast furnace on combustion efficiency of pulverized coal, Tetsu-to-Hagane, 101(2015), No. 12, p. 653. doi: 10.2355/tetsutohagane.TETSU-2015-052
    Z.F. Peng, X.J. Ning, G.W. Wang, et al., Structural characteristics and flammability of low-order coal pyrolysis semi-coke, J. Energy Inst., 93(2020), No. 4, p. 1341. doi: 10.1016/j.joei.2019.12.004
    H. Dang, G.W. Wang, C.M. Yu, et al., Study on chemical bond dissociation and the removal of oxygen-containing functional groups of low-rank coal during hydrothermal carbonization: DFT calculations, ACS Omega, 6(2021), No. 39, p. 25772. doi: 10.1021/acsomega.1c03866
    N. Zhang, G.W. Wang, C.M. Yu, et al., Physicochemical structure characteristics and combustion kinetics of low-rank coal by hydrothermal carbonization, Energy, 238(2022), art. No. 121682. doi: 10.1016/j.energy.2021.121682
    S.W. Du, W.H. Chen, and J. Lucas, Performances of pulverized coal injection in blowpipe and tuyere at various operational conditions, Energy Convers. Manage., 48(2007), No. 7, p. 2069. doi: 10.1016/j.enconman.2007.01.013
    H.K. Li, Y.J. Wang, Jiao K., et al., Study on alkali circulation process and its influence on coke ratio in blast furnace, [in] 10th International Symposium on High-Temperature Metallurgical Processing, San Antonio, 2019
    C. Rodríguez Correa, M. Stollovsky, T. Hehr, et al., Influence of the carbonization process on activated carbon properties from lignin and lignin-rich biomasses, ACS Sustainable Chem. Eng., 5(2017), No. 9, p. 8222. doi: 10.1021/acssuschemeng.7b01895
    H. Dang, R.S. Xu, J.L. Zhang, et al., Hydrothermal carbonization of waste furniture for clean blast furnace fuel production: Physicochemical, gasification characteristics and conversion mechanism investigation, Chem. Eng. J., 469(2023), art. No. 143980. doi: 10.1016/j.cej.2023.143980
    R.P. Li, J.L. Zhang, G.W. Wang, et al., Study on CO2 gasification reactivity of biomass char derived from high-temperature rapid pyrolysis, Appl. Therm. Eng., 121(2017), p. 1022. doi: 10.1016/j.applthermaleng.2017.04.132
    O. Beyssac, B. Goffé, J.P. Petitet, et al., On the characterization of disordered and heterogeneous carbonaceous materials by Raman spectroscopy, Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 59(2003), No. 10, p. 2267. doi: 10.1016/S1386-1425(03)00070-2
    Q. He, L. Ding, A. Raheem, et al., Kinetics comparison and insight into structure-performance correlation for leached biochar gasification, Chem. Eng. J., 417(2021), art. No. 129331. doi: 10.1016/j.cej.2021.129331
    N. Zhang, G.W. Wang, J.L. Zhang, et al., Study on co-combustion characteristics of hydrochar and anthracite coal, J. Energy Inst., 93(2020), No. 3, p. 1125. doi: 10.1016/j.joei.2019.10.006
    A. Mosqueda, J.T. Wei, K. Medrano, et al., Co-gasification reactivity and synergy of banana residue hydrochar and anthracite coal blends, Appl. Energy, 250(2019), p. 92. doi: 10.1016/j.apenergy.2019.05.008
    R.V.P. Antero, A.C.F. Alves, S.B. de Oliveira, et al., Challenges and alternatives for the adequacy of hydrothermal carbonization of lignocellulosic biomass in cleaner production systems: A review, J. Cleaner Prod., 252(2020), art. No. 119899. doi: 10.1016/j.jclepro.2019.119899
    H.Y. Gong, Y.D. Huang, H.Y. Hu, et al., The potential oxidation characteristics of CaCr2O4 during coal combustion with solid waste in a fluidized bed boiler: A thermogravimetric analysis, Chemosphere, 263(2021), art. No. 127974. doi: 10.1016/j.chemosphere.2020.127974
    Q. Hu, H.P. Yang, H.S. Xu, et al., Thermal behavior and reaction kinetics analysis of pyrolysis and subsequent in situ gasification of torrefied biomass pellets, Energy Convers. Manage., 161(2018), p. 205. doi: 10.1016/j.enconman.2018.02.003
    S. Nomura and T.G. Callcott, Maximum rates of pulverized coal injection in ironmaking blast furnaces, ISIJ Int., 51(2011), No. 7, p. 1033. doi: 10.2355/isijinternational.51.1033
    C.L. Zhang, G.W. Wang, X.J. Ning, et al., Numerical simulation of combustion behaviors of hydrochar derived from low-rank coal in the raceway of blast furnace, Fuel, 278(2020), art. No. 118267. doi: 10.1016/j.fuel.2020.118267
    Y.H. Zhou, P. Zhou, J.Y. Dan, et al., Effects of single lance configuration on coal combustion process in tuyere from viewpoint of coal plume, J. Iron Steel Res. Int., 28(2021), No. 7, p. 785. doi: 10.1007/s42243-020-00556-0
    R.K. Agrawal, On the compensation effect, J. Therm. Anal., 31(1986), No. 1, p. 73. doi: 10.1007/BF01913888
    P.J. Barrie, The mathematical origins of the kinetic compensation effect: 2. the effect of systematic errors, Phys. Chem. Chem. Phys., 14(2012), No. 1, p. 327. doi: 10.1039/C1CP22667C
    K. Yip, E. Ng, C.Z. Li, et al., A mechanistic study on kinetic compensation effect during low-temperature oxidation of coal chars, Proc. Combust. Inst., 33(2011), No. 2, p. 1755. doi: 10.1016/j.proci.2010.07.073
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