Mi-qi Wang, Ze-hua Zhou, Lin-tao Wu, Ying Ding,  and Ze-hua Wang, Characterization and in-situ formation mechanism of tungsten carbide reinforced Fe-based alloy coating by plasma cladding, Int. J. Miner. Metall. Mater., 25(2018), No. 4, pp. 439-443. https://doi.org/10.1007/s12613-018-1589-4
Cite this article as:
Mi-qi Wang, Ze-hua Zhou, Lin-tao Wu, Ying Ding,  and Ze-hua Wang, Characterization and in-situ formation mechanism of tungsten carbide reinforced Fe-based alloy coating by plasma cladding, Int. J. Miner. Metall. Mater., 25(2018), No. 4, pp. 439-443. https://doi.org/10.1007/s12613-018-1589-4
Research Article

Characterization and in-situ formation mechanism of tungsten carbide reinforced Fe-based alloy coating by plasma cladding

+ Author Affiliations
  • Corresponding author:

    Mi-qi Wang    E-mail: wangmiqihhu@163.com

  • Received: 24 September 2017Revised: 24 October 2017Accepted: 27 October 2017
  • The precursor carbonization method was first applied to prepare W-C compound powder to perform the in-situ synthesis of the WC phase in a Fe-based alloy coating. The in-situ formation mechanism during the cladding process is discussed in detail. The results reveal that fine and obtuse WC particles were successfully generated and distributed in Fe-based alloy coating via Fe/W-C compound powders. The WC particles were either surrounded by or were semi-enclosed in blocky M7C3 carbides. Moreover, net-like structures were confirmed as mixtures of M23C6 and α-Fe; these structures were transformed from M7C3. The coarse herringbone M3C carbides did not only derive from the decomposition of M7C3 but also partly originated from the chemical reaction at the α-Fe/M23C6 interface. During the cladding process, the phase evolution of the precipitated carbides was WC → M7C3 → M23C6+M3C.
  • loading
  • [1]
    G. Dong, B. Yan, Q. Deng, and T. Yu, Microstructure and wear resistance of in-situ NbC particles reinforced Ni-based alloy composite coating by laser cladding, J. Wuhan. Univ. Technol., 27(2012), No. 2, p. 231.
    [2]
    J.B. Liu, TiC/Fe cermet coating by plasma cladding using asphalt as a carbonaceous precursor, Prog. Nat. Sci., 18(2008), No. 4, p. 447.
    [3]
    J.B. Liu, L.M. Wang, and H.Q. Li, Reactive plasma cladding of TiC/Fe cermet coating using asphalt as a carbonaceous precursor, Appl. Surf. Sci., 255(2009), No. 9, p. 4921.
    [4]
    B.S. Du, Z.D. Zou, X.H. Wang, and S.Y. Qu, In-situ synthesis of TiB2/Fe composite coating by laser cladding, Mater. Lett., 62(2008), No. 4-5, p. 689.
    [5]
    S.Q. Jiang, G. Wang, Q.W. Ren, C.D. Yang, Z.H. Wang, and Z.H. Zhou, In-situ synthesis of Fe-based alloy clad coatings containing TiB2-TiN-(h-BN), Int. J. Miner. Metall. Mater., 22(2015), No. 6, p. 613.
    [6]
    L.J. Guo, X.B. Wang, P.P. Zhang, Z.H. Yang, and H.B. Wang, Synthesis of Fe based ZrB2 composite coating by gas tungsten arc welding, Mater. Sci. Technol., 29(2013), No. 1, p. 19.
    [7]
    J. Guo, Y. Li, H.W. Cui, X.F. Cui, and Z.B. Cai, Microstructure and tribological properties of in-situ synthesized TiN reinforced Ni/Ti alloy clad layer prepared by plasma cladding technique, J. Mater. Eng. Perform., 25(2016), No. 6, p. 2412.
    [8]
    D. Shu, Z.G. Li, K. Zhang, C.W. Yao, D. Y. Li, and Z.B. Dai, In-situ synthesized high volume fraction WC reinforced Ni-based coating by laser cladding, Mater. Lett., 195(2017), p. 178.
    [9]
    Y.L. Yuan, and Z.G. Li, A novel approach of in-situ synthesis of WC particulate-reinforced Fe-30Ni ceramic metal coating, Surf. Coat. Technol., 328(2017), p. 256.
    [10]
    H.T. Wang, S.Q. Zhang, J.H. Huang, J.L. Zhu, and H. Zhang, Reactive detonation spraying of in-situ synthesised TiC reinforced Fe36Ni based composite coatings via sucrose as carbonaceous precursor, Surf. Eng., 25(2009), No. 4, p. 295.
    [11]
    D. Shu, Z.G. Li, C.W. Yao, D.Y. Li, and Z.B. Dai, In-situ synthesised WC reinforced nickel coating by laser cladding, Surf. Eng., 34(2018), No. 4, p. 1.
    [12]
    L.B. Niu, M. Hojamberdiev, and Y.H. Xu, Preparation of in-situ-formed WC/Fe composite on gray cast iron substrate by a centrifugal casting process, J. Mater. Process. Technol., 210(2010), No. 14, p. 1986.
    [13]
    D.D. Gu and W. Meiners, Microstructure characteristics and formation mechanisms of in-situ WC cemented carbide based hardmetals prepared by selective laser melting, Mater. Sci. Eng. A, 527(2010), No. 29-30, p.7585.
    [14]
    G.R. Yang, C.P. Huang, W.M. Song, J. Li, J.J. Lu, Y.Ma, and Y. Hao, Microstructure characteristics of Ni/WC composite cladding coatings, Int. J. Miner. Metall. Mater., 23(2016), No. 2, p.184.
    [15]
    O. Verezub, Z. Kálazi. G. Buza, N.V. Verezub, and G. Kaptay, In-situ synthesis of a carbide reinforced steel matrix surface nanocomposite by laser melt injection technology and subsequent heat treatment, Surf. Coat. Technol., 203(2009), No. 20-21, p. 3049.
    [16]
    X.L. Wu and G.G. Chen, Microstructural features of an iron-based laser coating, J. Mater. Sci., 34(1999), No. 14, p. 3355.
    [17]
    D.V. Shtansky and G. Inden, Phase transformation in Fe-Mo-C and Fe-W-C steels-Ⅱ. Eutectoid reaction of M23C6 carbide decomposition during austenitization, Acta Mater., 45(1997), No. 7, p. 2879.
    [18]
    B. Binesh and M. Aghaie-Khafri, Phase evolution and mechanical behavior of the semi-solid SIMA processed 7075 aluminum alloy, Metals, 6(2016), No. 3, p.42.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Share Article

    Article Metrics

    Article Views(560) PDF Downloads(11) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return