Xing Chen, Xun Liu,  and Kai Huang, Synthesis of uniform hexagonal Ag nanoprisms with controlled thickness and tunable surface plasmon bands, Int. J. Miner. Metall. Mater., 26(2019), No. 6, pp. 796-802. https://doi.org/10.1007/s12613-019-1785-x
Cite this article as:
Xing Chen, Xun Liu,  and Kai Huang, Synthesis of uniform hexagonal Ag nanoprisms with controlled thickness and tunable surface plasmon bands, Int. J. Miner. Metall. Mater., 26(2019), No. 6, pp. 796-802. https://doi.org/10.1007/s12613-019-1785-x
Research Article

Synthesis of uniform hexagonal Ag nanoprisms with controlled thickness and tunable surface plasmon bands

+ Author Affiliations
  • Corresponding author:

    Kai Huang    E-mail: khuang@metall.ustb.edu.cn

  • Received: 24 May 2018Revised: 5 November 2018Accepted: 13 November 2018
  • In this work, we synthesized monodispersed hexagonal Ag nanoprisms in high yields in a system of poly(vinylpyrrolidone) (PVP) in N-methylpyrrolidone (NMP). A blue shift occurred and was strongly dependent on the thickness of the uniform Ag nanoprisms, which had almost the same radial area. When the Ag nanoprisms grew thicker, their in-plane dipole resonance peaks markedly shifted toward shorter wavelengths (i.e., blue shift). PVP played a critical role of favoring vertical growth of the Ag nanoplates, preventing aggregation, and inducing the formation of Ag hexagonal nanoprisms (HNPs) through the transformation from thin Ag triangular nanoprisms (TNPs). Compared with similar previous research, the present study provides quite uniform Ag hexagonal nanoplates, which makes the blue shift related more solely and distinctly to the thickness of the Ag nanoprisms. The findings of this work provide a new perspective toward understanding the unique optical characteristics of Ag HNPs with different aspect ratios.
  • loading
  • [1]
    X.Z. Zhu, X.L. Zhuo, Q. Li, Z. Yang, and J.F. Wang, Gold nanobipyramid-supported silver nanostructures with narrow plasmon linewidths and improved chemical stability, Adv. Funct. Mater., 26(2016), No. 3, p. 341.
    [2]
    Y.F. Zhang, Z. Ji, K. Chen, B.W. Liu, C.C. Jia, and S.W. Yang, Study on the preparation of Pt nanocapsules, Int. J. Miner. Metall. Mater., 24(2017), No. 1, p. 109.
    [3]
    H.J. You and J.X. Fang, Particle-mediated nucleation and growth of solution-synthesized metal nanocrystals: A new story beyond the LaMer curve, Nano Today, 11(2016), No. 2, p. 145.
    [4]
    Y. Xia, Y. Xiong, B. Lim, and S.E. Skrabalak, Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics?, Angew. Chem. Int. Ed., 48(2009), No. 1, p. 60.
    [5]
    Y.G. Sun, Controlled synthesis of colloidal silver nanoparticles in organic solutions: empirical rules for nucleation engineering, Chem. Soc. Rev., 42(2013), No. 7, p. 2497.
    [6]
    B. Khodashenas and H.R. Ghorbani, Synthesis of silver nanoparticles with different shapes, Arabian J. Chem., 2015. https://doi.org/10.1016/j.arabjc.2014.12.014.
    [7]
    X.W. Han, X.F. Zeng, J. Zhang, H.F. Huan, J.X. Wang, N.R. Foster, and J.F. Chen, Synthesis of transparent dispersion of monodispersed silver nanoparticles with excellent conductive performance using high-gravity technology, Chem. Eng. J., 296(2016), p. 182.
    [8]
    H.X. Yu, Q. Zhang, H.Y. Liu, M. Dahl, J.B. Joo, N. Li, L.J. Wang, and Y.D. Yin, Thermal synthesis of silver nanoplates revisited: A modified photochemical process, ACS Nano, 8(2014), No. 10, p. 10252.
    [9]
    C.B. Gao, Z.D. Lu, Y. Liu, Q. Zhang, M.F. Chi, Q. Cheng, and Y.D. Yin, Highly stable silver nanoplates for surface plasmon resonance biosensing, Angew. Chem. Int. Ed., 51(2012), No. 23, p. 5629.
    [10]
    Q. Zhang, J.P. Ge, T. Pham, J. Goebl, Y.X. Hu, Z.D. Lu, and Y.D. Yin, Reconstruction of silver nanoplates by UV irradiation: Tailored optical properties and enhanced stability, Angew. Chem. Int. Ed., 48(2009), No. 19, p. 3516.
    [11]
    H. McArdle, E. Spain, T.E. Keyes, R.L. Stallings, M. Brennan-Fournet, and R.J. Forster, Triangular silver nanoplates: Properties and ultrasensitive detection of miRNA, Electrochem. Commun., 79(2017), p. 23.
    [12]
    R.C. Jin, Y.W. Cao, C.A. Mirkin, K.L. Kelly, G.C. Schatz, and J.G. Zheng, Photoinduced conversion of silver nanospheres to nanoprisms, Science, 294(2001), No. 5548, p. 1901.
    [13]
    Q. Zhang, N. Li, J. Goebl, Z.D. Lu, and Y.D. Yin, A systematic study of the synthesis of silver nanoplates: Is citrate a “magic” reagent?, J. Am. Chem. Soc., 133(2011), No. 46, p. 18931.
    [14]
    G.S. Métraux and C.A. Mirkin, Rapid thermal synthesis of silver nanoprisms with chemically tailorable thickness, Adv. Mater., 17(2005), No. 4, p. 412.
    [15]
    X.F. Zhao, B. Chen, C. Li, T. Wang, J. Zhang, X.L. Jiao, and D.R. Chen, Large-scale synthesis of size-controllable silver nanoplates and their application in detecting strong oxidants in aqueous solutions, Chem. Eng. J., 285(2016), p. 690.
    [16]
    M.Z. Liu, M. Leng, C. Yu, X. Wang, and C. Wang, Selective synthesis of hexagonal Ag nanoplates in a solution-phase chemical reduction process, Nano Res. 3(2010), No. 12, p. 843.
    [17]
    M. Maillard, S. Giorgio, and M. Pileni, Sliver nanodisks, Adv. Mater., 14(2002), No. 15, p. 1084.
    [18]
    S.H. Chen and D.L. Carroll, Synthesis and characterization of truncated triangular silver nanoplates, Nano Lett., 2(2002), No. 9, p. 1003.
    [19]
    Q. Zhang, Y. Yang, J.T. Li, R. Iurilli, S.F. Xie, and D. Qin, Citrate-free synthesis of silver nanoplates and the mechanistic study, ACS Appl. Mater. Interfaces, 5(2013), p. 6333.
    [20]
    I. Washio, Y. Xiong, Y. Yin, and Y. Xia, Reduction by the end groups of poly(vinyl pyrrolidone): A new and versatile route to the kinetically controlled synthesis of Ag triangular nanoplates, Adv. Mater., 18(2006), No. 13, p. 1745.
    [21]
    L.P. Jiang, S. Xu, J.M. Zhu, J.R. Zhang, J.J. Zhu, and H.Y. Chen, Ultrasonic-assisted synthesis of monodisperse single-crystalline silver nanoplates and gold nanorings, Inorg. Chem., 43(2004), No. 19, p. 5877.
    [22]
    I. Pastoriza-Santos and L.M. Liz-Marzán, Synthesis of silver nanoprisms in DMF, Nano Lett., 2(2002), No. 8, p. 903.
    [23]
    M.H. Kim, J.J. Lee, J.B. Lee, and K.Y. Choi, Synthesis of silver nanoplates with controlled shapes by reducing silver nitrate with poly(vinyl pyrrolidone) in N-methylpyrrolidone, CrystEngComm, 15(2013), p. 4660.
    [24]
    J. An, B. Tang, X.H. Ning, J. Zhou, B. Zhao, W.Q. Xu, C. Corredor, and J.R. Lombardi, Photoinduced shape evolution: From triangular to hexagonal silver nanoplates, J. Phys. Chem. C, 111(2007), No. 49, p. 18055.
    [25]
    Z.L. Wang, Transmission electron microscopy of shape-controlled nanocrystals and their assemblies, J. Phys. Chem. B, 104(2012), No. 6, p. 1153.
    [26]
    M. Tsuji, S. Gomi, Y. Maeda, M. Matsunaga, S. Hikino, K. Uto, T. Tsuji, and H. Kawazumi, Rapid transformation from spherical nanoparticles, nanorods, cubes, or bipyramids to triangular prisms of silver with PVP, citrate, and H2O2, Langmuir, 28(2012), No. 24, p. 8845.
    [27]
    Q. Zhang, Y.X. Hu, S.R. Guo, J. Goebl, and Y.D. Yin, Seeded growth of uniform Ag nanoplates with high aspect ratio and widely tunable surface plasmon bands, Nano Lett., 10(2010), No. 12, p. 5037.
    [28]
    J. Zeng, X.H. Xia, M. Rycenga, P. Henneghan, Q.G. Li, and Y.N. Xia, Successive deposition of silver on silver nanoplates: Lateral versus vertical growth, Angew. Chem. Int. Ed., 50(2011), No. 1, p. 244.
    [29]
    D. Aherne, D.M. Ledwith, M. Gara, and J.M. Kelly, Optical properties and growth aspects of silver nanoprisms produced by a highly reproducible and rapid synthesis at room temperature, Adv. Funct. Mater., 18(2008), No. 14, p. 2005.
    [30]
    K.L. Kelly, E. Coronado, L.L. Zhao, and G.C. Schatz, The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment, J. Phys. Chem. B, 107(2003), No. 3, p. 668.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Share Article

    Article Metrics

    Article Views(424) PDF Downloads(10) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return