Metal-organic framework derived NiFe2O4/FeNi3@C composite for efficient electrocatalytic oxygen evolution reaction

Fangna Dai; Zhifei Wang; Huakai Xu; Chuanhai Jiang; Yuguo Ouyang; Chunyu Lu; Yuan Jing; Shiwei Yao; Xiaofei Wei

doi:10.1007/s12613-023-2721-7

Volume 30 Issue 10

Oct. 2023

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2023 > 30(10): 1914-1921

Fangna Dai, Zhifei Wang, Huakai Xu, Chuanhai Jiang, Yuguo Ouyang, Chunyu Lu, Yuan Jing, Shiwei Yao, and Xiaofei Wei, Metal-organic framework derived NiFe₂O₄/FeNi₃@C composite for efficient electrocatalytic oxygen evolution reaction, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1914-1921. https://doi.org/10.1007/s12613-023-2721-7

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Fangna Dai, Zhifei Wang, Huakai Xu, Chuanhai Jiang, Yuguo Ouyang, Chunyu Lu, Yuan Jing, Shiwei Yao, and Xiaofei Wei, Metal-organic framework derived NiFe2O4/FeNi3@C composite for efficient electrocatalytic oxygen evolution reaction, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1914-1921. https://doi.org/10.1007/s12613-023-2721-7

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Research Article

Metal-organic framework derived NiFe₂O₄/FeNi₃@C composite for efficient electrocatalytic oxygen evolution reaction

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Corresponding author:
Xiaofei Wei E-mail: b21140026@s.upc.edu.cn
Received: 30 March 2023; Revised: 3 August 2023; Accepted: 9 August 2023; Available online: 10 August 2023

Abstract

Abstract

Reducing the cost and improving the electrocatalytic activity are the key to developing high efficiency electrocatalysts for oxygen evolution reaction (OER). Here, bimetallic NiFe-based metal-organic framework (MOF) was prepared by solvothermal method, and then used as precursor to prepare NiFe-based MOF-derived materials by pyrolysis. The effects of different metal ratios and pyrolysis temperatures on the sample structure and OER electrocatalytic performance were investigated and compared. The experimental results showed that when the metal molar ratio was Fe : Ni = 1:5 and the pyrolysis temperature was 450°C, the sample (FeNi₅-MOF-450) exhibits a composite structure of NiFe₂O₄/FeNi₃/C and owns the superior electrocatalytic activity in OER. When the current density is 100 mA·cm⁻², the overpotential of the sample was 377 mV with Tafel slope of 56.2 mV·dec⁻¹, which indicates that FeNi₅-MOF-450 exhibits superior electrocatalytic performance than the commercial RuO₂. Moreover, the long-term stability of FeNi₅-MOF-450 further promotes its development in OER. This work demonstrated that the regulatory methods such as component optimization can effectively improve the OER catalytic performance of NiFe-based MOF-derived materials.
- metal-organic framework derivatives;
- NiFe-based electrocatalysts;
- electrocatalytic performance;
- oxygen evolution reaction

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References(52)

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