Hang-qi Feng, Zhi-bo Yang, Ye-tong Bai, Li Zhang,  and Yu-lin Liu, Effect of Cr content and cooling rate on the primary phase of Al-2.5Mn alloy, Int. J. Miner. Metall. Mater., 26(2019), No. 12, pp. 1551-1558. https://doi.org/10.1007/s12613-019-1862-1
Cite this article as:
Hang-qi Feng, Zhi-bo Yang, Ye-tong Bai, Li Zhang,  and Yu-lin Liu, Effect of Cr content and cooling rate on the primary phase of Al-2.5Mn alloy, Int. J. Miner. Metall. Mater., 26(2019), No. 12, pp. 1551-1558. https://doi.org/10.1007/s12613-019-1862-1
Research Article

Effect of Cr content and cooling rate on the primary phase of Al-2.5Mn alloy

+ Author Affiliations
  • Corresponding author:

    Yu-lin Liu    E-mail: ylliu@sau.edu.cn

  • Received: 6 April 2019Revised: 15 May 2019Accepted: 20 June 2019
  • The effect of Cr content and cooling rate on the microstructure of Al-Mn alloy was studied using well resistance furnace melting, and the alloy was analyzed using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The experimental results showed that adding Cr could significantly improve the morphology of the primary phase in the Al-2.5Mn alloy. Without Cr, the primary phase in the alloy was thick, needle-like, and strip-like structure. After adding 0.2wt%-0.5wt% Cr, the primary phase in the upper part of the alloy was gradually fined and reached the best effect at 0.35wt% Cr. When the content of Cr was 0.5wt%, the microstructure of the primary phase in the upper part began to coarsen. The bottom of the alloy was a large bulk phase, but still much finer than that without adding Cr. XRD and SEM analysis showed that the precipitation phase at the bottom was mainly Al85Mn7Cr8, while the fine microstructure at the top was Al6Mn and Al3Mn. The results of the cooling rate experiments showed that the primary phase of Al-2.5Mn-0.35Cr was further refined, and the eutectic microstructure was partly achieved, under air-cooling condition. And when the cooling method was iron die-cooling, the microstructure of the Al-2.5Mn-0.35Cr alloy was changed into a eutectic microstructure.
  • loading
  • [1]
    J. Sun, S.X. Xu, J. Tang, F.F. Wang, and Z.Q. Han, Development of squeeze casting technology for manufacturing aluminum alloy subframe for automobile, Foundry, 64(2015), No. 1, p. 17.
    [2]
    J.H. Park, K.J. Kim, J.W. Lee, and J.K. Yoon, Light-weight design of automotive suspension link based on design of experiment, Int. J. Automot. Technol., 16(2015), No. 1, p. 67.
    [3]
    X.H. Ao, S.M Xing, B.S. Yu, and Q.Y. Han, Effect of Ce addition on microstructures and mechanical properties of A380 aluminum alloy prepared by squeeze-casting, Int. J. Miner. Metall. Mater., 25(2018), No. 5, p. 553.
    [4]
    M.H. Farshidi, M. Rifai, and H. Miyamoto, Microstructure evolution of a recycled Al-Fe-Si-Cu alloy processed by tube channel pressing, Int. J. Miner. Metall. Mater., 25(2018), No. 10, p. 1166.
    [5]
    F.S. Pan and D.F. Zhang, Aluminum Alloy and Application, Chemical Industry Press, Beijing, 2006, p. 306.
    [6]
    X.C. Li, Microstructure and Metallographic Map of Aluminum Alloy Materials, Metallurgical Industry Press, Beijing, 2010, p. 1639.
    [7]
    Q. Zhao and S.X. Wang, Selection and Design of Aluminum Alloys, Chemical Industry Press, Beijing, 2017, p. 20.
    [8]
    X.M. Wang, Engineering Materials Science, Harbin Institute of Technology Press, Harbin, 2012, p. 148.
    [9]
    H. Mraied and W. Cai, The effects of Mn concentration on the tribocorrosion resistance of Al-Mn alloys, Wear, 380-381(2017), p. 191.
    [10]
    X.P. Chen, X.G. Li, S. Li, and Q. Liu, Continuous recrystallization of commercial Al-1.2wt%Mn alloy produced by thermomechanical processing, Mater. Lett., 180(2016), p. 101.
    [11]
    Z. Li, Z. Zhang, and X.G. Chen, Effect of magnesium on dispersoid strengthening of Al-Mn-Mg-Si (3xxx) alloys, Trans. Nonferrous Met. Soc. China, 26(2016), No. 11, p. 2793.
    [12]
    M. Sugamata, J. Kaneko, and N. Kimura, Structure and properties of rapidly solidified P/M samples of Al-Mn-Cr alloys, Mater. Sci. Forum, 416-418(2003), p. 359.
    [13]
    F.G. Coury, C.S. Kiminami, W.J. Botta, C. Bolfarini, and M. Kaufman, Design and production of Al-Mn-Ce alloys with tailored properties, Mater. Des., 110(2016), p. 436.
    [14]
    A. Kula, L. Blaz, and P. Lobry, Structure and properties studies of rapidly solidified Al-Mn alloys, Key Eng. Mater., 682(2016), p. 199.
    [15]
    D.W. Luo, J. Guo, Z.M. Yan, and T.J. Li, Effect of high magnetic fields on the solidification microstructure of an Al-Mn alloy, Rare Met., 28(2009), No. 3, p. 302.
    [16]
    Y.B. Dong, Y. Liu, and H. Lin, Leaching behavior of V, Pb, Cd, Cr, and As from stone coal waste rock with different particle sizes, Int. J. Miner. Metall. Mater., 25(2018), No. 8, p. 861.
    [17]
    C. Lin, S.S. Wu, S.L. Lü, P. An, and H.B. Wu, Effects of high-pressure rheo-squeeze casting on the Fe-rich phases and mechanical properties of Al-17Si-(1,1.5)Fe alloys, Int. J. Miner. Metall. Mater., 25(2018), No. 9, p. 1018.
    [18]
    K. Liu and X.G. Chen. Evolution of microstructure and elevated-temperature properties with Mn addition in Al-Mn-Mg alloys, J. Mater. Res., 32(2017), No. 13, p. 1.
    [19]
    L. Zhen, Z. Zhan, and X.G. Chen, Improvement in the mechanical properties and creep resistance of Al-Mn-Mg 3004 alloy with Sc and Zr addition, Mater. Sci. Eng. A, 729(2018), p. 196.
    [20]
    F.G. Coury, E.L. Pires, W. Wolf, F.H.P. de Almeida, A.L.C. e Silva, W.J. Botta, C.S. Kiminami, and M.J. Kaufman, Insight into the complex ternary phase behavior in Al-Mn-Ce alloys, J. Alloys Compd., 727(2017), p. 460.
    [21]
    S.L. Cui and I.H. Jung, Thermodynamic modeling of the Al-Cr-Mn ternary system, Metall. Mater. Trans. A, 48(2017), No. 3, p. 1383.
    [22]
    C.Q. Huang, J.X. Liu, and X.D. Jia, Effect of thermal deformation parameters on the microstructure, texture, and microhardness of 5754 aluminum alloy, Int. J. Miner. Metall. Mater., 26(2019), No. 9, p. 1140.
    [23]
    H.J. Kang, J.L. Li, T.M. Wang, and J.J. Guo, Growth behavior of primary intermetallic phases and mechanical properties for directionally solidified Al-Mn-Be alloy, Acta Metall. Sin., 54(2018), No. 5, p. 809.
    [24]
    X.C. Liu, Y. Pan, Z.J. Tang, W.Q. He, and T. Lu, Microstructure control and high temperature properties of Al-Mn-based alloys, Acta Metall. Sin., 53(2017), No. 11, p. 1487.
    [25]
    V. Raghavan, Al-Mn-Ni-Ti (Aluminum-Manganese-Nickel-Titanium), J. Phase Equilib. Diffus., 26(2005), No. 3, p. 280.
    [26]
    L. Ping and G.L. Dunlop, Microstructural characterization of rapidly solidified Al-Mn-Cr alloys, Mater. Sci. Eng. A, 134(1991), p. 1182.
    [27]
    H.A. Razazi, M. Paidar, and O.O. Ojo, Effect of Mn and Cr on structure and mechanical properties of Al-10%Mg-0.1%Ti alloy, Vacuum, 155(2018), p. 619.
    [28]
    G.X. Hu, X. Cai, and Y.H. Rong, Fundamentals of Materials Science, Shanghai Jiao Tong University Press, Shanghai, 2010, p. 231.
    [29]
    Y.D. He and X.M. Zhang, Refinement mechanism of trace Cr, Mn, Ti and Zr as cast 7A55 alloys, Chin. J. Nonferrous Met., 15(2005), No. 10, p. 1594.
    [30]
    Y. Birol, Effect of Cr and Zr on the grain structure of extruded EN AW 6082 alloy, Met. Mater. Int., 20(2014), No. 4, p. 727.
    [31]
    H.Q. Hu, Principle of Metal Solidification, Mechanical Industry Press, Beijing, 2017, p. 173.
    [32]
    Y. Zhang, W.B. Du, S.B. Li, K. Liu, C.H. Wang, and X.B. Zheng, Effect of cooling rate on solidification structure of Mg-8Gd-1Er alloy, Rare Met. Mater. Eng., 47(2018), No. 10, p. 3120.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Share Article

    Article Metrics

    Article Views(659) PDF Downloads(20) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return