Feray Kocan and Umran Hicsonmez, Leaching kinetics of celestite in nitric acid solutions, Int. J. Miner. Metall. Mater., 26(2019), No. 1, pp. 11-20. https://doi.org/10.1007/s12613-019-1705-0
Cite this article as:
Feray Kocan and Umran Hicsonmez, Leaching kinetics of celestite in nitric acid solutions, Int. J. Miner. Metall. Mater., 26(2019), No. 1, pp. 11-20. https://doi.org/10.1007/s12613-019-1705-0
Research Article

Leaching kinetics of celestite in nitric acid solutions

+ Author Affiliations
  • Corresponding author:

    Feray Kocan    E-mail: feraykocan@hotmail.com

  • Received: 9 May 2018Revised: 3 September 2018Accepted: 13 September 2018
  • In this study, strontium nitrate extraction from celestite in nitric acid solutions was investigated using the leaching method. The influences of acid concentration, solid-to-liquid ratio, stirring speed, and reaction temperature on the leaching of strontium from celestite concentrate were studied. The results showed that the leaching rate increased with increasing acid concentration, stirring speed, and temperature and decreased with increasing solid-to-liquid ratio. The particle size was fixed in all of the dissolution experiments. The results showed that the stirring speed and the temperature were the most influential parameters with respect to the leaching process. The kinetic model best fit control by diffusion through the product layer. The activation energy of the dissolution celestite in nitric acid solutions was calculated to be 42.22 kJ/mol.
  • loading
  • [1]
    S. Chegrouche, A. Mellah, and M. Barkat, Removal of strontium from aqueous solutions by adsorption onto activated carbon, Desalination, 235(2009), No. 1-3, p. 306.
    [2]
    M.R. Palmer, C. Helvaci, and A.E. Fallick, Sulphur, sulphate oxygen and strontium isotope composition of Cenozoic Turkish evaporates, Chem. Geol., 209(2004), No. 3-4, p. 341.
    [3]
    P.W. Harben and M. Kuzvart, Industrial Minerals:A Global Geology, Industrial Minerals Information Ltd, London, 1996.
    [4]
    J.P. Macmillan, J.W. Park, R. Gerstenberg, H. Wagner, K. Köhler, and P. Wallbrecht, Strontium and Strontium Compounds, John Wiley & Sons, New York, 2012.
    [5]
    R.O. Ajemba and O.D. Onukwuli, Dissolution kinetics and mechanisms of reaction of Udi clay in nitric acid solution, Am. J. Sci. Ind. Res., 3(2012), No. 3, p. 115.
    [6]
    K. Liddell, T. Newton, M.D. Adams, and B. Muller, Energy consumption for Kell hydrometallurgical refining versus conventional pyrometallurgical smelting and refining of PGM concentrates, J. South Afr. Inst. Min. Metall., 111(2011), No. 2, p. 127.
    [7]
    S. Aydoğan, M. Erdemoğlu, A.A. Aras, G. Uçar, and A. Özkan, Dissolution kinetics of celestite (SrSO4) in HCl solution with BaCl2, Hydrometallurgy, 84(2006), No. 3-4, p. 239.
    [8]
    M. Erdemoğlu, M. Sarikaya, and M. Canbazoğlu, Leaching of celestite with sodium sulfide, J. Dispersion Sci. Technol., 27(2006), No. 4 p. 439.
    [9]
    R. Suárez-Orduña, J.C. Rendón-Angeles, and K. Yanagisawa, Kinetic study of the conversion of mineral celestite to strontianite under alkaline hydrothermal conditions, Int. J. Miner. Process., 83(2007), No. 1-2, p. 12.
    [10]
    D. Bingol, S. Aydogan, and S.S. Gultekin, Neural model for the leaching of celestite in sodium carbonate solution, Chem. Eng. J., 165(2010), No. 2, p. 617.
    [11]
    I.U. Ermis, Production of Ammonium Sulfate and Strontium Carbonate via Leaching Methods From Strontium Sulfate Concentrate[Dissertation], T.C. Selcuk University of Science and Technology Institute, Konya, 2011.
    [12]
    M. Zoraga and C. Kahruman, Kinetics of conversion of celestite to strontium carbonate in solutions containing carbonate, bicarbonate and ammonium ions, and dissolved ammonia, J. Serb. Chem. Soc., 79(2014), No. 3, p. 345.
    [13]
    F. De Buda, Method for Recovery and Conversion of Strontium Sulphate to Strontium Carbonate from Low and Medium Grade Celestite Ores, US Patent, Appl.US4666688A, 1987.
    [14]
    F. Kocan and U. Hicsonmez, Leaching of celestite in sodium hydroxide solutions and kinetic modelling, J. Dispersion Sci. Technol., 2018. https://doi.org/10.1080/01932691.2018.1464466.
    [15]
    S.Y. Qin, B.W. Yin, Y.F. Zhang, and Y. Zhang, Leaching kinetics of szaibelyite ore in NaOH solution, Hydrometallurgy, 157(2015), p. 333.
    [16]
    Y.F. Zhang, J.Y. Ma, Y.H. Qin, J.F. Zhou, L. Yang, Z.K. Wu, T.L. Wang, W.G. Wang, and C.W. Wang, Ultrasound-assisted leaching of potassium from phosphorus-potassium associated ore, Hydrometallurgy, 166(2016), p. 237.
    [17]
    D.D. Wu, S.M. Wen, and J.S. Deng, Leaching kinetics of cerrusite using a new complexation reaction reagent, New J. Chem., 39(2015), No. 3, p. 1922.
    [18]
    A. Künkül, A. Gülezgin, and N. Demirkiran, Investigation of the use of ammonium acetate as an alternative lixiviant in the leaching of malachite ore, Chem. Ind. Chem. Eng. Q., 19(2013), No. 1, p. 25.
    [19]
    Z.I. Zafar, Determination of semi empirical kinetic model for dissolution of bauxite ore with sulfuric acid:Parametric cumulative effect on the Arrhenius parameters, Chem. Eng. J., 141(2008), No. 1-3, p. 233.
    [20]
    M. Iwai and J.M. Toguri, The leaching of celestite in sodium carbonate solution, Hydrometallurgy, 22(1989), No. 1-2, p. 87.
    [21]
    A.H.E. Castillejos, F.P.B. de la Cruz del, and A.S. Uribe, The direct conversion of celestite to strontium carbonate in sodium carbonate aqueous media, Hydrometallurgy, 40(1996), No. 1-2, p. 207.
    [22]
    S.S. Behera and P.K. Parhi, Leaching kinetics study of neodymium from the scrap magnet using acetic acid, Sep. Purif. Technol. 160(2016), p. 59.
    [23]
    Q.C. Feng, S.M. Wen, W.J. Zhao, X. Bai, and Y. Chen, Dissolution of smithsonite in methane sulfonic acid, Russ. J. Non-ferrous Met., 56(2015), No. 4, p. 365.
    [24]
    Q.C. Feng, S.M. Wen, Y.J. Wang, W.J. Zhao, J.S. Deng, Investigation of leaching kinetics of cerussite in sodium hydroxide solutions, Physicochem. Prob. Miner. Process., 51(2015), No. 2, p. 491.
    [25]
    S. Espiari, F. Rashchi, and S.K. Sadrnezhaad, Hydrometallurgical treatment of tailings with high zinc content, Hydrometallurgy, 82(2006), No. 1-2, p. 54.
    [26]
    A. Ekmekyapar, N. Demirkiran, A. Künkül, and E. Aktaş, Leaching of malachite ore in ammonium sulfate solutions and production of copper oxide, Braz. J. Chem. Eng., 32(2015), No. 1, p. 155.
    [27]
    W. Astuti, T. Hirajima, K. Sasaki, and N. Okibe, Comparison of atmospheric citric acid leaching kinetics of nickel from different Indonesian saprolitic ores, Hydrometallurgy, 161(2016), p. 138.
    [28]
    O. Levenspiel, Chemical Reaction Engineering, John Wiley & Sons, New York, 1999.
    [29]
    T. Rosenqvist, Principles of Extractive Metallurgy, McGraw-Hill Book Company, New York, 1980.
    [30]
    C. Bilal, The Reaction Kinetics of Colemanite with Sulfuric Acid[Dissertation], Technical University, Istanbul, 2003.
    [31]
    H.L. Hosgun, Dissolution Kinetics of Aluminum from Kaolin in HCl and NaOH Solutions[Dissertation], Osmangazi University, Eskisehir, 1996.
    [32]
    M. Kandilcik, Dissolution Kinetics of Tincal Mineral in Ammonium Sulfate Solutions[Dissertation], Yuzuncu Yil University, Van, 2013.
    [33]
    A. Aran, Materials Science Lecture Notes[Dissertation], Istanbul Technical University, Istanbul, 2008.
    [34]
    F.R.P. Carrillo, A.S. Uribe, and A.H.E. Castillejos, A laboratory study of the leaching of celestite in a Pachuca tank, Miner. Eng., 8(1995), No. 4-5, p. 495.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Share Article

    Article Metrics

    Article Views(705) PDF Downloads(29) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return