Construction of 3D porous Cu<sub>1.81</sub>S/nitrogen-doped carbon frameworks for ultrafast and long-cycle life sodium-ion storage

Chen Chen; Hongyu Xue; Qilin Hu; Mengfan Wang; Pan Shang; Ziyan Liu; Tao Peng; Deyang Zhang; Yongsong Luo

doi:10.1007/s12613-024-2890-z

Volume 32 Issue 1

Jan. 2025

Turn off MathJax

Article Contents

Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2025 > 32(1): 191-200

Chen Chen, Hongyu Xue, Qilin Hu, Mengfan Wang, Pan Shang, Ziyan Liu, Tao Peng, Deyang Zhang, and Yongsong Luo, Construction of 3D porous Cu_1.81S/nitrogen-doped carbon frameworks for ultrafast and long-cycle life sodium-ion storage, Int. J. Miner. Metall. Mater., 32(2025), No. 1, pp. 191-200. https://doi.org/10.1007/s12613-024-2890-z

Cite this article as:

Chen Chen, Hongyu Xue, Qilin Hu, Mengfan Wang, Pan Shang, Ziyan Liu, Tao Peng, Deyang Zhang, and Yongsong Luo, Construction of 3D porous Cu1.81S/nitrogen-doped carbon frameworks for ultrafast and long-cycle life sodium-ion storage, Int. J. Miner. Metall. Mater., 32(2025), No. 1, pp. 191-200. https://doi.org/10.1007/s12613-024-2890-z

Citation:

PDF( 5716 KB)

Research Article

Construction of 3D porous Cu_1.81S/nitrogen-doped carbon frameworks for ultrafast and long-cycle life sodium-ion storage

+ Author Affiliations

Corresponding authors:
Chen Chen E-mail: chenpaper@outlook.com

Yongsong Luo E-mail: ysluo@xynu.edu.cn
Received: 30 November 2023; Revised: 4 March 2024; Accepted: 21 March 2024; Available online: 22 March 2024

Abstract

Abstract

Transition metal sulfides have great potential as anode materials for sodium-ion batteries (SIBs) due to their high theoretical specific capacities. However, the inferior intrinsic conductivity and large volume variation during sodiation–desodiation processes seriously affect its high-rate and long-cycle performance, unbeneficial for the application as fast-charging and long-cycling SIBs anode. Herein, the three-dimensional porous Cu_1.81S/nitrogen-doped carbon frameworks (Cu_1.81S/NC) are synthesized by the simple and facile sol–gel and annealing processes, which can accommodate the volumetric expansion of Cu_1.81S nanoparticles and accelerate the transmission of ions and electrons during Na⁺ insertion/extraction processes, exhibiting the excellent rate capability (250.6 mAh·g⁻¹ at 20.0 A·g⁻¹) and outstanding cycling stability (70% capacity retention for 6000 cycles at 10.0 A·g⁻¹) for SIBs. Moreover, the Na-ion full cells coupled with Na₃V₂(PO₄)₃/C cathode also demonstrate the satisfactory reversible specific capacity of 330.5 mAh·g⁻¹ at 5.0 A·g⁻¹ and long-cycle performance with the 86.9% capacity retention at 2.0 A·g⁻¹ after 750 cycles. This work proposes a promising way for the conversion-based metal sulfides for the applications as fast-charging sodium-ion battery anode.
- copper sulfide nanoparticles;
- porous carbon framework;
- fast charging;
- long-cycle performance;
- sodium-ion full batteries

FullText(HTML)

Supplements(1)

Supplementary Information-s12613-024-2890-z.docx

References(66)

References

[1]	B. Chen, S.M. Sui, F. He, et al., Interfacial engineering of transition metal dichalcogenide/carbon heterostructures for electrochemical energy applications, Chem. Soc. Rev., 52(2023), No. 22, p. 7802. doi: 10.1039/D3CS00445G
[2]	J.W. Huang, K. Wu, G. Xu, M.H. Wu, S.X. Dou, and C. Wu, Recent progress and strategic perspectives of inorganic solid electrolytes: Fundamentals, modifications, and applications in sodium metal batteries, Chem. Soc. Rev., 52(2023), No. 15, p. 4933. doi: 10.1039/D2CS01029A
[3]	J. Xu, Y.B. Liu, P.L. Chen, et al., Interlayer-expanded VS₂ nanosheet: Fast ion transport, dynamic mechanism and application in Zn²⁺ and Mg²⁺/Li⁺ hybrid batteries systems, J. Colloid Interface Sci., 620(2022), p. 119. doi: 10.1016/j.jcis.2022.04.009
[4]	H.Q. Liu, Y.N. He, K.Z. Cao, et al., Activating commercial Al pellets by replacing the passivation layer for high-performance half/full Li-ion batteries, Chem. Eng. J., 433(2022), art. No. 133572. doi: 10.1016/j.cej.2021.133572
[5]	J. Wang, S.Q. Zhao, L. Tang, et al., Review of the electrochemical performance and interfacial issues of high-nickel layered cathodes in inorganic all-solid-state batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 5, p. 1003. doi: 10.1007/s12613-022-2453-0
[6]	A. Kumar Prajapati and A. Bhatnagar, A review on anode materials for lithium/sodium-ion batteries, J. Energy Chem., 83(2023), p. 509. doi: 10.1016/j.jechem.2023.04.043
[7]	M. Chen, F.M. Liu, S.S. Chen, et al. , In situ self-catalyzed formation of carbon nanotube wrapped and amorphous nanocarbon shell coated LiFePO₄ microclew for high-power lithium ion batteries, Carbon, 203(2023), p. 661. doi: 10.1016/j.carbon.2022.12.015
[8]	Z. Dong, X. Wu, M.Y. Chen, et al., Self-supporting 1T-MoS₂@WS₂@CC composite materials for potential high-capacity sodium storage system, J. Colloid Interface Sci, 630(2023), Part B, . 426. doi: 10.1016/j.jcis.2022.10.072
[9]	W.H. Xie, W.J. Wang, L.F. Duan, et al., Amorphous carbon nanofibers incorporated with ultrafine GeO₂ nanoparticles for enhanced lithium storage performance, J. Alloys Compd., 918(2022), art. No. 165687. doi: 10.1016/j.jallcom.2022.165687
[10]	D. Wang, Q. Ma, K.H. Tian, C.Q. Duan, Z.Y. Wang, and Y.G. Liu, Ultrafine nano-scale Cu₂Sb alloy confined in three-dimensional porous carbon as an anode for sodium-ion and potassium-ion batteries, Int. J. Miner. Metall. Mater., 28(2021), No. 10, p. 1666. doi: 10.1007/s12613-021-2286-2
[11]	D. Zang, C.Y. Geng, X. Zheng, et al., Facile synthesis of the Mn₃O₄ polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion battery, Int. J. Miner. Metall. Mater., 30(2023), No. 6, p. 1152. doi: 10.1007/s12613-022-2590-5
[12]	X.H. Ma, Z.J. Chen, T.W. Zhang, et al., Efficient utilization of glass fiber separator for low-cost sodium-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 10, p. 1878. doi: 10.1007/s12613-023-2691-9
[13]	Y.F. Zhu, Y. Xiao, S.X. Dou, Y.M. Kang, and S.L. Chou, Spinel/post-spinel engineering on layered oxide cathodes for sodium-ion batteries, eScience, 1(2021), No. 1, p. 13. doi: 10.1016/j.esci.2021.10.003
[14]	Y. Liu, Y. Qing, B. Zhou, et al., Yolk−shell Sb@Void@Graphdiyne nanoboxes for high-rate and long cycle life sodium-ion batteries, ACS Nano, 17(2023), No. 3, p. 2431. doi: 10.1021/acsnano.2c09679
[15]	S.H. Liu, W.R. Zheng, W.H. Xie, et al., Synthesis of three-dimensional honeycomb-like Fe₃N@NC composites with enhanced lithium storage properties, Carbon, 192(2022), p. 162. doi: 10.1016/j.carbon.2022.02.057
[16]	L.N. Wang, X. Wu, F.T. Wang, X. Chen, J. Xu, and K.J. Huang, 1T-Phase MoS₂ with large layer spacing supported on carbon cloth for high-performance Na⁺ storage, J. Colloid Interface Sci., 583(2021), p. 579. doi: 10.1016/j.jcis.2020.09.055
[17]	J.S. Wang, F. Li, S. Zhao, L.T. Zheng, Y.Y. Huang, and Z.S. Hong, Uniform nanoplating of metallic magnesium film on titanium dioxide nanotubes as a skeleton for reversible Na metal anode, Int. J. Miner. Metall. Mater., 30(2023), No. 10, p. 1868. doi: 10.1007/s12613-023-2685-7
[18]	J. Yu, Y.B. Wei, B.C. Meng, et al., Homogeneous distributed natural pyrite-derived composite induced by modified graphite as high-performance lithium-ion batteries anode, Int. J. Miner. Metall. Mater., 30(2023), No. 7, p. 1353. doi: 10.1007/s12613-023-2598-5
[19]	Z. Tang, S.Y. Zhou, Y.C. Huang, et al., Improving the initial coulombic efficiency of carbonaceous materials for Li/Na-ion batteries: Origins, solutions, and perspectives, Electrochem. Energy Rev., 6(2023), No. 1, art. No. 8. doi: 10.1007/s41918-022-00178-y
[20]	J. Xu, Q. Liu, Z. Dong, et al., Interconnected MoS₂ on 2D graphdiyne for reversible sodium storage, ACS Appl. Mater. Interfaces, 13(2021), No. 46, p. 54974. doi: 10.1021/acsami.1c15484
[21]	C. Chen, Q.L. Hu, H.Y. Xue, et al., Rational construction of 3D porous Fe₃N@C frameworks for high-performance sodium-ion half/full batteries, J. Alloys Compd., 934(2023), art. No. 167934. doi: 10.1016/j.jallcom.2022.167934
[22]	X. Wu, X.C. Xie, H.H. Zhang, and K.J. Huang, Engineering stable and fast sodium diffusion route by constructing hierarchical MoS₂ hollow spheres, J. Colloid Interface Sci., 595(2021), p. 43. doi: 10.1016/j.jcis.2021.03.112
[23]	Z.H. Wu, C.Y. Wang, Z.Y. Hui, et al., Growing single-crystalline seeds on lithiophobic substrates to enable fast-charging lithium-metal batteries, Nat. Energy, 8(2023), p. 340.
[24]	M.M. Yuan, H.J. Liu, and F. Ran, Fast-charging cathode materials for lithium & sodium ion batteries, Mater. Today, 63(2023), p. 360. doi: 10.1016/j.mattod.2023.02.007
[25]	D.P. Qiu, A. Gao, W.T. Zhao, et al., Fast-charging degradation mechanism of two-dimensional FeSe anode in sodium-ion batteries, ACS Energy Lett., 8(2023), No. 10, p. 4052. doi: 10.1021/acsenergylett.3c01086
[26]	Y.Y. Liu, H.D. Shi, and Z.S. Wu, Recent status, key strategies and challenging perspectives of fast-charging graphite anodes for lithium-ion batteries, Energy Environ. Sci., 16(2023), No. 11, p. 4834. doi: 10.1039/D3EE02213G
[27]	J. Wang, Y.F. Yuan, X.H. Rao, et al., Realizing high-performance Na₃V₂(PO₄)₂O₂F cathode for sodium-ion batteries via Nb-doping, Int. J. Miner. Metall. Mater., 30(2023), No. 10, p. 1859. doi: 10.1007/s12613-023-2666-x
[28]	K.Y. Chen, G.J. Li, Z.H. Hu, et al., Construction of γ-MnS/α-MnS hetero-phase junction for high-performance sodium-ion batteries, Chem. Eng. J., 435(2022), art. No. 135149. doi: 10.1016/j.cej.2022.135149
[29]	Z.Q. Hao, X.Y. Shi, Z. Yang, L. Li, and S.L. Chou, Developing high-performance metal selenides for sodium-ion batteries, Adv. Funct. Mater., 32(2022), No. 51, art. No. 2208093. doi: 10.1002/adfm.202208093
[30]	Y.J. Wu, W. Shuang, Y. Wang, et al., Implementation of structural and surface engineering strategies to copper sulfide for enhanced sodium-ion storage, J. Alloys Compd., 923(2022), art. No. 166308. doi: 10.1016/j.jallcom.2022.166308
[31]	H.Q. Liu, Y.N. He, H. Zhang, et al., Lowering the voltage-hysteresis of CuS anode for Li-ion batteries via constructing heterostructure, Chem. Eng. J., 425(2021), art. No. 130548. doi: 10.1016/j.cej.2021.130548
[32]	Z. Ali, T. Zhang, M. Asif, L.N. Zhao, Y. Yu, and Y.L. Hou, Transition metal chalcogenide anodes for sodium storage, Mater. Today, 35(2020), p. 131. doi: 10.1016/j.mattod.2019.11.008
[33]	P.F. Huang, H.J. Ying, S.L. Zhang, Z. Zhang, and W.Q. Han, In situ fabrication of via Lewis acidic etching route for efficient sodium storage, J. Mater. Chem. A, 10(2022), No. 41, p. 22135. doi: 10.1039/D2TA06695E
[34]	R. Lu, S. Zhou, S.M. Chai, et al., Cu₉S₅ nanoparticles encapsulated in N, S co-doped carbon nanofibers as anodes for high-performance lithium-ion and sodium-ion batteries, J. Phys. D: Appl. Phys., 55(2022), No. 33, art. No. 334001. doi: 10.1088/1361-6463/ac7111
[35]	X.D. Ding, S. Lei, C.F. Du, Z.L. Xie, J.R. Li, and X.Y. Huang, Copper Sulfides: Small-sized CuS nanoparticles/N, S co-doped rGO composites as the anode materials for high-performance lithium-ion batteries, Adv. Mater. Interfaces, 6(2019), No. 6, art. No. 1900038. doi: 10.1002/admi.201900038
[36]	Y.Y. Sun, Y. Li, L.M. Sheng, et al., Universal synthesis of free-standing metal-sulfides@metal@multi-walled carbon nanotube anode for high-performance sodium ion battery, Chem. Eng. J., 414(2021), art. No. 128732. doi: 10.1016/j.cej.2021.128732
[37]	Y. Shang, X.X. Li, S.Z. Huang, et al., A selective reduction approach to construct robust Cu_1.81S truss structures for high-performance sodium storage, Matter, 2(2020), No. 2, p. 428. doi: 10.1016/j.matt.2019.10.027
[38]	J.Z. Li, L.L. Wang, L. Li, C.X. Lv, I.V. Zatovsky, and W. Han, Metal sulfides@carbon microfiber networks for boosting lithium ion/sodium ion storage via a general metal – Aspergillus niger bioleaching strategy, ACS Appl. Mater. Interfaces, 11(2019), No. 8, p. 8072. doi: 10.1021/acsami.8b21976
[39]	J. Xia, L. Liu, S. Jamil, et al., Free-standing SnS/C nanofiber anodes for ultralong cycle-life lithium-ion batteries and sodium-ion batteries, Energy Storage Mater., 17(2019), p. 1. doi: 10.1016/j.ensm.2018.08.005
[40]	Y.N. Chen, Y.B. Zhao, W.J. He, et al., Cu-MOFs derived three-dimensional Cu_1.81S@C for high energy storage performance, Mater. Today Commun., 37(2023), art. No. 106955. doi: 10.1016/j.mtcomm.2023.106955
[41]	L.X. Xie, Z. Yang, J.Y. Sun, et al., Bi₂Se₃/C nanocomposite as a new sodium-ion battery anode material, Nano Micro Lett., 10(2018), No. 3, art. No. 50. doi: 10.1007/s40820-018-0201-9
[42]	W.Q. Wang, Y.Y. Yang, Y.N. Nuli, J.J. Zhou, J. Yang, and J.L. Wang, Metal organic framework (MOF)-derived carbon-encapsulated cuprous sulfide cathode based on displacement reaction for Hybrid Mg²⁺/Li⁺ batteries, J. Power Sources, 445(2020), art. No. 227325. doi: 10.1016/j.jpowsour.2019.227325
[43]	X.Y. Yang, C.L. Du, Y.Q. Zhu, et al., Constructing defect-rich unconventional phase Cu_7.2S₄ nanotubes via microwave-induced selective etching for ultra-stable rechargeable magnesium batteries, Chem. Eng. J., 430(2022), art. No. 133108. doi: 10.1016/j.cej.2021.133108
[44]	C. Chen, Q.L. Hu, F. Yang, et al., A facile synthesis of CuSe nanosheets for high-performance sodium-ion hybrid capacitors, RSC Adv., 12(2022), No. 33, p. 21558. doi: 10.1039/D2RA03206F
[45]	Y.H. Xiao, F. Yue, Z.Q. Wen, et al., Elastic buffering layer on CuS enabling high-rate and long-life sodium-ion storage, Nanomicro Lett., 14(2022), No. 1, art. No. 193. doi: 10.1007/s40820-022-00924-3
[46]	Y.H. Zhao, Z. Hu, C.L. Fan, et al., Novel structural design and adsorption/insertion coordinating quasi-metallic Na storage mechanism toward high-performance hard carbon anode derived from carboxymethyl cellulose, Small, 19(2023), No. 41, art. No. e2303296. doi: 10.1002/smll.202303296
[47]	Y. Jiang, F. Wu, Z.Q. Ye, et al., Confining CoTe₂–ZnTe heterostructures on petal-like nitrogen-doped carbon for fast and robust sodium storage, Chem. Eng. J., 451(2023), art. No. 138430. doi: 10.1016/j.cej.2022.138430
[48]	G.Z. Fang, Z.X. Wu, J. Zhou, et al., Observation of pseudocapacitive effect and fast ion diffusion in bimetallic sulfides as an advanced sodium-ion battery anode, Adv. Energy Mater., 8(2018), No. 19, art. No. 1703155. doi: 10.1002/aenm.201703155
[49]	Z.H. Pan, X.H. Zhang, S.T. Xu, M.Z. Gu, X.H. Rui, and X.J. Zhang, Chloride-doping, defect and interlayer engineering of copper sulfide for superior sodium-ion batteries, J. Mater. Chem. A, 11(2023), No. 8, p. 4102. doi: 10.1039/D2TA09612A
[50]	M.J. Jing, F.Y. Li, M.J. Chen, et al., Facile synthetic strategy to uniform Cu₉S₅ embedded into carbon: A novel anode for sodium-ion batteries, J. Alloys Compd., 762(2018), p. 473. doi: 10.1016/j.jallcom.2018.05.224
[51]	Y.H. Wang, Y. Yang, D.Y. Zhang, et al., Inter-overlapped MoS₂/C composites with large-interlayer-spacing for high-performance sodium-ion batteries, Nanoscale Horiz., 5(2020), No. 7, p. 1127. doi: 10.1039/D0NH00152J
[52]	H. Li, Y.H. Wang, J.L. Jiang, Y.Y. Zhang, Y.Y. Peng, and J.B. Zhao, CuS microspheres as high-performance anode material for Na-ion batteries, Electrochim. Acta, 247(2017), p. 851. doi: 10.1016/j.electacta.2017.07.018
[53]	R.H. Liu, Y.H. Zhang, D.D. Wang, et al., Microwave-assisted synthesis of self-assembled camellia-like CuS superstructure of ultra-thin nanosheets and exploration of its sodium ion storage properties, J. Electroanal. Chem., 898(2021), art. No. 115607. doi: 10.1016/j.jelechem.2021.115607
[54]	J.B. Wang, J. Okabe, K. Urita, I. Moriguchi, and M.D. Wei, Cu₂S hollow spheres as an anode for high-rate sodium storage performance, J. Electroanal. Chem., 874(2020), art. No. 114523. doi: 10.1016/j.jelechem.2020.114523
[55]	L.F. Zhang, Y. Hu, Y. Liu, J.X. Bai, H. Ruan, and S.W. Guo, Tunable CuS nanocables with hierarchical nanosheet-assembly for ultrafast and long-cycle life sodium-ion storage, Ceram. Int., 47(2021), No. 10, p. 14138. doi: 10.1016/j.ceramint.2021.01.284
[56]	Y.H. Xiao, D.C. Su, X.Z. Wang, et al., CuS Microspheres with Tunable Interlayer space and micropore as a high-rate and long-life anode for sodium-ion batteries, Adv. Energy Mater., 8(2018), No. 22, art. No. 1800930. doi: 10.1002/aenm.201800930
[57]	Zulkifli, S. Lee, G. Alfaza, A.N. Fahri, et al., Encapsulation of Cu₂S with a nitrogen-doped carbon boosts Na⁺ storage with a reversible Na₂S conversion reaction, Mater. Today Sustain., 22(2023), art. No. 100348. doi: 10.1016/j.mtsust.2023.100348
[58]	H. Qi, Y. Hou, W.J. Wang, W. Deng, L. Tang, and C.Y. Zhang, Single-crystalline nanoflakes assembled CuS microspheres with improved sodium ion storage, J. Alloys Compd., 942(2023), art. No. 168884. doi: 10.1016/j.jallcom.2023.168884
[59]	X. Pei, Y.Q. Zhu, C.L. Du, et al., Single-crystal copper sulfide anode with fast ion diffusion for high-rate sodium-ion batteries, ACS Appl. Energy Mater., 6(2023), No. 15, p. 8132. doi: 10.1021/acsaem.3c01234
[60]	X.Y. Tong, Z. Wang, Z.Y. Liu, et al., Phosphorus-doped copper sulfide microspheres with a hollow structure for high-performance sodium-ion batteries, New J. Chem., 47(2023), No. 20, p. 9861. doi: 10.1039/D3NJ00709J
[61]	C. Chen, Q.L. Hu, H.Y. Xue, et al., Achieving high-rate capacity FeSe₂@N-doped carbon decorated with Ti₃C₂T_x MXenes for sodium ion batteries, Mater. Today Chem., 34(2023), art. No. 101796. doi: 10.1016/j.mtchem.2023.101796
[62]	A.N. Wang, W.W. Hong, L. Li, et al., Bi₃Se₄ nanodots in porous carbon: A new anode candidate for fast lithium/sodium storage, Energy Storage Mater., 53(2022), p. 1. doi: 10.1016/j.ensm.2022.08.042
[63]	B. Yan, L.C. Lin, H. Sun, et al., Double-shelled NiS/SnS@N-doped carbon nanoboxes engineered from NiSn(OH)₆ cube templates for advanced sodium-ion battery anodes, Chem. Eng. J., 477(2023), art. No. 146950. doi: 10.1016/j.cej.2023.146950
[64]	C. Chen, Q.L. Hu, H.Y. Xue, et al., Ultrafast and ultrastable FeSe₂ embedded in nitrogen-doped carbon nanofibers anode for sodium-ion half/full batteries, Nanotechnology, 35(2023), No. 5, art. No. 055404. doi: 10.1088/1361-6528/ad06d7
[65]	Y.J. Liu, M. Qiu, X. Hu, et al., Anion defects engineering of ternary Nb-based chalcogenide anodes toward high-performance sodium-based dual-ion batteries, Nano Micro Lett., 15(2023), No. 1, art. No. 104. doi: 10.1007/s40820-023-01070-0
[66]	Z. Wang, S.M. Chen, J.M. Qiu, et al., Full-cell presodiation strategy to enable high-performance Na-ion batteries, Adv. Energy Mater., 13(2023), No. 45, art. No. 2302514. doi: 10.1002/aenm.202302514