Yi-min Zhang, Ling-yun Yi, Li-na Wang, De-sheng Chen, Wei-jing Wang, Ya-hui Liu, Hong-xin Zhao,  and Tao Qi, A novel process for the recovery of iron, titanium, and vanadium from vanadium-bearing titanomagnetite:sodium modification-direct reduction coupled process, Int. J. Miner. Metall. Mater., 24(2017), No. 5, pp. 504-511. https://doi.org/10.1007/s12613-017-1431-4
Cite this article as:
Yi-min Zhang, Ling-yun Yi, Li-na Wang, De-sheng Chen, Wei-jing Wang, Ya-hui Liu, Hong-xin Zhao,  and Tao Qi, A novel process for the recovery of iron, titanium, and vanadium from vanadium-bearing titanomagnetite:sodium modification-direct reduction coupled process, Int. J. Miner. Metall. Mater., 24(2017), No. 5, pp. 504-511. https://doi.org/10.1007/s12613-017-1431-4
Research Article

A novel process for the recovery of iron, titanium, and vanadium from vanadium-bearing titanomagnetite:sodium modification-direct reduction coupled process

+ Author Affiliations
  • Corresponding author:

    Tao Qi    E-mail: tqgreen@home.ipe.ac.cn

  • Received: 19 September 2016Revised: 18 December 2016Accepted: 19 December 2016
  • A sodium modification-direct reduction coupled process was proposed for the simultaneous extraction of V and Fe from vanadium-bearing titanomagnetite. The sodium oxidation of vanadium oxides to water-soluble sodium vanadate and the transformation of iron oxides to metallic iron were accomplished in a single-step high-temperature process. The increase in roasting temperature favors the reduction of iron oxides but disfavors the oxidation of vanadium oxides. The recoveries of vanadium, iron, and titanium reached 84.52%, 89.37%, and 95.59%, respectively. Moreover, the acid decomposition efficiency of titanium slag reached 96.45%. Compared with traditional processes, the novel process provides several advantages, including a shorter flow, a lower energy consumption, and a higher utilization efficiency of vanadium-bearing titanomagnetite resources.
  • loading
  • [1]
    J.H. Chen, C.P. Guan, Y. Wang, Y.M. Zhou, and X.J. Tang, Experimental research on improving the recovery of vanadium titanomagnetite ore in Hongge mining areas in Panzhihua, Sichuan Nonferrous Met.,(2011), No. 2, p. 17.
    [2]
    X.Q. Wang, Blast Furnace Process for Vanadium-bearing Titanomagnetite, Metallurgical Industry Press, Beijing, 1994.
    [3]
    K.J. Hu, G. Xi, J. Yao, and X. Xi Status quo of manufacturing techniques of titanium of titanium slag in the world, World Nonferrous Met.,(2006), No. 12, p. 26.
    [4]
    Z.J. Liu, G.Q. Yang, Q.G. Xue, J.L. Zhang, and T.J. Yang, Research on direct reduction of coal-containing pellets of vanadic-titanomagnetite by rotary hearth furnace, Chin. J. Process Eng., 9(2009), Suppl. 1, p. 51.
    [5]
    J. Deng, X. Xue, and G.G. Liu, Current situation and development of comprehensive utilization of vanadiumbearing titanomagnetite at PANGANG, J. Mater. Metall., 6(2007), No. 2, p. 83.
    [6]
    B.C. Jena, W. Dresler, and I.G. Reilly, Extraction of titanium, vanadium and iron from titanomagnetite deposits at pipestone lake, Manitoba, Canada, Miner. Eng., 8(1995), No. 1-2, p. 159.
    [7]
    E. Hukkanen and H. Walden, The production of vanadium and steel from titanomagnetites, Int. J. Miner. Process., 15(1985), No. 1-2, p. 89.
    [8]
    L.H. Zhou, D.P. Tao, M.X. Fang, F.H. Zeng, and X. Pu, Carbothermic reduction of V-Ti magnetite ore, Chin. J. Rare Met., 33(2009), No. 3, p. 406.
    [9]
    L. Hong, Y.H. Ding, and H.E. Xie, Prospect of comprehensive utilization of V-rearing titanomagnetite by rotary hearth furnace process, Met. Mine,(2007), No. 5, p. 10.
    [10]
    X. Xue, Research on direct reduction of vanadic titanomagnetite, Iron Steel Vanadium Titanium, 28(2007), No. 3, p. 37.
    [11]
    R.R. Moskalyk and A.M. Alfantazi, Processing of vanadium:a review, Miner. Eng., 16(2003), No. 9, p. 793.
    [12]
    Y.X. Qin, Comparison of direct reduction by rotary hearth furnace-electric furnace smelting process and blast furnace process, Jiangsu Metall., 32(2004), No. 2, p. 9.
    [13]
    W.C. Song, K. Li, Q. Zheng, and H. Li, A novel process of vanadium extraction from molten vanadium bearing slag, Waste Biomass Valorization, 5(2014), No. 3, p. 327.
    [14]
    D.S. Chen, L.S. Zhao, T. Qi, G.P. Hu, H.X. Zhao, J. Li, and L.N. Wang, Desilication from titanium-vanadium slag by alkaline leaching, Trans. Nonferrous Met. Soc. China, 23(2013), No. 10, p. 3076.
    [15]
    L. Zhang, L.N. Zhang, M.Y. Wang, G.Q. Li, and Z.T. Sui, Dynamic oxidation of the Ti-bearing blast furnace, ISIJ Int., 46(2006), No. 3, p. 458.
    [16]
    L. Zhang, L.N. Zhang, M.Y. Wang, G.Q. Li, and Z.T. Sui, Recovery of titanium compounds from molten Ti-bearing blast furnace slag under the dynamic oxidation condition, Miner. Eng., 20(2007), No. 7, p. 684.
    [17]
    H.Y. Sun, X.J. Dong, X.F. She, Q.G. Xue, and J.S. Wang, Solid state reduction of titanomagnetite concentrate by graphite, ISIJ Int., 53(2013), No. 4, p. 564.
    [18]
    D.S. Chen, B. Song, L.N. Wang, T. Qi, Y. Wang, and W.J. Wang, Solid state reduction of Panzhihua titanomagnetite concentrates with pulverized coal, Miner. Eng., 24(2011), No. 8, p. 864.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Share Article

    Article Metrics

    Article Views(709) PDF Downloads(46) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return