Polypyrrole-coated triple-layer yolk-shell Fe<sub>2</sub>O<sub>3</sub> anode materials with their superior overall performance in lithium-ion batteries

Zhen He; Jiaming Liu; Yuqian Wei; Yunfei Song; Wuxin Yang; Aobo Yang; Yuxin Wang; Bo Li

doi:10.1007/s12613-024-2954-0

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Zhen He, Jiaming Liu, Yuqian Wei, Yunfei Song, Wuxin Yang, Aobo Yang, Yuxin Wang, and Bo Li, Polypyrrole-coated triple-layer yolk-shell Fe₂O₃ anode materials with their superior overall performance in lithium-ion batteries, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-2954-0

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Zhen He, Jiaming Liu, Yuqian Wei, Yunfei Song, Wuxin Yang, Aobo Yang, Yuxin Wang, and Bo Li, Polypyrrole-coated triple-layer yolk-shell Fe2O3 anode materials with their superior overall performance in lithium-ion batteries, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-2954-0

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Research Article

Polypyrrole-coated triple-layer yolk-shell Fe₂O₃ anode materials with their superior overall performance in lithium-ion batteries

+ Author Affiliations

Corresponding authors:
Yuxin Wang E-mail: ywan943@163.com

Bo Li E-mail: bli219@aucklanduni.ac.nz
Received: 22 February 2024; Revised: 31 May 2024; Accepted: 6 June 2024; Available online: 12 June 2024

Abstract

Abstract

Iron oxide (Fe₂O₃) emerges as a highly attractive anode candidate among rapidly expanding energy storage market. Nonetheless, its considerable volume changes during cycling as an electrode material result in a vast reduced battery cycle life. In this work, an approach is pioneered for preparing high-performance Fe₂O₃ anode materials, by innovatively synthesizing a triple-layer yolk-shell Fe₂O₃ uniformly coated with a conductive polypyrrole (Ppy) layer (Fe₂O₃@Ppy-TLY). The uniform polypyrrole coating introduces more reaction sites and adsorption sites, and maintains structure stability through charge-discharge process. In the uses as lithium-ion battery electrodes, Fe₂O₃@Ppy-TLY demonstrates high reversible specific capacity (maintaining a discharge capacity of 1375.11 mAh·g⁻¹ after 500 cycles at 1 C), exceptional cycling stability (retaining the steady charge-discharge performance at 544.33 mAh·g⁻¹ after 6000 ultrafast charge-discharge cycles at a 10 C current density), and outstanding high current charge-discharge performance (retaining a reversible capacity of 156.75 mAh·g⁻¹ after 10000 cycles at 15 C), thereby exhibiting superior lithium storage performance. This work introduces innovative advancements for Fe₂O₃ anode design, aiming to enhance its performance in energy storage fields.
- Fe₂O₃;
- structure design;
- anode material;
- lithium-ion battery

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[1]	J.X. Sun, L.Q. Ye, X.R. Zhao, P.P. Zhang, and J. Yang, Electronic modulation and structural engineering of carbon-based anodes for low-temperature lithium-ion batteries: A review, Molecules, 28(2023), No. 5, art. No. 2108. doi: 10.3390/molecules28052108
[2]	P.F. Hu, C.F. Meng, F.G. Li, et al., Hierarchical multi-yolk-shell copper oxide@copper-1,3,5-benzenetricarboxylate as an ultrastable anode for lithium ion batteries, J. Colloid Interface Sci., 617(2022), p. 568. doi: 10.1016/j.jcis.2022.02.134
[3]	L. Chen, M.R. Yang, F. Kong, J.Y. Guo, H.B. Shu, and J. Dai, Metallic penta-Graphene/penta-BN₂ heterostructure with high specific capacity: A novel application platform for Li/Na-ion batteries, J. Alloys Compd., 901(2022), art. No. 163538. doi: 10.1016/j.jallcom.2021.163538
[4]	J.L. Chen, X.M. Guo, M.Y. Gao, et al., Self-supporting dual-confined porous Si@c-ZIF@carbon nanofibers for high-performance lithium-ion batteries, Chem. Commun., 57(2021), No. 81, p. 10580. doi: 10.1039/D1CC04172J
[5]	J.J. Xu, D. Wang, S.Y. Kong, R.Z. Li, Z.L. Hong, and F.Q. Huang, Pyrochlore phase Ce₂Sn₂O₇ via an atom-confining strategy for reversible lithium storage, J. Mater. Chem. A, 8(2020), No. 11, p. 5744. doi: 10.1039/C9TA13602A
[6]	D. Zhang, C.Y. Zhang, X. Zheng, et al., Facile synthesis of the Mn₃O₄ polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 6, p. 1152. doi: 10.1007/s12613-022-2590-5
[7]	L. Chen, M.R. Yang, F. Kong, W.L. Du, J.Y. Guo, and H.B. Shu, Penta-BCN monolayer with high specific capacity and mobility as a compelling anode material for rechargeable batteries, Phys. Chem. Chem. Phys., 23(2021), No. 32, p. 17693. doi: 10.1039/D1CP03017E
[8]	P. Wang, M.Q. Shen, H. Zhou, C.F. Meng, and A.H. Yuan, MOF-derived CuS@Cu-BTC composites as high-performance anodes for lithium-ion batteries, Small, 15(2019), No. 47, art. No. 1903522. doi: 10.1002/smll.201903522
[9]	J. Yu, Y.B. Wei, B.C. Meng, et al., Homogeneous distributed natural pyrite-derived composite induced by modified graphite as high-performance lithium-ion batteries anode, Int. J. Miner. Metall. Mater., 30(2023), No. 7, p. 1353. doi: 10.1007/s12613-023-2598-5
[10]	K. Cao, L. Jiao, H. Liu, et al., 3D Hierarchical porous α‐Fe₂O₃ nanosheets for high‐performance lithium‐ion batteries, Adv. Energy Mater., 5(2015), No. 4, art. No. 1401421. doi: 10.1002/aenm.201401421
[11]	J.F. Zhao, S.C. Zhang, W.B. Liu, Z.J. Du, and H. Fang, Fe₃O₄/PPy composite nanospheres as anode for lithium-ion batteries with superior cycling performance, Electrochim. Acta, 121(2014), p. 428. doi: 10.1016/j.electacta.2013.12.105
[12]	B. Li, T. Zhang, S.H. Wei, and W. Gao, Nitrogen-doped carbon hollow spheres packed with multiple nano Sn particles for enhanced lithium storage, Chem. Eng. J., 446(2022), art. No. 136768. doi: 10.1016/j.cej.2022.136768
[13]	B. Li, W. Zhang, T. Zhang, S.H. Wei, and W. Gao, Accurately tailoring yolk-shell spheres to balance cycling stability and volumetric capacity of lithium storage, J. Alloys Compd., 917(2022), art. No. 165548. doi: 10.1016/j.jallcom.2022.165548
[14]	G.L. Xia, Q.L. Gao, D.L. Sun, and X.B. Yu, Porous carbon nanofibers encapsulated with peapod-like hematite nanoparticles for high-rate and long-life battery anodes, Small, 13(2017), No. 44, art. No. 1701561. doi: 10.1002/smll.201701561
[15]	J.M. Jeong, B.G. Choi, S.C. Lee, et al., Hierarchical hollow spheres of Fe₂O₃@Polyaniline for lithium ion battery anodes, Adv. Mater., 25(2013), No. 43, p. 6250. doi: 10.1002/adma.201302710
[16]	Y.C. Chen, C.X. Kang, L. Ma, et al., MOF-derived Fe₂O₃ decorated with MnO₂ nanosheet arrays as anode for high energy density hybrid supercapacitor, Chem. Eng. J., 417(2021), art. No. 129243. doi: 10.1016/j.cej.2021.129243
[17]	C. Park, E. Samuel, B. Joshi, et al., Supersonically sprayed Fe₂O₃/C/CNT composites for highly stable Li-ion battery anodes, Chem. Eng. J., 395(2020), art. No. 125018. doi: 10.1016/j.cej.2020.125018
[18]	Y.S. Choi, W. Choi, W.S. Yoon, and J.M. Kim, Unveiling the genesis and effectiveness of negative fading in nanostructured iron oxide anode materials for lithium-ion batteries, ACS Nano, 16(2022), No. 1, p. 631. doi: 10.1021/acsnano.1c07943
[19]	X.Y. Chen, N. Sawut, K.A. Chen, et al., Filling carbon: A microstructure-engineered hard carbon for efficient alkali metal ion storage, Energy Environ. Sci., 16(2023), No. 9, p. 4041. doi: 10.1039/D3EE01154B
[20]	H. Kim, J.C. Hyun, D.H. Kim, et al., Revisiting lithium- and sodium-ion storage in hard carbon anodes, Adv. Mater., 35(2023), No. 12, art. No. 2209128. doi: 10.1002/adma.202209128
[21]	W.J. Han, X.Y. Qin, J.X. Wu, et al., Electrosprayed porous Fe₃O₄/carbon microspheres as anode materials for high-performance lithium-ion batteries, Nano Res., 11(2018), No. 2, p. 892. doi: 10.1007/s12274-017-1700-6
[22]	S.Y. Zhang, P.G. Zhang, A.J. Xie, S.K. Li, F.Z. Huang, and Y.H. Shen, A novel 2D porous print fabric-like α-Fe₂O₃ sheet with high performance as the anode material for lithium-ion battery, Electrochim. Acta, 212(2016), p. 912. doi: 10.1016/j.electacta.2016.06.099
[23]	H. Huang, L.J. Kong, W. Shuang, W. Xu, J. He, and X.H. Bu, Controlled synthesis of core-shell Fe₂O₃@N-C with ultralong cycle life for lithium-ion batteries, Chin. Chem. Lett., 33(2022), No. 2, p. 1037. doi: 10.1016/j.cclet.2021.08.013
[24]	X.Y. Hou, J.L. Kang, G. Zhou, and J.T. Wang, Preparation of Fe₂O₃@C composite with octahedron-like Fe₂O₃ embedded in carbon framework as a superior anode for LIBs, Mater. Lett., 313(2022), art. No. 131736. doi: 10.1016/j.matlet.2022.131736
[25]	Z.X. Lu, J. Wang, W.L. Feng, et al., Zinc single-atom regulated hard carbons for high rate and low temperature sodium ion batteries, Adv. Mater., 35(2023),No. 26, art. No. 2211461. doi: 10.1002/adma.202211461
[26]	F.P. Chen, Y.J. Di, Q. Su, et al., Vanadium-modified hard carbon spheres with sufficient pseudographitic domains as high-performance anode for sodium-ion batteries, Carbon Energy, 5(2023), No. 2, art. No. e191. doi: 10.1002/cey2.191
[27]	H.Y. Wang, H.X. Chen, C. Chen, et al., Tea-derived carbon materials as anode for high-performance sodium ion batteries, Chin. Chem. Lett., 34(2023), No. 4, art. No. 107465. doi: 10.1016/j.cclet.2022.04.063
[28]	C. Zhao, Z.F. Yan, B. Zhou, et al., Identifying the role of lewis-base sites for the chemistry in lithium-oxygen batteries, Angew. Chem. Int. Ed., 62(2023), No. 32, art. No. e202302746. doi: 10.1002/anie.202302746
[29]	L.L. Zhang, T. Wang, T.N. Gao, et al., Multistage self-assembly strategy: Designed synthesis of N-doped mesoporous carbon with high and controllable pyridine N content for ultrahigh surface-area-normalized capacitance, CCS Chem., 3(2021), No. 2, p. 870. doi: 10.31635/ccschem.020.202000233
[30]	R. Arrigo, M. Hävecker, S. Wrabetz, et al., Tuning the acid/base properties of nanocarbons by functionalization via amination, J. Am. Chem. Soc., 132(2010), No. 28, p. 9616. doi: 10.1021/ja910169v
[31]	J.Y. Mao, D.C. Niu, N. Zheng, et al., Fe₃O₄-embedded and N-doped hierarchically porous carbon nanospheres as high-performance lithium ion battery anodes, ACS Sustainable Chem. Eng., 7(2019), No. 3, p. 3424. doi: 10.1021/acssuschemeng.8b05651
[32]	P. Bhattacharya, M. Kota, D.H. Suh, K.C. Roh, and H.S. Park, Biomimetic spider-web-like composites for enhanced rate capability and cycle life of lithium ion battery anodes, Adv. Energy Mater., 7(2017), No. 17, art. No. 1700331. doi: 10.1002/aenm.201700331
[33]	Z.C. Yang, J.G. Shen, and L.A. Archer, An in situ method of creating metal oxide–carbon composites and their application as anode materials for lithium-ion batteries, J. Mater. Chem., 21(2011), No. 30, p. 11092. doi: 10.1039/c1jm10902b
[34]	Y. Yang, J.Q. Li, D.Q. Chen, and J.B. Zhao, A facile electrophoretic deposition route to the Fe₃O₄/CNTs/rGO composite electrode as a binder-free anode for lithium ion battery, ACS Appl. Mater. Interfaces, 8(2016), No. 40, p. 26730. doi: 10.1021/acsami.6b07990
[35]	F.X. Ma, H.B. Wu, C.Y. Xu, L. Zhen, and X.W. (David) Lou, Self-organized sheaf-like Fe₃O₄/C hierarchical microrods with superior lithium storage properties, Nanoscale, 7(2015), No. 10, p. 4411. doi: 10.1039/C5NR00046G
[36]	L.P. Kong, Y.T. Zhu, P.J. Williams, M. Kabbani, F.R. Brushett, and J.L.M. Rupp, Insights into Li⁺ storage mechanisms, kinetics, and reversibility of defect-engineered and functionalized multi-walled carbon nanotubes for enhanced energy storage, J. Mater. Chem. A, 12(2024), No. 7, p. 4299. doi: 10.1039/D3TA07362A
[37]	J.H. Kim, G.D. Park, and Y.C. Kang, Amorphous iron oxide–selenite composite microspheres with a yolk–shell structure as highly efficient anode materials for lithium-ion batteries, Nanoscale, 12(2020), No. 19, p. 10790. doi: 10.1039/D0NR01905D
[38]	X. Huang, H. Yu, J. Chen, Z.Y. Lu, R. Yazami, and H.H. Hng, Ultrahigh rate capabilities of lithium-ion batteries from 3D ordered hierarchically porous electrodes with entrapped active nanoparticles configuration, Adv. Mater., 26(2014), No. 8, p. 1296. doi: 10.1002/adma.201304467
[39]	S.H. Lee, S.H. Yu, J.E. Lee, et al., Self-assembled Fe₃O₄ nanoparticle clusters as high-performance anodes for lithium ion batteries via geometric confinement, Nano Lett., 13(2013), No. 9, p. 4249. doi: 10.1021/nl401952h
[40]	L. Liu, X.F. Yang, C.X. Lv, et al., Seaweed-derived route to Fe₂O₃ hollow nanoparticles/N-doped graphene aerogels with high lithium ion storage performance, ACS Appl. Mater. Interfaces, 8(2016), No. 11, p. 7047. doi: 10.1021/acsami.5b12427
[41]	L.W. Su, Y.R. Zhong, and Z. Zhou, Role of transition metal nanoparticles in the extra lithium storage capacity of transition metal oxides: A case study of hierarchical core–shell Fe₃O₄@C and Fe@C microspheres, J. Mater. Chem. A, 1(2013), No. 47, p. 15158. doi: 10.1039/c3ta13233a
[42]	T.Z. Yuan, Y.Z. Jiang, W.P. Sun, et al., Ever-increasing pseudocapacitance in RGO–MnO–RGO sandwich nanostructures for ultrahigh-rate lithium storage, Adv. Funct. Mater., 26(2016), No. 13, p. 2198. doi: 10.1002/adfm.201504849
[43]	Y.T. Ma, J. Huang, X. Liu, et al., 3D graphene-encapsulated hierarchical urchin-like Fe₃O₄ porous particles with enhanced lithium storage properties, Chem. Eng. J., 327(2017), p. 678. doi: 10.1016/j.cej.2017.06.147
[44]	H. Wu, G.H. Yu, L.J. Pan, et al., Stable Li-ion battery anodes by in situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles, Nat. Commun., 4(2013), art. No. 1943. doi: 10.1038/ncomms2941
[45]	X.S. Zhou, L.J. Wan, and Y.G. Guo, Binding SnO₂ nanocrystals in nitrogen-doped graphene sheets as anode materials for lithium-ion batteries, Adv. Mater., 25(2013), No. 15, p. 2152. doi: 10.1002/adma.201300071
[46]	J.H. Zhao, X.X. He, W.H. Lai, et al., Catalytic defect-repairing using manganese ions for hard carbon anode with high-capacity and high-initial-coulombic-efficiency in sodium-ion batteries, Adv. Energy Mater., 13(2023), No. 18, art. No. 2300444. doi: 10.1002/aenm.202300444
[47]	J.C. Guo, Q. Liu, C.S. Wang, and M.R. Zachariah, Interdispersed amorphous MnOx–carbon nanocomposites with superior electrochemical performance as lithium-storage material, Adv. Funct. Mater., 22(2012), No. 4, p. 803. doi: 10.1002/adfm.201102137
[48]	P. Santhoshkumar, K. Prasanna, Y.N. Jo, I.N. Sivagami, S.H. Kang, and C.W. Lee, A facile and highly efficient short-time homogenization hydrothermal approach for the smart production of high-quality α-Fe₂O₃ for rechargeable lithium batteries, J. Mater. Chem. A, 5(2017), No. 32, p. 16712. doi: 10.1039/C7TA04797E
[49]	M. Hong, Y.J. Su, C. Zhou, et al., Scalable synthesis of γ-Fe₂O₃/CNT composite as high-performance anode material for lithium-ion batteries, J. Alloys Compd., 770(2019), p. 116. doi: 10.1016/j.jallcom.2018.08.118
[50]	P. Huang, W. Tao, H.X. Wu, et al., N-doped coaxial CNTs@α-Fe₂O₃@C nanofibers as anode material for high performance lithium ion battery, J. Energy Chem., 27(2018), No. 5, p. 1453. doi: 10.1016/j.jechem.2017.09.011
[51]	M. Li, H.R. Du, L. Kuai, K.F. Huang, Y.Y. Xia, and B.Y. Geng, Scalable dry production process of a superior 3D net-like carbon-based iron oxide anode material for lithium-ion batteries, Angew. Chem. Int. Ed., 56(2017), No. 41, p. 12649. doi: 10.1002/anie.201707647
[52]	Z.Z. Du, X.J. Chen, W. Hu, et al., Cobalt in nitrogen-doped graphene as single-atom catalyst for high-sulfur content lithium–sulfur batteries, J. Am. Chem. Soc., 141(2019), No. 9, p. 3977. doi: 10.1021/jacs.8b12973