MOF-derived molybdenum selenide on Ti3C2Tx with superior capacitive performance for lithium-ion capacitors

Jianjian Zhong; Lu Qin; Jianling Li; Zhe Yang; Kai Yang; Mingjie Zhang

doi:10.1007/s12613-022-2469-5

Volume 29 Issue 5

Apr. 2022

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2022 > 29(5): 1061-1072

Jianjian Zhong, Lu Qin, Jianling Li, Zhe Yang, Kai Yang, and Mingjie Zhang, MOF-derived molybdenum selenide on Ti₃C₂T_x with superior capacitive performance for lithium-ion capacitors, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 1061-1072. https://doi.org/10.1007/s12613-022-2469-5

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Jianjian Zhong, Lu Qin, Jianling Li, Zhe Yang, Kai Yang, and Mingjie Zhang, MOF-derived molybdenum selenide on Ti3C2Tx with superior capacitive performance for lithium-ion capacitors, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 1061-1072. https://doi.org/10.1007/s12613-022-2469-5

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Research Article

MOF-derived molybdenum selenide on Ti₃C₂T_x with superior capacitive performance for lithium-ion capacitors

+ Author Affiliations

Corresponding author:
Jianling Li E-mail: lijianling@ustb.edu.cn
Received: 24 January 2022; Revised: 2 March 2022; Accepted: 9 March 2022; Available online: 10 March 2022

Abstract

Abstract

Two-dimensional Ti₃C₂T_x exhibits outstanding rate property and cycle performance in lithium-ion capacitors (LICs) due to its unique layered structure, excellent electronic conductivity, and high specific surface area. However, like graphene, Ti₃C₂T_x restacks during electrochemical cycling due to hydrogen bonding or van der Waals forces, leading to a decrease in the specific surface area and an increase in the diffusion distance of electrolyte ions between the interlayer of the material. Here, a transition metal selenide MoSe₂ with a special three-stacked atomic layered structure, derived from metal–organic framework (MOF), is introduced into the Ti₃C₂T_x structure through a solvothermal method. The synergic effects of rapid Li⁺ diffusion and pillaring effect from the MoSe₂ and excellent conductivity from the Ti₃C₂T_x sheets endow the material with excellent electrochemical reaction kinetics and capacity. The composite Ti₃C₂T_x@MoSe₂ material exhibits a high capacity over 300 mAh·g⁻¹ at 150 mA·g⁻¹ and excellent rate property with a specific capacity of 150 mAh·g⁻¹ at 1500 mA·g⁻¹. Additionally, the material shows a superior capacitive contribution of 86.0% at 2.0 mV·s⁻¹ due to the fast electrochemical reactions. A Ti₃C₂T_x@MoSe₂//AC LIC device is also fabricated and exhibits stable cycle performance.
- two-dimensional titanium carbide;
- molybdenum selenide;
- solvothermal method;
- electrochemical kinetics

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References(37)

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