Zeeshan Baig, Othman Mamat, Mazli Mustapha, Asad Mumtaz, Sadaqat Ali,  and Mansoor Sarfraz, Surfactant-decorated graphite nanoplatelets (GNPs) reinforced aluminum nanocomposites: sintering effects on hardness and wear, Int. J. Miner. Metall. Mater., 25(2018), No. 6, pp. 704-715. https://doi.org/10.1007/s12613-018-1618-3
Cite this article as:
Zeeshan Baig, Othman Mamat, Mazli Mustapha, Asad Mumtaz, Sadaqat Ali,  and Mansoor Sarfraz, Surfactant-decorated graphite nanoplatelets (GNPs) reinforced aluminum nanocomposites: sintering effects on hardness and wear, Int. J. Miner. Metall. Mater., 25(2018), No. 6, pp. 704-715. https://doi.org/10.1007/s12613-018-1618-3
Research Article

Surfactant-decorated graphite nanoplatelets (GNPs) reinforced aluminum nanocomposites: sintering effects on hardness and wear

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  • The exceptional properties of graphene make it ideal as a reinforcement to enhance the properties of aluminum matrices and this critically depends on uniform dispersion. In this study, the dispersion issue was addressed by sonication and non-covalent surface functionalization of graphite nanoplatelets (GNPs) using two types of surfactant: anionic (sodium dodecyl benzene sulfate (SDBS)) and non-ionic polymeric (ethyl cellulose (EC)). After colloidal mixing with Al powder, consolidation was performed at two sintering temperatures (550 and 620℃). The structure, density, mechanical and wear properties of the nanocomposite samples were investigated and compared with a pure Al and a pure GNPs/Al nanocomposite sample. Noticeably, EC-based 0.5wt% GNPs/Al samples showed the highest increment of 31% increase in hardness with reduced wear rate of 98.25% at 620℃, while a 22% increase in hardness with reduced wear rate of 96.98% at 550℃ was observed, as compared to pure Al. Microstructural analysis and the overall results validate the use of EC-based GNPs/Al nanocomposites as they performed better than pure Al and pure GNPs/Al nanocomposite at both sintering temperatures.
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  • [1]
    Y. Dong, R. Umer, and A.K.T. Lau, Fillers and Reinforcements for Advanced Nanocomposites, Woodhead Publishing, UK, 2015.
    [2]
    S.C. Tjong, Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets, Mater. Sci. Eng. R, 74(2013), No. 10, p. 281.
    [3]
    C.N.R. Rao and A.K. Sood, Graphene: Synthesis, Properties, and Phenomena, Wiley-VCH, Germany, 2013.
    [4]
    Z. Hu, G. Tong, D. Lin, C. Chen, H. Guo, J. Xu, and L. Zhou, Graphene-reinforced metal matrix nanocomposites-a review, Mater. Sci. Technol., 32(2016), No. 9, p.930.
    [5]
    H.G. Prashantha Kumar and M. Anthony Xavior, Effect of graphene addition and tribological performance of Al 6061/graphene flake composite, Tribol. Mater. Surf. Interfaces, 11(2017), No. 2, p.88.
    [6]
    A. Nieto, A. Bisht, D. Lahiri, C. Zhang, and A. Agarwal, Graphene reinforced metal and ceramic matrix composites: a review, Int. Mater. Rev., 62(2017), No. 5, p. 241.
    [7]
    H. Asgharzadeh and M. Sedigh, Synthesis and mechanical properties of Al matrix composites reinforced with few-layer graphene and graphene oxide, J. Alloys Compd., 728(2017), p. 47.
    [8]
    Z. Baig, O. Mamat, and M. Mustapha, Recent progress on the dispersion and the strengthening effect of carbon nanotubes and graphene-reinforced metal nanocomposites: a review, Crit. Rev. Solid State Mater. Sci., 43(2018), No. 1, p. 1.
    [9]
    B. Chen and K. Kondoh, Sintering behaviors of carbon nanotubes-aluminum composite powders, Metals, 6(2016), No. 9, p. 213.
    [10]
    Z. Baig, O. Mamat, M. Mustapha, A. Mumtaz, M. Sarfraz, and S. Haider, An efficient approach to address issues of graphene nanoplatelets (GNPs) incorporation in aluminium powders and their compaction behavior, Metals, 8(2018), No. 2, p. 90.
    [11]
    H.P. Zhang, C. Xu, W.L. Xiao, K. Ameyama, and C.L. Ma, Enhanced mechanical properties of Al5083 alloy with graphene nanoplates prepared by ball milling and hot extrusion, Mater. Sci. Eng. A, 658(2016), p. 8.
    [12]
    X. Zeng, J. Teng, J.G. Yu, AS. Tan, D.F. Fu, and H. Zhang, Fabrication of homogeneously dispersed graphene/Al composites by solution mixing and powder metallurgy, Int. J. Miner. Metall. Mater., 25(2018), No. 1, p. 102.
    [13]
    L. Guardia, M.J. Fernández-Merino, J.I. Paredes, P. Solis-Fernandez, S. Villar-Rodil, A. Martinez-Alonso, and J.M.D. Tascón, High-throughput production of pristine graphene in an aqueous dispersion assisted by non-ionic surfactants, Carbon, 49(2011), No. 5, p. 1653.
    [14]
    V. Georgakilas, M. Otyepka, A.B. Bourlinos, V. Chandra, N. Kim, K.C. Kemp, P. Hobza, R. Zboril, and K.S. Kim, Functionalization of graphene: covalent and non-covalent approaches, derivatives and applications, Chem. Rev., 112(2012). No. 11, p. 6156.
    [15]
    J.C. Wei and F. Inam, Processing of epoxy/graphene nanocomposites: effects of surfactants, J. Polym. Sci. Appl., 1(2017), No. 1, p. 1.
    [16]
    WM. Tian, S.M.. Li, B. Wang, X. Chen, J.H. Liu, and M. Yu, Graphene-reinforced aluminum matrix composites prepared by spark plasma sintering, Int. J. Miner. Metall. Mater., 23(2016), No. 6, p. 723.
    [17]
    Z. Baig, O. Mamat, M. Mustapha, and M. Sarfraz, Influence of surfactant type on the dispersion state and properties of graphene nanoplatelets reinforced aluminium matrix nanocomposites, Fullerenes Nanotubes Carbon Nanostruct., 25(2017), No. 9, p. 545.
    [18]
    Z. Baig, O. Mamat, M. Mustapha, A. Mumtaz, K.S. Munir, M. Sarfraz, Investigation of tip sonication effects on structural quality of graphene nanoplatelets (GNPs) for superior solvent dispersion, Ultrason. Sonochem., 45(2018), p. 133.
    [19]
    X.N. Mu, H.N. Cai, H.M, Zhang, Q.B. Fan, Z.H. Zhang, Y.X. Wu, Y. X.Ge, and D.D Wang, Interface evolution and superior tensile properties of multi-layer graphene reinforced pure Ti matrix composite, Mater. Des., 140(2017), p. 431.
    [20]
    X. Gao, H. Yue, E. Guo, H. Zhang, X.Y. Lin, L.H. Yao, and B. Wang, Preparation and tensile properties of homogeneously dispersed graphene reinforced aluminum matrix composites, Mater. Des., 94(2016), p. 54.
    [21]
    L.K. Pillari, A.K. Shukla, S.V.S.N. Murty, and V. Umasankar, Processing and characterization of graphene and multi-wall carbon nanotube-reinforced aluminium alloy AA2219 composites processed by ball milling and vacuum hot pressing, Metall. Microst. Anal., 6(2017), No. 4, p. 289.
    [22]
    W.S. Yang, G.Q. Chen, J. Qiao, S.F. Liu, R. Xiao, R.H. Dong, M. Hussain, and G.H. Wu, Graphene nanoflakes reinforced Al-20Si matrix composites prepared by pressure infiltration method, Mater. Sci. Eng. A, 700(2017), p. 351.
    [23]
    J.H. Liu, U. Khan, J. Coleman, B. Fernandez, P. Rodriguez, S. Naher, and D. Brabazon, Graphene oxide and graphene nanosheet reinforced aluminium matrix composites: powder synthesis and prepared composite characteristics, Mater. Des., 94(2016), p. 87.
    [24]
    S.N. Alam and L. Kumar, Mechanical properties of aluminium based metal matrix composites reinforced with graphite nanoplatelets, Mater. Sci. Eng. A, 667(2016), p. 16.
    [25]
    R. Pérez-Bustamante, D. Bolaños-Morales, J. Bonilla-Martínez, I. Estrada-Guel, and R. Martínez-Sánchez, Microstructural and hardness behavior of graphene-nanoplatelets/aluminum composites synthesized by mechanical alloying, J. Alloys. Compd., 615(2014), Suppl. 1, p. S578.
    [26]
    Z. Baig, O. Mamat, and M. Mustapha, Recent progress on the dispersion and the strengthening effect of carbon nanotubes and graphene reinforced metal nanocomposites: a review, Crit. Rev. Solid State Mater. Sci., 43(2018), No. 1, p. 1.
    [27]
    Q. Zhang, Z.B. Qin, Q. Luo, Z. Wu, L.L. Liu, B. Shen, and W.B. Hu, Microstructure and nanoindentation behavior of Cu composites reinforced with graphene nanoplatelets by electroless co-deposition technique, Sci. Rep., 7(2017), p. 1338.
    [28]
    A. Saboori, M. Pavese, C. Badini, and P. Fino, Development of Al- and Cu-based nanocomposites reinforced by graphene nanoplatelets: fabrication and characterization, Front. Mater. Sci., 11(2017), No. 2, p. 171.
    [29]
    P. Hidalgo-Manrique, S.J. Yan, F. Lin, Q.H. Hong, I.A. Kinloch, X. Chen, R.J. Young, X.Y. Zhang, and S.L. Dai, Microstructure and mechanical behavior of aluminium matrix composites reinforced with graphene oxide and carbon nanotubes, J. Mater. Sci., 52(2017), No. 23, p. 13466.
    [30]
    D.S. Li, Y. Ye, X.J. Liao, and Q.H. Qin, A novel method for preparing and characterizing graphene nanoplatelets/aluminum nanocomposites, Nano Res., 11(2018), No. 3, p. 1642.
    [31]
    M. Kostecki, J. Woźniak, T. Cygan, M. Petrus, and A. Olszyna, Tribological properties of aluminium alloy composites reinforced with multi-layer graphene—The influence of spark plasma texturing process, Materials, 10(2017), No. 8, p. 928.
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