Spinel LiMn<sub>2</sub>O<sub>4</sub> integrated with coating and doping by Sn self-segregation

Huaifang Shang; Dingguo Xia

doi:10.1007/s12613-022-2482-8

Volume 29 Issue 5

Apr. 2022

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2022 > 29(5): 909-916

Huaifang Shangand Dingguo Xia, Spinel LiMn₂O₄ integrated with coating and doping by Sn self-segregation, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 909-916. https://doi.org/10.1007/s12613-022-2482-8

Cite this article as:

Huaifang Shangand Dingguo Xia, Spinel LiMn2O4 integrated with coating and doping by Sn self-segregation, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 909-916. https://doi.org/10.1007/s12613-022-2482-8

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Research Article

Spinel LiMn₂O₄ integrated with coating and doping by Sn self-segregation

Huaifang Shang¹ and
Dingguo Xia^2,

+ Author Affiliations

Corresponding author:
Dingguo Xia E-mail: dgxia@pku.edu.cn
Received: 31 January 2022; Revised: 14 March 2022; Accepted: 23 March 2022; Available online: 24 March 2022

Abstract

Abstract

The development of high-performance and low-cost cathode materials is of great significance for the progress in lithium-ion batteries. The use of Co and even Ni is not conducive to the sustainable and healthy development of the power battery industry owing to their high cost and limited resources. Here, we report LiMn₂O₄ integrated with coating and doping by Sn self-segregation. Auger electron energy spectrum and soft X-ray absorption spectrum show that the coating is Sn-rich LiMn₂O₄, with a small Sn doping in the bulk phase. The integration strategy can not only mitigate the Jahn–Teller distortion but also effectively avoid the dissolution of manganese. The as-obtained product demonstrates superior high initial capacities of 124 mAh·g⁻¹ and 120 mAh·g⁻¹ with the capacity retention of 91.1% and 90.2% at 25°C and 55°C after 50 cycles, respectively. This novel material-processing method highlights a new development direction for the progress of cathode materials for lithium-ion batteries.
- spinel lithium manganate;
- coating and doping;
- tin self-segregation;
- high capacity;
- good stability

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