Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrV<sub><i>x</i></sub>N hard coatings

Hongbo Ju; Moussa Athmani; Jing Luan; Abbas AL-Rjoub; Albano Cavaleiro; Talha Bin Yaqub; Abdelouahad Chala; Fabio Ferreira; Filipe Fernandes

doi:10.1007/s12613-023-2655-0

Volume 30 Issue 12

Dec. 2023

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2023 > 30(12): 2459-2468

Hongbo Ju, Moussa Athmani, Jing Luan, Abbas AL-Rjoub, Albano Cavaleiro, Talha Bin Yaqub, Abdelouahad Chala, Fabio Ferreira, and Filipe Fernandes, Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrV_xN hard coatings, Int. J. Miner. Metall. Mater., 30(2023), No. 12, pp. 2459-2468. https://doi.org/10.1007/s12613-023-2655-0

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Hongbo Ju, Moussa Athmani, Jing Luan, Abbas AL-Rjoub, Albano Cavaleiro, Talha Bin Yaqub, Abdelouahad Chala, Fabio Ferreira, and Filipe Fernandes, Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrVxN hard coatings, Int. J. Miner. Metall. Mater., 30(2023), No. 12, pp. 2459-2468. https://doi.org/10.1007/s12613-023-2655-0

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Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrV_xN hard coatings

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Corresponding authors:
Hongbo Ju E-mail: hju@uc.pt

Filipe Fernandes E-mail: fid@isep.ipp.pt
Received: 23 February 2023; Revised: 24 March 2023; Accepted: 17 April 2023; Available online: 1 December 2023

Abstract

Abstract

In the last decades, vanadium alloyed coatings have been introduced as potential candidates for self-lubrication due to their perfect tribological properties. In this work, the influence of V incorporation on the wear performance and oxidation resistance of TiSiN/CrN film coatings deposited by direct current (DC) reactive magnetron sputtering is investigated. The results show that vanadium incorporation significantly decreases the oxidation resistance of the coatings. In general, two layers are formed during the oxidation process: i) Ti(V)O₂ on top, followed by a protective layer, which is subdivided into two layers, Cr₂O₃ and Si–O. ii) The diffusion of V controls the oxidation of V-containing coatings. The addition of vanadium improves the wear resistance of coatings, and the wear rate decreases with increasing V content in the coatings; however, the friction coefficient is independent of the chemical composition of the coatings. The wear of the V-containing coatings is driven by polishing wear.
- DC magnetron sputtering;
- TiSiN/CrV_xN multilayer coatings;
- oxidation resistance;
- tribology;
- wear rate

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References(51)

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