Ming-tao Mao, Han-jie Guo, Fei Wang,  and Xiao-lin Sun, Chemical composition and structural identification of primary carbides in as-cast H13 steel, Int. J. Miner. Metall. Mater., 26(2019), No. 7, pp. 839-848. https://doi.org/10.1007/s12613-019-1796-7
Cite this article as:
Ming-tao Mao, Han-jie Guo, Fei Wang,  and Xiao-lin Sun, Chemical composition and structural identification of primary carbides in as-cast H13 steel, Int. J. Miner. Metall. Mater., 26(2019), No. 7, pp. 839-848. https://doi.org/10.1007/s12613-019-1796-7
Research Article

Chemical composition and structural identification of primary carbides in as-cast H13 steel

+ Author Affiliations
  • Corresponding author:

    Han-jie Guo    E-mail: guohanjie@ustb.edu.cn

  • Received: 13 September 2018Revised: 27 December 2018Accepted: 11 January 2019
  • The aim of this study was to characterize the primary carbides formed in as-cast H13 steel. The composition, morphology, type, and size of primary carbides in as-cast H13 steel were investigated by optical microscope (OM), field emission scanning electron microscopy (FE-SEM), electron back-scattered diffraction (EBSD), and X-ray diffraction (XRD) analysis. The number of primary carbides was investigated by ASPEX automated inclusion analysis system. The results indicated that primary carbides in as-cast H13 steel are mainly composed of Cr, Mo, V, and Ti, and there exist four kinds of primary carbides in the interdendritic zones of H13 steel, which are stripy Mo-Cr-rich M2C, eutectic Mo-Cr-rich M2C, V-rich MC, and V-rich MC with Ti and N. Thermodynamic calculation indicated that M2C precipitates in liquid phase at solid fractions larger than 0.99, while MC precipitates in liquid phase at solid fractions larger than 0.96. Statistical results indicated that the number of M2C is much greater than the number of other kinds of primary carbides. Most primary carbides are blocky, with lengths of no more than 10 μm and a length/width ratio of no more than 3. The large primary carbides in as-cast H13 steel are mainly M2C.
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